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141.
CHEN Shi-Hua XIAO Jing-Lin 《理论物理通讯》2008,50(12):1287-1289
On the condition of electric-LO phonon strong coupling in unsymmetrical parabolic confinement potential quantum dot (QD), we obtain the eigenenergies of the ground state and the first-excited state, the eigenfunctions of the ground state, and the first-excited state by using variational method of Pekar type. This system in QD may be employed as a two-level quantum system-qubit. When the electron is in the superposition state of the ground state and the first-excited state, we obtain the time evolution of the electron density. The relations both the probability density of electron and the period of oscillation with the electron-LO-phonon coupling strength, the confinement strengths in the xy-plane and the z-direction are discussed. 相似文献
142.
给出了拓扑线性空间中的一个Drop定理.利用此Drop定理,证明了拓扑线性空间中的每个序列紧凸集具有Drop性质;每个可数紧闭凸集具有拟Drop性质.而且结出了拓扑线性空间中Drop性质和拟Drop性质的序列流特征.也讨论了Drop性质和拟Drop性质与泛函取极值之间的联系. 相似文献
143.
Haixia Wang Qishao Lu Qingyun Wang 《Communications in Nonlinear Science & Numerical Simulation》2008,13(8):1668-1675
Bursting is an important electrical behavior in neuron’s firing. In this paper, based on the fast/slow dynamical bifurcation analysis and the phase plane analysis, two types of bursting are presented in the modified Morris–Lecar neuronal model, and the associated bifurcation mechanisms of switching between the active phase and the silent phase are analyzed. For two coupled bursters, it is found that the same type of coupled bursters may have different synchronization transition path from that of two different types of coupled bursters. The analysis of bursting types and the transition to synchronization may provide us with better insight into neuronal encoding and information transmission. 相似文献
144.
采用基于密度泛函理论的第一性原理计算方法,系统地研究了不同掺杂浓度下过渡族元素Cr、Mn、Co、Ni在Al13Fe4相中的占位情况、结构稳定性和机械性能. 计算得到所有的Al13(Fe24-xMx) (M=Cr、Mn、Co、Ni;X=1,2,4)相都具有良好的热力学稳定性和机械稳定性. 相同掺杂浓度化合物的形成焓按如下顺序减小:Al78(Fe24-xCrx) > Al78(Fe24-xMnx) > Al13Fe4 > Al78(Fe24-xNix) > Al78(Fe24-xCox).形成焓的降低增加了Al13Fe4相成核驱动力,Co和Ni有利于促进Al-Fe合金中Al13Fe4相形核,细化Al13Fe4相. 过渡族元素可以改善金属间化合物的脆性,增强塑性变形能力. 并且随着掺杂浓度的增加,过渡族元素的加入对脆性的改善呈先增大后减小的趋势. 相似文献
145.
金刚石纳米柱是实现色心单光子源增强的有效结构,而纳米柱结构尺寸决定泵浦光对色心的激发强度.本文为提高其激发效率,采用时域有限差分法(Finite Difference Time Domain, FDTD)研究金刚石纳米柱的光学性质.通过仿真分析了纳米柱直径和高度对内部电场强度的影响.结果表明,在泵浦光波长为532 nm时,纳米柱内部中轴线上场强受尺寸变化影响较大,当直径不变、改变高度时,场强最大值随高度周期性变化,周期约为150 nm;当高度不变、改变直径时,场强最大值也随直径周期性变化,周期约为150 nm.通过研究不同波长的泵浦光对金刚石纳米柱内部中轴线上电场分布的影响发现,不同波长的泵浦光对纳米柱内部中轴线上最强场强对应的纳米柱尺寸有较大影响,但对于纳米柱最大场强随纳米柱尺寸变化的趋势几乎没有影响.本文通过研究上述内容,较为全面地掌握了纳米柱尺寸及泵浦光对纳米柱内部电场强度的影响规律,找到了纳米柱内部中轴线上最强场强位置,确定了激发色心的效率最高值所在位置,为金刚石纳米柱单光子源的制备提供理论指导. 相似文献
146.
A convenient method has been developed for the preparation of a variety of 2-mercaptobenzothiazoles from 2-haloanilines and CS2 mediated by metal sulfide. In this reaction, 2-haloanilines reacted with CS2 in the presence of Na2S?·?9H2O to form 2-mercaptobenzothiazoles. Na2S?·?9H2O functioned both as an activator of CS2 and as a base. Furthermore, NMR analysis was used to identify the different reaction mechanisms of 2-haloanilines and CS2 mediated by Na2S or 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), which demonstrated that Na2S interacted only with CS2, while DBU reacted with both 2-iodoaniline and CS2. 相似文献
147.
<正>Nitration of 4,4'-biphenyldicarboxylic acid(BPDC) was studied and an aromatic carboxylic acid containing two nitro groups was synthesized and characterized through elemental analysis and IR spectra.Crystal structure of DNBPDC(DNBPDC=2,2'- dinitro-4,4'-biphenyldicarboxylic acid) was determined by X-ray single crystal diffraction and the thermal decomposition was carried out through DSC and TG-DTG analyses. 相似文献
148.
以柠檬酸为配位剂,溶胶-凝胶法制备Ni2V2O7,采用X射线衍射、氮气物理吸附、电感耦合等离子体原子发射光谱、氢气程序升温还原、X射线光电子能谱和透射电子显微镜等技术对催化剂进行了表征.通过差热-热重分析,考察干凝胶分解为Ni2V2O7的温度以及分解过程的热效应并研究了不同焙烧温度与Ni2V2O7的形成、晶化程度之间的关系以及对丙烷氧化脱氢(ODH)制丙烯反应催化性能的影响. 相似文献
149.
应用固载表面毛细流自组装环荧光显微成像技术,建立了Ca2+增敏米诺环素荧光体系测定牛奶中米诺环残留量的分析方法。将米诺环素溶液与一定量的氯化钙溶液,pH 8.50的氨性缓冲溶液及PVA-124溶液充分混合均匀。反应10 min后,滴在疏水性载玻片表面上,微波加热,溶剂受热挥发后,形成直径约为1.7 mm,环带宽约为45.3μm的自组装环。当点样体积为0.3μL时,线性范围为5.6×10-13~1.8×10-11mol,方法的检出限(3σ)为5.6×10-14mol。应用于米诺环素胶囊中米诺环素和牛奶中残留米诺环素的检测,回收率分别为104.3%~105.0%和96.0%~105.9%,相对标准偏差(n=5)小于3.5%。 相似文献
150.
SUN Yong-an SHEN Yue-nian JIA Mei-lin GUO Jin-ling 《高等学校化学研究》2010,(3):453-459
An Au/ceria(0.44%, mass fraction) catalyst containing gold ions was prepared by a modified deposition precipitation method, and the evolution of gold ions in the catalyst and its influence on the catalysis of CO oxidation were investigated. It was found that the as-prepared catalyst containing gold ions with high valence could fully oxidize CO at –10 °C initially but was deactivated gradually at low temperatures during the reaction with CO or treatment by unpurified air. The deactivation of the catalyst during CO oxidation or treatment of it by unpurified air was independent and progressive at low temperatures while the activity of the catalyst at relatively high temperatures was maintained well. During the reaction with CO or treatment by unpurified air, the XPS results indicate that gold species evolved from high valence to low valence and the diffuse reflectance UV-Vis spectra show that high valence gold was reduced to charged gold clusters, gold clusters grew to small gold crystals and small gold crystals grew to large gold particles. Accordingly, the high valence gold corresponded to the activity at low temperatures and the metallic gold was active and relatively stable at high temperatures. The turnover frequencies(TOF) of the catalysts treated by different methods at 273 K decreased with the evolution of gold species from high valence to low valence, no maximum of TOF was observed although gold particles in the catalyst attained to about 2―3 nm during the treatment. An Au/ceria catalyst with a gold load of 0.87% (mass fraction) maintained a good activity for CO oxidation within 18 h at room temperature. The catalysts were characterized via transmitted electronic microscopy(TEM), inductively coupled plasma optical emission spectrometry(ICP-OES), X-ray diffraction(XRD) and BET specific surface area and UV-Vis DRS as well. 相似文献