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131.
Kiumars Kaveh Christopher Manon Takuya Murata 《Journal of Pure and Applied Algebra》2021,225(11):106713
We study the generic tropical initial ideals of a positively graded Cohen-Macaulay algebra R over an algebraically closed field k. Building on work of Römer and Schmitz, we give a formula for each initial ideal, and we express the associated quasivaluations in terms of certain I-adic filtrations. As a corollary, we show that in the case that R is a domain, every initial ideal coming from the codimension 1 skeleton of the tropical variety is prime, so “generic presentations of Cohen-Macaulay domains are well-poised in codimension 1.” 相似文献
132.
Uniform and Semi-uniform Convergence for Discontinuous Skew-product Transformation and Observation 下载免费PDF全文
In this paper, for a discontinuous skew-product transformation with the integrable observation function, we obtain uniform ergodic theorem and semi-uniform ergodic theorem. The main assumptions are that discontinuity sets of transformation and observation function are ignorable in some measure-theoretical sense. The theorems extend the classical results which have been established for continuous transformations and continuous observation functions. 相似文献
133.
《Tetrahedron: Asymmetry》2014,25(1):98-101
An efficient enantioselective aza-Michael addition of pyrazole to chalcone was established. In the presence of the primary amine derived from cinchona alkaloid and acidic additive, the reactions afforded 1,4-adducts in high yields (up to 98%) with 68–88% ee. 相似文献
134.
利用多种荧光光谱法、紫外光谱法并结合分子模拟等方法,表征了模拟生理条件下一种植物药活性组分考拉维酸(KA)影响人血清白蛋白(HSA)的结构信息.同步荧光及紫外光谱证实考拉维酸的存在影响了HSA的微环境;二维及三维荧光光谱表明考拉维酸可以猝灭HSA的内源荧光,使其构象发生变化.荧光偏振的测定提供了考拉维酸与HSA作用后生成的配合物弛豫时间与聚集特性的信息,揭示KA的存在使HSA的流动性和微粘度发生变化.定量求得不同温度下(298、308和318 K)考拉维酸与HSA作用的键合参数和热力学参数.分子模拟表明考拉维酸键合位点于HSA分子的疏水腔内,并与赖氨酸Lys195和天冬氨酸Asp451形成三个氢键,与HSA的键合模式主要是疏水作用;位点竞争实验证明考拉维酸在HSA亚结构域的位点II位发生作用.另外,获得的相关物理化学参数从分子水平上揭示了考拉维酸与HSA相互作用的机制.结果表明,HSA对考拉维酸有较强的结合能力,提示人血清白蛋白对考拉维酸可起到储存和转运的作用. 相似文献
135.
136.
人体中有益元素的缺乏或有毒有害元素过量导致众多健康问题,微量元素在医学地质研究中占有举足轻重的作用。随着医学地质研究的不断深入和新技术的快速发展,微量元素的研究领域和研究程度也不断扩大和深入,该文综述了微量元素在医学地质中的主要研究内容,研究方法及风险评价,指出了微量元素研究的薄弱环节及其发展趋势,以期推动进一步研究。 相似文献
137.
The mechanism and dynamical properties for the reaction of NCS and OH radicals have been investigated theoretically. The minimum energy paths (MEP) of the reaction were calculated using the density functional theory(DFT) at the B3LYP/6-311 G^** level, and the energies along the MEP were further refined at the QCISD(T)/6-311 G^** level. As a result, the reaction mechanism of the title reaction involves three channels, producing HCS NO and HNC SO products, respectively. Path Ⅰ and path Ⅱ are competitive, with some advantages for path Ⅰ in kinetics. As for path Ⅲ, it looks difficult to react for its high energy barrier. Moreover, the rate constant have been calculated over the temperature range of 8190-2500K using canonical variational transition-state theory (CVT). It was found that the rate constants for both path Ⅰ and path Ⅱ are negatively dependent on temperature, which is similarwith the experimental results for reactions of NCS with NO and NO2, and the variational effect for the rate constant calculation olavs an important role in whole temperature range. 相似文献
138.
1992年Brualdi与Jung首次引出了最大跳跃数M(n,k),即每行每列均含k个1的阶为n的(0,1)-矩阵的跳跃数的极大数,给出了满足条件1≤k ≤n ≤10的(0,1)-矩阵的最大跳跃数M(n,k)的一个表,并提出了几个猜想,其中包括猜想M(2k-2,k)=3k-4 [k-2/2].本文证明了当k≥11时,对每个A∈∧(2k-2,k)有b(A)≥4.还得到了该猜想的另一个反例. 相似文献
139.
Xue-Ming Zhou Cai-Juan Zheng Xiao-Ping Song Yu-Hua Cao A-Qian Huang 《Natural product research》2016,30(21):2429-2433
A new phenolic glycoside derivative, saproglucoside (1), along with five known phenolic glycoside derivatives (2–6) were isolated from the stems of Saprosma merrillii. The structure of the new compound 1 was determined by 1D and 2D NMR as well as by HRESIMS and hydrolysis. The inhibitory activities of all compounds against seven pathogenic bacteria and two cancer cell lines were evaluated. 相似文献
140.