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411.
合成了晶态层状有机-无机多功能材料苯乙烯基膦酸-磷酸氢锆(α-ZPPVPA),并研究了正丁胺(BA)对α-ZPPVPA的插层性能。用元素分析、XRD、IR、TG、SEM和TEM等分析方法对α-ZPPVPA及其插层化合物α-ZPPVPA-BA进行了结构表征和形貌分析。结果表明,正丁胺成功地插入了α-ZPPVPA层板之间,层间距为2.41 nm,正丁胺的插入使α-ZPPVPA的层间距(1.66 nm)增大了0.75 nm,插入的正丁胺在α-ZPPVPA中呈双分子层排列,且苯乙烯基侧链不饱和双键的存在不影响α-ZPPVPA与正丁胺的插层反应。  相似文献   
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本文使用基于微扰理论的代数方法(AM),研究了碱金属Na_2分子的X~1∑_g~+、6~1∑_g~+、1~3Δ_g、2~3Δ_g、1~3∑_g~-、A~1∑_u~+、7~3Δ_g等七个电子态的离解能;然后使用最近提出的新公式计算了这些电子态的离解能,并分别与离解能的实验值进行了对比.结果表明:使用新公式得到的分子离解能与实验值更为接近.对于那些用实验方法还难以获得其离解能的电子态,该式提供了一种获得其离解能的新方法.  相似文献   
414.
The analysis of the functioning of the brain allows to propose a computational model of multilayer artificial neural network susceptible of associating some response to a particular input, so that when we present that input, we get the required output by the stability of its states and by minimizing the function of energy of the network. The problem of explosion in the number of interconnections has been solved by the introduction of a layer between the input and the output layer of the network. In this paper, we propose the adaptive bidirectional associative memory by conjugate gradient algorithm, so as to study the behavior and performances of the network on pairs of patterns through using the autoassociative or heteroassociative memories.  相似文献   
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Analytical modelling, controller design and simulation of an air-to-air runaround coil heat recovery system are studied. The system consists of two plate-fin-tube coils, a storage tank, two circulating pumps, an auxiliary heater and associated distribution network. Simulation results showing the transient response characteristics of the open-loop and closed-loop system are given. Results show that the designed controllers are able to hold the preheat temperature and the storage tank temperature at their respective setpoints irrespective of changes in outdoor and exhaust (source heat) temperatures.  相似文献   
417.
Infrared spectra of peroxyformic acid (HCOOOH) and the six isotopic modifications H13COOOH, HC18OOOH, DCOOOH, HCOOOD, H13COOOD, DCOOOD have been recorded in an argon matrix in the spectral range 200–4000 cm−1. Assignments of the observed absorption lines are presented for the available isotopic species. All fundamental vibrations except one have been identified. A general valence force field has been determined based on the measured vibrational frequencies and on an ab initio MP2/6-31G** force field.  相似文献   
418.
《中国化学快报》2023,34(3):107555
Recent studies have proposed that the high-valent iron species (such as FeIVO2+) rather than sulfate radical (SO4??) and hydroxyl radical (?OH) are the main reactive oxidant species (ROS) in Fe(II)/peroxydisulfate (PDS) system with the methyl phenyl sulfoxide (PMSO) as the FeIVO2+ probe. However, many operational factors may interfere with the accuracy of this method, so the contribution of FeIVO2+ calculated by this method is controversial. In this study, the possible effect of Fe(II) concentration, pollutant type, reducing agent, or coexisted anions on FeIVO2+ production and its corresponding contribution to the removal of target pollutants in the Fe(II)/PDS system were investigated in detail, and the intrinsic mechanisms involved were also explored. This study shows that ROS generation is a complex process in the Fe(II)/PDS system, and multiple combinatorial approaches are urgently required to deeply explore the contribution of ROS to the elimination of target contaminants.  相似文献   
419.
《中国化学快报》2023,34(11):108381
Electrophilic aromatic substitution (EAS) is a critical chemical reaction in organic chemistry in which electrophiles reagents is normally required. Recently, a study published by Yaping Zang and colleagues in Nature Communications demonstrates the use of an electric field as a catalyst to regulate EAS reactivity, replacing conventional chemical reagents. The research team discovered that an electric field could activate an otherwise unreactive electrophile and break inert nonpolar C-C bonds under mild conditions. These unprecedented results showcase the potential for broadening the scope of EAS reactions via electric field catalysis.
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420.
本文研究R3中一类九体中心构型,该构型由两个正四面体及几何中心带一个质量构成.利用中心构型等价类的性质及分析方法,得到了该构型构成中心构型的充分和必要条件,并且证明了对任意给定的质量比这类中心构型存在且唯一,推广了文献[16]的结论.  相似文献   
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