| 正丁胺对晶态层状苯乙烯基膦酸-磷酸氢锆的插层研究 |
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| 引用本文： | 张怀志,傅相锴,王长炜,罗云飞,贾紫永.正丁胺对晶态层状苯乙烯基膦酸-磷酸氢锆的插层研究[J].无机化学学报,2011,27(5):872-876. |
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| 作者姓名： | 张怀志 傅相锴 王长炜 罗云飞 贾紫永 |
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| 作者单位： | 西南大学化学化工学院,重庆市应用化学市级重点实验室,三峡库区生态环境教育部重点实验室,重庆,400715 |
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| 基金项目： | 国家科技部科技中小型企业技术创新基金(No.09C26215112399); 国家人力资源和社会保障部留学人员回国创业启动支持计划(人社厅发2009(143号))资助项目 |
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| 摘 要： | 合成了晶态层状有机-无机多功能材料苯乙烯基膦酸-磷酸氢锆(α-ZPPVPA),并研究了正丁胺(BA)对α-ZPPVPA的插层性能。用元素分析、XRD、IR、TG、SEM和TEM等分析方法对α-ZPPVPA及其插层化合物α-ZPPVPA-BA进行了结构表征和形貌分析。结果表明,正丁胺成功地插入了α-ZPPVPA层板之间,层间距为2.41 nm,正丁胺的插入使α-ZPPVPA的层间距(1.66 nm)增大了0.75 nm,插入的正丁胺在α-ZPPVPA中呈双分子层排列,且苯乙烯基侧链不饱和双键的存在不影响α-ZPPVPA与正丁胺的插层反应。
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| 关 键 词： | 苯乙烯基膦酸-磷酸氢锆 层状化合物 插层 正丁胺 |
Intercalation of n-Butylamine into Layered Crystalline Zirconium Phenylvinylphosphonate-Phosphate |
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| ZHANG Huai-Zhi,FU Xiang-Kai,WANG Chang-Wei,LUO Yun-Fei and JIA Zi-Yong.Intercalation of n-Butylamine into Layered Crystalline Zirconium Phenylvinylphosphonate-Phosphate[J].Chinese Journal of Inorganic Chemistry,2011,27(5):872-876. |
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| Authors: | ZHANG Huai-Zhi FU Xiang-Kai WANG Chang-Wei LUO Yun-Fei and JIA Zi-Yong |
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| Institution: | College of Chemistry and Chemical Engineering, Southwest University, Key Laboratory of Applied Chemistry of Chongqing Municipality, Key Laboratory of the Three Gorges Reservoir Regions Eco-Environment, Ministry of Education, Chongqing 400715,China,College of Chemistry and Chemical Engineering, Southwest University, Key Laboratory of Applied Chemistry of Chongqing Municipality, Key Laboratory of the Three Gorges Reservoir Regions Eco-Environment, Ministry of Education, Chongqing 400715,China,College of Chemistry and Chemical Engineering, Southwest University, Key Laboratory of Applied Chemistry of Chongqing Municipality, Key Laboratory of the Three Gorges Reservoir Regions Eco-Environment, Ministry of Education, Chongqing 400715,China,College of Chemistry and Chemical Engineering, Southwest University, Key Laboratory of Applied Chemistry of Chongqing Municipality, Key Laboratory of the Three Gorges Reservoir Regions Eco-Environment, Ministry of Education, Chongqing 400715,China and College of Chemistry and Chemical Engineering, Southwest University, Key Laboratory of Applied Chemistry of Chongqing Municipality, Key Laboratory of the Three Gorges Reservoir Regions Eco-Environment, Ministry of Education, Chongqing 400715,China |
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| Abstract: | Layered crystalline zirconium phenylvinylphosphonate-phosphate(α-ZPPVPA) was synthesized as organic-inorganic multifunctional material.The intercalation complex of n-butylamine(BA) into α-ZPPVPA was studied.α-ZPPVPA and its intercalation complex α-ZPPVPA-BA were characterized by elemental analysis,XRD,IR,TG,SEM and TEM.The results indicated that n-butylamines were successfully intercalated into α-ZPPVPA interlayer and the interlayer distance of α-ZPPVPA-BA was 0.75 nm larger than that of α-ZPPVPA(1.66 nm).The n-butylamines,which intercalated into α-ZPPVPA,formed bi-molecule layer.The existence of unsaturated double bonds has no influence on the intercalation reaction of n-butylamine into α-ZPPVPA |
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| Keywords: | zirconium phenylvinylphosphonate-phosphate layered compound intercalation n-butylamine |
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