Efficient Fluorescent Recognition of Carboxylates in Aqueous Media Using Facilely Electrosynthesized Poly(9-Aminofluorene)

A variety of carboxylates were recognized using poly(9-aminofluorene) (P9AF) in the HEPES buffer (pH 7.4), and a proposed possible mechanism was proposed as following. The intermolecular hydrogen bonding interactions resulted in electron transfer between P9AF and carboxylates. P9AF was facilely electrosynthesized in boron trifluoride diethyl etherate and could be used as an efficient fluorescent sensing material for the detection of AcO^?. On binding to AcO^?, fluorescence quenching of P9AF was demonstrated by a maximum 80 % reduction in the fluorescence intensity, while no obvious fluorescence change could be observed in the presence of some other common anions. Some different carboxylates could be recognized at different levels by P9AF. Substituent groups in carboxylates could affect the intermolecular interaction between carboxylates and P9AF. These could be explained by a possible mechanism that hydrogen bonding was the main way of intermolecular interactions between P9AF and carboxylates, which was further confirmed by absorption spectra monitoring and density functional calculations. The significant advantage of this strategy is that it does not require a prequenching procedure and the polymer can be used directly for analyte detection.     

Single-machine common due window assignment and scheduling to minimize the total cost

In this paper we consider a single-machine common due window assignment and scheduling problem with batch delivery cost. The starting time and size of the due window are decision variables. Finished jobs are delivered in batches. There is no capacity limit on each delivery batch, and the cost per batch delivery is fixed and independent of the number of jobs in the batch. The objective is to find a job sequence, a delivery date for each job, and a starting time and a size for the due window that jointly minimize the total cost comprising earliness, weighted number of tardy jobs, job holding, due window starting time and size, and batch delivery. We provide some properties of the optimal solution and present polynomial-time algorithms for the problem.     

EXISTENCE OF POSITIVE SOLUTIONS TO SUBLINEAR SECOND-ORDER PERIODIC BOUNDARY VALUE PROBLEM

In this paper, we consider a second-order periodic boundary value problem. By the topological degree theory and fixed point index theory, we prove the existence of positive solutions which gives the relationship between the first positive eigenvalue of the associated eigenvalue problem and the behavior of the nonlinear term of the system.     

关于L2(Rd)中仿射子空间小波标架的一个注记

研究了L2(Rd)的有限生成仿射子空间中小波标架的构造.证明了任意有限生成仿射子空间都容许一个具有有限多个生成元的Parseval小波标架,并且得到了仿射子空间是约化子空间的一个充分条件.对其傅里叶变换是一个特征函数的单个函数生成的仿射子空间,得到了与小波标架构造相关的投影算子在傅里叶域上的明确表达式,同时也给出了一些例子.     

Ionoluminescence in the presence of ionizing radiation

An increase in the ionoluminescence intensity from a ZnS-CdS:Ag sample by a factor of more than 20 upon additional electronic excitation by UV light has been found. The effect decreases in magnitude with an increase in the energy of bombarding H₂⁺ ions and peaks at an energy below 175 eV. This effect manifests itself in samples having a system of shallow electron traps and is due to the relaxation of highly excited anharmonic atomic vibrations, caused by the ion impact, through the electronic channel. A mechanism is proposed and computed for the phenomenon revealed.     

An extension of the mean free path approach to X-ray absorption spectroscopy

In the partial electron yield (PEY) acquisition mode commonly used in X-ray absorption spectroscopy (XAS) both elastically and inelastically scattered electrons are acquired, the latter contribution dominating the detector signal. Hence, the majority of the inelastic scattering events will not result in signal attenuation as happens in the case of X-ray photoelectron spectroscopy (XPS). To determine the respective changes in the effective mean free paths (MFP) we have performed XPS and near edge X-ray absorption fine structure (NEXAFS) spectroscopy measurements for a series of self-assembled monolayers of alkanethiols on gold substrates. The length of the alkyl chain and, therefore, the film thickness was varied. In agreement with expectations, the obtained MFPs for the Au 4f photoelectrons and C_KLL Auger electrons in the PEY acquisition mode (with the respective inelastic contributions) exceed the corresponding values for the Au 4f and C_KLL electrons of the same kinetic energies in the constant final state acquisition mode. Furthermore, the effective PEY-MFP for the C_KLL Auger electrons increased with decreasing retarding voltage of the PEY detector, which correlates with the enhanced contribution of the inelastically scattered electrons in the acquired signal. The results obtained are of importance for the analysis of XAS spectra of thin organic films and polymers.     

Multiple microflame quartz tube atomizer — further development towards the ideal hydride atomizer for atomic absorption spectrometry

The development of an improved type of hydride atomizer for atomic absorption spectrometry — multiple microflame quartz tube atomizer (MMQTA) — is presented. The main feature of this atomizer is recurrent analyte atomization proceeding over its whole optical tube length, which is achieved by production of H-radicals at multiple points within the tube by oxygen microflames burning in the hydrogen-containing atmosphere. The MMQTA design optimization leading to a complete filling of the observation volume with H-radicals is described. The influence of individual atomization parameters is discussed. Optimum H-radical producing oxygen intake into the MMQTA was found to correspond to a H₂:O₂ stoichiometric (3:1) ratio. The performance of the individual MMQTA tube designs is evaluated and compared to a typical externally heated quartz tube atomizer (EHQTA) — the linearity of calibration graphs for As, Se and Sb is significantly improved in all MMQTA tubes, without compromising the sensitivity, simplicity, low cost and easy operation. In fact, the free atom reactions within the tube causing calibration curvature are avoided up to an analyte concentration of at least 200 ng ml⁻¹ for Se and Sb and 100 ng ml⁻¹ for As. Tolerance limits of 0.7, 1.4, 0.2 and 0.2 μg ml⁻¹ are achieved for the atomization interferences of As on Se, Se on As, Sb on Se and Se on Sb, respectively, which is an improvement by 1–2 orders of magnitude in comparison to the conventional EHQTA with the same hydride generation system.     

Analysis of transient response of saturated porous elastic soil under cyclic loading using element-free Galerkin method

A two-dimensional numerical procedure is presented to analyse the transient response of saturated porous elastic soil layer under cyclic loading. The procedure is based on the element-free Galerkin method and incorporated into the periodic conditions (temporal and spatial periodicity). Its shape function is constructed by moving least-square approximants, essential boundary conditions are implemented through Lagrange multipliers and the periodic conditions are implemented through a revised variational formulation. Time domain is discretized through the Crank–Nicolson scheme. Analytical solutions are developed to assess the effectiveness and accuracy of the current procedure in one and two dimensions. For only temporal periodic problems, a one-dimensional transient problem of finite thickness soil layer is analysed for sinusoidal surface loading. For both temporal and spatial periodic problems, a typical two-dimensional wave-induced transient problem with the seabed of finite thickness is analysed. Finally, a moving boundary problem is analysed. It is found that the current procedure is simple, efficient and accurate in predicting the response of soil layer under cyclic loading.     

Novel multi-responsive fluorescence switch for Hg2+ and UV/vis lights based on diarylethene-rhodamine derivative

A new multi-responsive fluorescent switch DTE-Pip-Rho 1O has been designed and synthesized in this study. For this molecule, the reactive site of spirolactam ring is far away from the diarylethene unit through the intramolecular piperazine. It exhibited high selectivity and sensitivity to Hg²⁺ in addition to obvious color change (colorless-pink) and fluorescence “off-on” (dark-orange) during this process. It is believed that the color change is due to Hg²⁺-assisted hydrolysis of rhodamine hydrazide. Therefore, the new molecule can be used as colorimentric and fluorescent chemosensor for Hg²⁺ with high selectivity. The detection limits of absorbance and fluorescence for Hg²⁺ were calculated to be 1.15?μM and 1.16?μM, respectively. The resulting DTE-Pip-Rho 1O-Hg²⁺ could also function as a reversible fluorescence photo-switch in response to UV/vis light owing to FRET mechanism. Moreover, it has been demonstrated that the photo-switchable system displayed excellent fatigue resistance and remarkable anti-photobleaching capability.