溶胶凝胶法固定抗体制备黄曲霉毒素免疫传感器

利用溶胶凝胶法,将正硅酸乙酯在HCl存在下水解形成的硅溶胶和黄曲霉毒素B1抗体的混合液涂于玻碳电极表面,制备非标记型电化学阻抗免疫传感器。以[Fe(CN)6]3-/4-的磷酸盐缓冲溶液为测试底液,分别研究传感器的循环伏安和交流阻抗行为。实验表明,电极因免疫反应所形成的复合物阻碍了[Fe(CN)6]3-/4-在电极表面的扩散,其氧化还原峰电流明显减小,电子转移阻抗随黄曲霉毒素浓度增加而线性增大。当介质pH=6.5和孵育时间为20 min时,免疫前后传感器的电子转移阻抗变化值最大。在此最佳条件下,传感器电子转移阻抗对黄曲霉毒素响应的线性范围为1.0～10μg/L;检出限为0.1μg/L(S/N=3)。此方法具有高的灵敏度和稳定性,可应用于食品中黄曲霉毒素的测定。     

魔芋总生物碱量的测定

用酸性染料比色法测定魔芋总生物碱量,以盐酸金刚烷胺计,在2—10μg/mL范围内线性关系良好。设计正交试验选择总生物碱的最佳提取条件为：料液比1：12,乙醇浓度85%,索氏提取4h。     

咖酚伪麻片中盐酸伪麻黄碱的含量

建立高效液相色谱法测定咖酚伪麻片中盐酸伪麻黄碱含量的方法。色谱柱为C18（150mm×4.6mm×5μm）,流动相为0.05mol/L磷酸二氢钠-甲醇（75∶25）,流速为1mL/min,检测波长为210nm。盐酸伪麻黄碱在0.2155—1.0776μg/g范围内线性良好,r=0.9999;盐酸伪麻黄碱的平均收率为100.92%,RSD值为0.41%（n=5）。此法操作简单,准确性好,可用于咖酚伪麻片中盐酸伪麻黄碱的含量测定。     

直读光谱法测定不锈钢中铬的不确定度评定

利用光电直读光谱仪测定不锈钢中铬含量,对其在测量过程中不确定度产生的原因进行了分析,并对测量结果的不确定度进行了评定。     

New scintillators based on barium fluoride crystals and ceramics

Experimental studies on the optical properties of new crystals and ceramics based on CeF₃- and CdF₂-doped barium fluoride were aimed at producing scintillators with a higher light yield level (particularly in the ultra-short wavelength range with a luminescence time of 0.6–0.8 ns) that could be used in the development of fast and low-cost optical sensors for positron emission tomography (PET). Ceramics manufactured on the basis of BaF₂ single crystals with various concentrations of Ce and Cd are transparent in the 300–600 nm wavelength range; this is comparable to BaF₂ single crystals.     

风速对空气源热泵翅片管换热器结霜特性影响

针对风速对空气源热泵翅片管室外换热器结霜特性的影响进行了实验研究.实验结果表明,结霜量随风速的增加不是成线形增长,在风速为1.3m/s时结霜量最小.霜层厚度随着风速的增加反而减小,而翅片管换热器的最大换热量随着风速的增加而增加.     

Synthesis of Nanosized Silicon Carbide Through Non-Transferred Arc Thermal Plasma

A thermal plasma system was used for the preparation of nanosized SiC powder. First SiC was synthesized by solid-state reaction using waste silicon and activated carbon powders and then plasma processing was carried out to form nanosized SiC. Phase and structural analysis was carried out by X-ray diffraction which confirmed the formation of SiC in both cases. Plasma treatment did not show any kind of change in structure and phase of SiC; except little free silicon. Morphological investigation showed the formation of 20–30 nm spherical SiC particles after plasma treatment which was initially 1–5 μm. It was found that DC current played an important role in the reduction of particle size. It was proposed that nanosized SiC was formed due to the dissociation of grains from their grain boundary due to strong plasma gas stream.     

用硫化助熔剂法合成红外上转换材料的研究

本文采用一种优化的硫化助熔剂方法合成了红外上转换材料,这种材料能够在室温下将红外光转换成可见光。这种新工艺在反应效率、生产成本、环境保护、工艺难度等方面均优于传统的热熔工艺。文章给出了红外上转换材料的激励光谱和发射光谱。     

How to deal with potentially huge dimensional state space: The meta-dynamics approach—application to a model of the co-evolution of bacterio-phage populations

In many problems coming from the “complexity sciences”, the presence of high-dimensional state spaces and non-linear equations renders traditional mathematical objects useless. To deal with these issues, several approaches have recently been studied, most of them presenting the particularity of splitting the dynamical events in two categories; an upper level in which the events describe how the structure of the system changes (the meta-dynamics) and a lower level with the events describing the evolution of the elements in the structure (the dynamics). The state space is then not defined in extenso but unfolds or contracts during the evolution of the system. In term of simulation, this view allows us to deal with only a small part of the state space at each step avoiding the time and memory limitations.     

Acoustic damping characterization and microstructure evolution in nickel-based superalloy during creep

We studied the microstructure evolution of a nickel-based superalloy, Waspaloy, subjected to tensile creep at 1073 K through monitoring of shear-wave attenuation and velocity using electromagnetic acoustic resonance (EMAR). Contactless transduction based on the Lorentz force mechanism is the key to establishing a monitor for microstructural change in the bulk of the metals with a high sensitivity. There is a clear relationship between the attenuation and the life fraction. In the interval, 35 to 40% of the creep life, attenuation experiences a peak, being independent of the applied stress. This novel phenomenon is interpreted in terms of drastic change in dislocation mobility and the coarsening of γ′-precipitates, which is supported by SEM and TEM observations. At this period, dense dislocations start tangling to γ′-precipitates and the coarsening and condensation of γ′-precipitates become saturated. The EMAR has a potential to assess the damage advance and to predict the remaining creep life of metals.