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941.
表面修饰DBS基团对TiO2气相光催化性能的影响 总被引:1,自引:1,他引:1
采用溶胶-水热法直接获得表面修饰十二烷基苯磺酸钠(DBS)分子基团的TiO2纳米粒子, 并考察了DBS表面修饰对纳米TiO2光催化氧化降解气相n-C5H12反应的活性和寿命的影响, 并利用表面光电压(SPS)谱和光致发光(PL)光谱等方法研究了DBS表面修饰的影响机制. 结果表明, 表面修饰DBS分子基团能够抑制TiO2纳米微晶生长, 促进纳米TiO2分散, 增强吸附性和提高光生电荷分离, 使光催化活性显著提高. 但寿命并未下降, 这与TiO2和DBS基团的光稳定性有关. 动力学研究结果表明, TiO2光催化氧化n-C5H12反应遵循Langmuir-Hinshelwood动力学模型, 为准一级反应. 相似文献
942.
《Spectrochimica Acta Part B: Atomic Spectroscopy》2005,60(1):13-26
This paper reviews a range of instrumental microanalytical techniques for their potential in following the development of nanotechnology. Needs for development in secondary ion mass spectrometry (SIMS), transmission electron microscopy (TEM), Auger emission spectrometry (AES) laser mass spectrometry, X-ray photon spectroscopy are discussed as well as synchrotron-based methods for analysis. Objectives for development in all these areas for the coming 5 years are defined. Developments of instrumentation in three European synchrotron installations are given as examples of ongoing development in this field. 相似文献
943.
新型固载化螯合钛酸酯催化合成高沸点酯的研究 总被引:9,自引:0,他引:9
新型固载化螯合钛酸酯催化合成高沸点酯的研究1)刘继红王春凤车丕智邢伯军孔祥球(哈尔滨师范大学化学系哈尔滨150080)关键词固载化螯合钛酸酯催化剂高沸点酯酯化反应分类号O643.32目前,固载化催化剂以其独特的功能日益受到人们的重视.均相催化剂的高分... 相似文献
944.
The novel coordination polymer {[Cd(p-CMSP)(Him)(H2O)]·3H2O}n (
p-CMSP2-=p-(carboxymethoxy)phenylthioacetate, Him=imidazole) was synthesized by the reaction of
Cd(NO3)2, imidazole and p-(carboxymethoxy)phenylthioacetic acid in an aqueous solution, and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. The crystal structure is of monoclinic, space group
P21/c with a=1.144 0(2) nm, b=1.876 7(4) nm, c=0.877 89(18) nm, β=106.31(3)° and V=1.808 9(7)
nm3, Z=4, R=0.023 2, wR=0.051 4. Each Cd(II) atom displays a distorted octahedral coordination geometry, defined by three carboxyl O atoms from different
p-CMSP2- ligands, one S atom from thioether, one N atom from imidazole and one water molecule. Adjacent Cd(II) ions are bridged by
p-CMSP2- groups, resulting in a 2D layer structure. The adjacent Cd…Cd distances are 0.492 7 nm and 1.144 0 nm. Furthermore, such layers are linked through hydrogen bonds to form supramolecular network. CCDC: 269474. 相似文献
945.
《Tetrahedron: Asymmetry》2006,17(18):2672-2677
Starting from one stereogenic center (in this case from l-serine), we obtained two chiral Schiff bases possessing oxazoline moieties, each of which recognized a different enantioface of aldehydes with a high enantiomeric excess [up to 93% ee (R) and 89% ee (S)] in the addition reaction of diketene to 2-furfural. 相似文献
946.
在不同介质(依次为甲醇、乙醇、正丙醇、正丁醇)中合成了邻苯二甲酸Tb3+稀土二元配合物. 利用元素分析和红外光谱分析等对配合物的组成和结构进行了表征. 荧光光谱结果表明, 直链醇作为合成介质时配合物的荧光强度大小顺序依次为: 甲醇>乙醇>正丙醇>正丁醇. 同时该配合物在2~300 K范围内测定的变温磁化率说明该配合物具有反铁磁性. 相似文献
947.
The behavior of benzene produced during the fixed-temperature reaction and the temperature-programmed surface reaction of
methane under non-oxidation aromatization over Mo/HZSM-5 catalyst was monitored in real-time by the resonance-enhanced 2-photon
ionization technique. A new phenomenon of benzene formation in the induction period is found to correspond to the migration
of the molybdenum species in the catalyst.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
948.
Yongchen Shang Wenxiang Zhang Mingjun Jia Piaoping Yang Dazhen Jiang Tonghao Wu 《Reaction Kinetics and Catalysis Letters》2005,85(2):245-251
Summary Modification of HMCM-22 zeolite with tetraethoxysilane (TEOS) can considerably improve the catalytic performances, especially the selectivity to isobutene, for the reaction of n-butene skeletal isomerization. 相似文献
949.
用丙酮和四氢呋喃混合溶液对Pt-WO3/C电极进行表面活化处理后, 乙二醇在Pt-WO3/C电极上的电催化氧化活性大幅度提高. 发现无论在中性溶液中还是在酸性溶液中, 表面活化处理后的Pt-WO3/C电极, 乙二醇的起始氧化电位负移, 氧化峰电流在酸性介质中增加到表面活化处理前的3.2倍; 中性介质中增加到表面处理前的4.7倍, 其主要原因是表面活化处理后, 一方面增加了催化剂Pt的活性表面, 另一方面也促进了电极表面吸附的CO的电氧化, 减少了CO对电极表面的毒化作用. 相似文献
950.
《Electrochemistry communications》2007,9(5):1107-1112
Structural and electronic properties of Li4Ti5O12 spinel are studied from density functional theory based first principles calculations. Differences on these properties between delithiated state Li4Ti5O12 and lithiated state Li7Ti5O12 are compared. The optimized lattice constant of Li4Ti5O12 is 8.619 Å, which is even a little larger (0.2%) than 8.604 Å of the lithiated state Li7Ti5O12. The arrangement of the Li and Ti atoms at the 16d sites of the spinel structure is also investigated in a cubic unit cell. Large 1 × 1 × 3 supercell models are constructed and used to calculate the total energy and electronic structure. The average intercalation potential is also calculated, with metallic lithium as reference. 相似文献