Synthesis, structure and optical properties of Eu/TiO2 nanocrystals at room temperature

The nanocrystal samples of titanium dioxide doped with europium ion (Eu³⁺/TiO₂ nanocrystal) are synthesized by the sol-gel method with hydrothermal treatment. The Eu³⁺ contents (molar ratio) in the samples are 0, 0.5%, 1%, 2%, 3% and 4%. The X-ray diffraction, UV-Vis spectroscopy data and scanning electron microscope image show that crystallite size is reduced by the doping of Eu³⁺ into TiO₂. Comparing the Raman spectra of TiO₂ with Eu³⁺/TiO₂ (molar ratio Eu³⁺/TiO₂=1%, 2% and 4%) nanocrystals at different annealing temperatures indicates that the anatase-to-rutile phase transformation temperatures of Eu³⁺/TiO₂ nanocrystals are higher than that of TiO₂. This is due to the formation of Eu-O-Ti bonds on the surface of the TiO₂ crystallite, as characterized by the X-ray photoelectron spectroscopy. The photoluminescence spectra of TiO₂ in Eu³⁺/TiO₂ nanocrystals are interpreted by the surface self-trapped and defect-trapped exciton relaxation. The photoluminescence of Eu³⁺ in Eu³⁺/TiO₂ nanocrystals has the strongest emission intensity at 2% of Eu³⁺ concentration.     

Synchronization of complex dynamical networks with time delays

In the present paper, two kinds of dynamical complex networks are considered. The first is that elements of every node have different time delays but all nodes in such networks have the same time-delay vector. The second is that different nodes have different time-delay vectors, and the elements of each node also have different time delays. Corresponding synchronization theorems are established. Numerical examples show the efficiency of the derived theorems.     

S[a,b]类中边界Nevanlinna-Pick插值(Ⅱ)

继续作者最近的研究,用所谓的Hankel向量方法建立S[a,b]函数类中带边界插值数据的Nevanlinna-Pick插值问题与[a,b]上的某种带约束条件的Hausdorff矩量问题之间解集之间明确的一一对应关系.通过N[a,b]函数类与S[a,b]函数类之间的联系,从而由BNP(N[a,b])问题的可解性准则和解的参数化描述获得BNP(S[a,b)问题的可解性准则和解的参数化表示.     

Second order parabolic equations in Banach spaces with dynamic boundary conditions

In this paper, we exhibit a unified treatment of the mixed initial boundary value problem for second order (in time) parabolic linear differential equations in Banach spaces, whose boundary conditions are of a dynamical nature. Results regarding existence, uniqueness, continuous dependence (on initial data) and regularity of classical and strict solutions are established. Moreover, several examples are given as samples for possible applications.

     

CONSTRUCTIONS OF POWER BASES OF CYCLOTOMIC FIELDS

Suppose Q(ζ_m) is the m-th cyclotomic number field, where ζ_m is an m-th primitive root of unity, m>1 any integer. Let a_m=ζ_m+ζ_m~2+...+ζ_m~((m-1)/2) if m is odd and let β_m be the product of the integersl-ζ_m(1相似文献   

A simple and accurate method for analysis of dielectric periodic structures

A simple and accurate approach for analysis of dielectric periodic structures is proposed in this paper. The method combines the coupled-mode theory with Floquet theory and joins the eigenmode expansion with the space harmonic expansion properly. As a result, the whole analysis procedure is significantly simplifid. Numerical results for the filter characteristics of some dielectric periodic structures show that the present method is effective, accurate and useful.Supported by The National Natural Science Foundation of China and The Foundation of State Educational Commission.     

Lower-dimensional linear complementarity problem approaches to the solution of a bi-obstacle problem

A globally convergent Broyden-like method for solving a bi-obstacle problem is proposed based on its equivalent lower-dimensional linear complementarity problem. A suitable line search technique is introduced here. The global and superlinear convergence of the method is verified under appropriate assumptions.     

Electrochemical oxidation of tetramethoxy precursor as a key step for the synthesis of coenzyme Q10

The feasibility of electrosynthesis of coenzyme Q₁₀ (1) by electrooxidation of tetramethoxy precursor (2) has been investigated at carbon, Pt and BDD anodes in a divided cell. The process strongly depends on the applied potential, anode material and water content of the solvent. At carbon anodes in CH₃CN/CH₂Cl₂ + 0.15 M Bu₄NBF₄ at proper operative conditions high faradic efficiency (>60%) and excellent selectivity (95–97%) of the target product were obtained.     

Analysis of dispersion characteristics of groove guides with mode-matching method

Groove guide is widely recognized as one of the most promising millimeter wave transmission structures. In this paper, the mode-matching method is used to analyse the dispersion characteristics of single and asymmetrical double groove guides, and the unified formulae of Nth-order approximation dispersion equations are presented. Based on this analysis, a general program for calculating the dispersion characteristrics of single and asymmetrical double groove guides has been completed. Some comparisons between the results obtained by present method and published data show that very good agreement has been seen. The effectiveness and the reliability of the given formulae and program are thus verified.     

极值图论与度序列

本文简要概述极值图论与度序列的最新研究进展，同时提出了一些有待进一步解决的问题和猜想．