沉积温度对Cu2O薄膜生长过程及光电性能的影响

以硫酸铜为铜源,采用一步化学浴沉积法制备出了晶粒尺寸可调的纳米晶Cu₂O薄膜。通过X射线衍射、扫描电镜和紫外可见分光光度法研究了沉积温度对薄膜晶体结构、成核密度、晶粒尺寸、薄膜厚度和光电性能的影响。结果表明,当在60~90℃范围内调节温度时,能够很好地控制晶粒尺寸、薄膜厚度,并将禁带宽度控制在33~51nm、392~556nm和2.47~2.61eV范围内;随着晶粒尺寸的减小,紫外可见光谱的吸收边有明显的蓝移。此外还对薄膜的生长过程,成核密度和颗粒尺寸变化的机理进行了讨论。     

Can chunking reduce syntactic complexity of natural languages?

Natural language is a complex adaptive system with multiple levels. The hierarchical structure may have much to do with the complexity of language. Dependency Distance has been invoked to explain various linguistic patterns regarding syntactic complexity. However, little attention has been paid to how the structural properties of language to minimize dependency distance. This article computationally simulates several chunked artificial languages, and shows, through comparison with Mandarin Chinese, that chunking may significantly reduce mean dependency distance of linear sequences. These results suggest that language may have evolved the mechanism of dynamic chunking to reduce the complexity for the sake of efficient communication. © 2016 Wiley Periodicals, Inc. Complexity 21: 33–41, 2016     

电荷耦合效应对高耐压沟槽栅极超势垒整流器击穿电压的影响

通过沟槽结构和可调节的电子势垒,沟槽栅极超势垒整流器可以更为有效地实现通态压降和反向漏电流之间的良好折衷.在高压应用时,电荷耦合效应对于提高该器件的反向承压能力起到了关键作用.本文通过理论模型与器件模拟结果,分析了沟槽深度、栅氧厚度和台面宽度等关键参数对电荷耦合作用下二维电场分布的影响,归纳出了提高该器件击穿电压的思路与方法,为器件设计提供了有意义的指导.在此基础上,提出了阶梯栅氧结构,该结构在维持几乎相同击穿电压的同时,使正向导通压降降低51.49%.     

Ab initio/DFT electronic structure calculations,spectroscopic studies of 5-bromo-2-pyridinecarbonitrile – A comparative study

Fourier transform infrared (FTIR) and FT-Raman spectra have been recorded and extensive spectroscopic investigations have been carried out on 5-bromo-2-pyridinecarbonitrile (5B2PC). The optimized geometries, wavenumber and intensity of the vibrational bands of (5B2PC) have been calculated using density functional level of theory (DFT/B3LYP) employing 6-311G(d,p) basis set. On the basis of the comparison between calculated and experimental results, assignments of the fundamental vibrational modes are examined. The molecular stability and bond strength were investigated by applying the natural bond orbital (NBO) analysis. The electronic properties like HOMO–LUMO analysis of (5B2PC) have been reported.     

含氮-空位缺陷锯齿状石墨烯纳米条带中负微分电阻和自旋过滤效应

采用第一性原理和非平衡格林函数方法,系统研究了含氮空位缺陷锯齿状石墨烯纳米条带的自旋极化输运特性．理论计算结果表明边界非对称的这类石墨纳米条带的基态具有铁磁性,由其构建的分子结中负微分电阻效应具有鲁棒性,是电极局域的态密度及依赖偏压的散射区-电极耦合作用结果．此外,在特定偏压区域还观察到几乎完美的自旋过滤效应．     

Existence of symmetric positive solutions for a class of Sturm-Liouville-like boundary value problems

This paper deals with the existence of symmetric positive solutions for a class of singular Sturm-Liouville-like boundary value problems with a one-dimensional p-Laplacian operator. By using the fixed theorem of cone expansion and compression of norm type in a cone, the existence of positive solutions is established though nonlinear term contains the first derivative of unknown function.     

合肥滨湖新区静压管桩单桩极限承载力与终压力关系的载荷试验研究

以合肥滨湖某安置房项目PHC管桩加固工程为依托,利用PHC静压管桩的载荷试验,对静压管桩的单桩极限承载力Qu、静压管桩施工中的终压力Pu进行了研究。得到以碎石层为持力层时,单桩极限承载力与终压力之间的关系,单桩竖向极限承载力小于终压力,且为终压力的60%~90%;通过对长径比(L/d)与压力比(Qu/Pu)进行回归分析,发现两者大致呈双曲线关系。建立了静压管桩单桩极限承载力与终压力之间关系的地区经验公式,便于在静压管桩施工中更加可靠地控制终压力。     

基于联系矩阵的围岩稳定性组合评价模型

围岩稳定性评价受诸多类型因素影响,是一个复杂不确定系统问题.为克服基于单一信息评价方法只能从特定角度分析围岩稳定性问题的缺陷,应用集对分析耦合理论探讨了可统一与融合各类信息特点的围岩稳定性组合评价新模型,以充分利用各类评价方法所包含的有用信息和避免单一方法预测错误的风险.该模型首先基于各种典型评价方法独立分析围岩稳定性,然后将获得的评价结果两两构成集对进行同异反分析,以构建联系矩阵和合理确定权重,最后基于组合原理综合评定围岩稳定性类别.实例应用结果表明,该模型用于围岩稳定性评价是有效可行的,且能综合各类评价方法的优点与提高预测精度,也为类似评价问题提供了参考.     

Coherent Spin Transport Through a Six-Coordinate FeN6 Spin-Crossover Complex with Two Di erent Spin Con gurations

Due to the magnetic bistability, single-molecule spin-crossover (SCO) complexes have been considered to be the most promising building blocks for molecular spintronic devices. Here, we explore the SCO behavior and coherent spin transport properties of a six-coordinate FeN₆ complex with the low-spin (LS) and high-spin (HS) states by performing extensive first-principles calculations combined with non-equilibrium Green’s function technique. Theoretical results show that the LS?HS spin transition via changing the metal-ligand bond lengths can be realized by external stimuli, such as under light radiation in experiments. According to the calculated zero-bias transmission coefficients and density of states as well as the I-V curves under small bias voltages of FeN₆ SCO complex with the LS and HS states sandwiched between two Au electrodes, we find that the examined molecular junction can act as a molecular switch, tuning from the OFF (LS) state to the ON (HS) state. Moreover, the spin-down electrons govern the current of the HS molecular junction, and this observed perfect spin-filtering effect is not sensitive to the detailed anchoring structure. These theoretical findings highlight this examined six-coordinate FeN₆ SCO complex for potential applications in molecular spintronics.