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71.
根据 30万t乙烯工程“橡胶”装置中生产工艺控制的实际需要 ,研究了在线分析己烷中痕量四氢呋喃的气相色谱柱系统。使用自制的 7μm特厚膜甲基硅氧烷大孔径弹性石英毛细管柱 ,通过试验不同条件下色谱柱的分离特性及研究组分在柱内的运动轨迹 ,给出了总的柱切换时间程序。在上述基础上 ,完成了正己烷、环己烷中 10 -6(体积分数 )级的四氢呋喃分析。现场应用一年多的实践表明 ,所研制的柱系统从分析时间、运行稳定性、定量准确性 (相对标准偏差小于 5 % )等方面均满足工艺控制的要求。 相似文献
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氯化银比浊法测定铜箔镀液中微量氯 总被引:2,自引:0,他引:2
采用氯化银比浊法,在不分离硫酸铜的条件下,直接测定镀铜电解液中微量氯离子。对试验条件和可能存在的干扰进行了研究,榈的加标回收率在98.7% ̄107.0%之间,相对标准偏差在2.7% ̄8.8%之间。方法快速简单,结果满意。 相似文献
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Na Wu Junling Wang Can Liao Longfei Han Lei Song Yuan Hu Xiaowei Mu Yongchun Kan 《Journal of Energy Chemistry》2022,(1):372-384
In this work,we have successfully prepared a novel separator modified with N,S co-doped carbon framework(named NSPCF)with confined CoS2 nanoparticles and rooted carbon nanotubes material(named NSPCF@CoS2)to apply for high-performance Lithium-Sulfur batteries(Li-S batteries).Robust carbon structure with large specific surface can act as a physical barrier and possess physical adsorption effect on lithium polysulfides(LiPSs).In addition,highly-conductive carbon can improve integral conductivity,leading to the fast charge transport and reaction kinetics.Also,doping heteroatoms could form more active sites to adsorb LiPSs strongly so that modified separator could inhibit the shuttle effect effectively.Moreover,the presence of CoS2 further enhances the ability of modified separator to trap LiPSs owing to the Lewis acid-base action.As a result,the NSPCF@CoS2@C-150 battery can deliver initial discharge capacities of 863.0,776.2,649.1 and 489.4 mAh g-1 at 0.1,0.5,1 and 2C with a high sulfur loading of 2.04 mg cm-2,respectively.Notably,when turning the current density back to 0.1 C,its discharge capacity can recover to 1008.7 mAh g-1.In addition,the modified separators exhibit outstanding capacities to restrain the growth of lithium dendrites.It is noteworthy that the flame retardant performances of Li-S batteries are improved dramatically owing to the novel structures of modified separators.This rationally designed separator endows Li-S batteries with higher safety and excellent electrochemical performances,providing a feasible strategy for practical application of Li-S batteries. 相似文献
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Can Liao Wei Wang Junling Wang Longfei Han Shuilai Qiu Lei Song Zhou Gui Yongchun Kan Yuan Hu 《Journal of Energy Chemistry》2021,(5):1-10
To date,lithium-ion batteries are becoming increasingly significant in the application of portable devices and electrical vehicles,and revolutionary progress in theoretical research and industrial application has been achieved.However,the commercial polyolefin separators with unsatisfying electrolytes affinity and poor thermal stability have extremely restricted the further application of lithium-ion batteries,especially in the high-temperature fields.In this work,magnetron sputtering deposition technique is employed to modify the commercial polyimide separator by coating silicon nitride on both sides.Magnetron sputtering deposition modified polyimide(MSD-PI)composite separator shows high thermal stability and ionic conductivity.More importantly,compared with the cells using Celgard separator,the cells with MSD-PI separator exhibit superior electrochemical performance,especially long-term cycle performance under high temperature environment,owing to the high thermal conductivity of surface Si3 N4 particles.Hence,lithium-ion batteries with MSD-PI separator are capable of improving thermal safety and capacity retention,which demonstrates that magnetron sputtering deposition technique could be regarded as a promising strategy to develop advanced organic/inorganic composite separators for high-temperature lithium-ion batteries. 相似文献
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Liu Jun Shi Yifei Cheng Lu Sun Jianzhong Yu Sujie Lu Xuechu Biranje Santosh Xu Wenyang Zhang Xinyu Song Junlong wang Qianqian Han Wenjia Zhang Zhen 《Cellulose (London, England)》2021,28(9):5643-5656
Cellulose - Nanocellulose has been highlighted as one of the most promising biomaterials for biomedical applications with the potential to outperform conventional polymeric materials. However, the... 相似文献
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