Syntheses and Structures of Sil abridged Hafnocene Dichlorides

The present paper covers three silabridged hafnocene dichlorides(1, 2 and 3) prepared by sequential reactions of α, ω-dichloropermethyl polysilane with cyclopentadienyl sodium, n-butyl lithium and hafnium tetrachloride. Their structures were characterized by elemental analyses, UV, 1H(13C) NMR and MS. Furthermore the crystal and molecular structures of 1 and 2 were determined by X-ray diffraction method. The crystal of 1 is monoclinic, space group C2/c with a=1. 3401(4), b=0. 9977(3), c = 1. 0922(4) nm; β=94. 07(1)° V=3. 6342 nm3, Z = 2, Dc = 2.155 g·cm-3. The final deviation factor R = 0. 064. The crystal of 2 is monoclinic, space group P21/c with a=0.0847(1), b=1.5181(1), c=2.9824(2) nm; β= 94. 07(1)°? V=3.634 nm3; Dc= l. 805 g·cm-3. The final deviation factor R = 0. 033. The relationship between the silabridged structure and spectral properties is also discussed.     

von-Neumann正则环与左SF-环

环R称为左SF-环,如果每个单左R-模是平坦的.众所周知,Von-Neumann正则环是SF-环,但SF-环是否是正则环至今仍是公开问题,本文主要研究左SF-环是正则环的条件,证明了:如果R是左SF-环且R的每个极大左(右)理想是广义弱理想,那么R是强正则环.并且推广了Rege[3]中的相应结果.     

线性加指数效用函数的组合投资研究

应用无差异曲线法较好地解决了在投资决策分析中具有特殊重要地位的线性加指数效用函数的最优组合投资比例的求解问题,并给出实例予以说明.     

青岛港货运吞吐量的时间序列模型

运用时间序列分析方法对时间序列建立ARMA,ARIMA模型.搜集了青岛港1999年1月～2003年5月的货运吞吐量数据,对进行分析,建立了青岛港货运吞吐量的模型.通过预留的部分数据对模型进行检验,并对模型的残差进行检验,得出模型比较合理.     

解抛物问题的一类新的瀑布型多重网格法

本文推广石钟兹 ,许学军对椭圆问题提出的新的瀑布型多重网格法到抛物问题 ,建立了相应的理论结果 .     

显像管调制特性的测量与分析

测试了显象管调制特性曲线，并分析了特性曲线与显像管工作原理．     

非Lipschitz系数的倒向半线性随机发展方程的适度解

文中将研究如下的无穷维空间的倒向半线性随机发 展方程x(t)+∫TteA(s-t)f(s,x(s),y(s))ds+∫Tte A(s-t )(g(s,x(s))+y(s))dw(s)=eA(T-t)X,在类似于Ymada条件下获得了该方程适度解的存在性和唯一性定理.     

利用电泳技术在不锈钢和铁基底上制备MgB2带材

本文首次报道了利用电泳技术在铁和不锈钢基底上制备MgB2超导带材.电阻测量表明,沉积在铁和不锈钢基底上MgB2带材的超导零电阻转变温度分别为37.5K和31K,超导转变宽度分别为0.3K和1K.磁测量表明,(5K,OT)时不锈钢基底上带材的临界电流密度为6×105(A/cm2).X射线衍射谱和扫描电子显微镜图象表明样品结晶良好,晶粒生长致密.本工艺制备MgB2带材时不受系统真空度的限制,生长迅速,成本低廉,并且可以根据不同的需要任意选择基底的形状和大小.     

宜产葛根中微量元素含量的测定

原子吸收分光光度法测定了宜昌地区产葛根中的Cu．Fe．Zn、Mn、Mo．Mg、Se等6种微量元素。为葛根的药效进一步研究和综合开发利用提供了新的科学依据。     

Study on the Chemical Constituent from the Seed of Litchi chinensis Sonn.

Seed of Litchi chinensis Sonn. is a traditional Chinese medicine, having curative effects on gastric disease, diabetes,and relieving pain.[1] Two new compounds 4-O-p-coumaroylquinic acid butyl ester (1) and 3-O-p-coumaroylquinic acid butyl ester (2), along with five known compounds: 5-O-p-coumaroylquinic acid butyl ester (3),[2] 3-O-p-coumaroylquinic acid methyl ester (4),[3] n-butyl-1-β-D-fructopyranoside (5),[4] D-1-O-methylmyo-inositol (6)[5] and 1H-imidazole-2,3-dihydro-2-oxo-4-carboxylic acid methyl ester (7)[5] were isolated and purified from the ethanol extracts of the seed of L.chinensis Sonn. Their structures, shown in Figure 1, were elucidated by ESI-MS, 1H NMR and 13C NMR, including 2DNMR spectroscopy.