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排序方式: 共有1316条查询结果,搜索用时 187 毫秒
111.
Makoto KanematsuKana Soga Yuki ManabeSachie Morimoto Masahiro YoshidaKozo Shishido 《Tetrahedron》2011,67(26):4758-4766
The second-generation enantioselective synthesis of heliannuol A and the first enantioselective total synthesis of heliannuol K (via two routes) have both been accomplished efficiently; (heliannuol A, nine steps and 25% yield; heliannuol K, seven steps and 47% yield). Highlights of our synthetic strategy include a substrate-controlled chirality transfer in the Lewis acid mediated Claisen rearrangement of the allyl aryl ether for the key construction of a tertiary stereogenic center at the benzylic position followed by, for heliannuol A, ring-closing metathesis, diastereoselective epoxidation, and regioselective cleavage of the epoxide; and for heliannuol K, ring-closing metathesis and conjugate reduction of the eight-membered enone. 相似文献
112.
Koji Takagi Hiroki Kakiuchi Yasuo Yuki Masato Suzuki 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4786-4794
The synthesis and optical properties of polymers bearing the repeating unit of terfluorene and various organosilicon groups were investigated. Polymers with high molecular weight and good solubility could be obtained by Suzuki coupling polymerization from silylene‐containing fluorene‐based dibromo monomers and 9,9‐dihexylfluorene‐2,7‐bis(trimethyleneborate). From UV spectra of polymers bearing acyclic silylene bridge, the organosilicon units not only interrupted a π‐conjugation but also contributed to an electronic communication between connected fluorenes. The emission maximum wavelengths (ca. 400 nm) blue‐shifted when compared with that of polyfluorene (418 nm) and the fluorescence quantum yields were considerably high (>0.82) in the CHCl3 solution. On the other hand, rather broad emission was observed at 480 nm and the fluorescence quantum yield was quite low (0.004) in the solution‐state PL spectrum of tetraphenylsilole‐containing polymer. The polymer emitted visible green light in the spin‐coated film. The fluorescence peak intensity at 486 nm gradually decreased when the film was illuminated with the UV light of 359 nm in air. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4786–4794, 2007 相似文献
113.
High Ethene/Ethane Selectivity in 2,2′‐Bipyridine‐Based Silver(I) Complexes by Removal of Coordinated Solvent 下载免费PDF全文
Dr. Matthew G. Cowan William M. McDanel Prof. Hans H. Funke Dr. Yuki Kohno Prof. Douglas L. Gin Prof. Richard D. Noble 《Angewandte Chemie (International ed. in English)》2015,54(19):5740-5743
Following removal of coordinated CH3CN, the resulting complexes [AgI(2,2′‐bipyridine)][BF4] ( 1 ) and [AgI(6,6′‐dimethyl‐2,2′‐bipyridine)][OTf] ( 2 ) show ethene/ethane sorption selectivities of 390 and 340, respectively, and corresponding ethene sorption capacities of 2.38 and 2.18 mmol g?1 when tested at an applied gas pressure of 90 kPa and a temperature of (20±1) °C. These ethene/ethane selectivities are 13 times higher than those reported for known solid sorbents for ethene/ethane separation. For 2 , ethene sorption reached 90 % of equilibrium capacity within 15 minutes, and this equilibrium capacity was maintained over the three sorption/desorption cycles tested. The rates of ethene sorption were also measured. To our knowledge, these are the first complexes, designed for olefin/paraffin separations, which have open silver(I) sites. The high selectivities arise from these open silver(I) sites and the relatively low molecular surface areas of the complexes. 相似文献
114.
115.
Dr. Aya Yoshimura Yuki Takamachi Prof. Dr. Li‐Biao Han Prof. Dr. Akiya Ogawa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(40):13930-13933
An efficient metal‐free diboration of terminal alkynes is reported. In the presence of a catalytic amount of organosulfides under light, the addition of bis(pinacolato)diboron (B2pin2) to terminal alkynes takes place efficiently to produce the corresponding double borylation products in good yields. Mechanistic studies indicate that this metal‐free sulfide‐catalyzed diboration of alkynes likely occurs by generation of a boryl‐centered radical with the aid of light and a sulfide, since such a radical was detected in the reaction mixture by electron spin resonance (ESR) spectroscopy. The present form of catalysis (sulfide/light) is thought to be unprecedented and provides a new means of preparation for organoboranes without heavy metal contamination in the products, which is highly desired in the preparation of drugs and electronic materials. 相似文献
116.
Native Mannose‐Dominant Extraction by Pyridine–Phenol Alternating Oligomers Having an Extremely Efficient Repeating Motif of Hydrogen‐Bonding Acceptors and Donors 下载免费PDF全文
Yuki Ohishi Dr. Hajime Abe Prof. Dr. Masahiko Inouye 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(46):16504-16511
Pyridine–phenol alternating oligomers in which pyridine and phenol moieties are alternatingly linked through acetylene bonds at the 2,6‐positions of the aromatic rings were designed and synthesized. The pyridine nitrogen atom and the neighboring phenolic hydroxyl group were oriented so that they do not form an intramolecular hydrogen bond but cooperatively act as hydrogen‐bonding acceptor and donor in a push–pull fashion for the hydroxyl group of saccharides. The longer oligomer strongly bound to lipophilic glycosides in 1,2‐dichloroethane, and association constants approached 108 M ?1. Moreover, the oligomer extracted native saccharides from a solid phase to apolar organic solvents up to the extent of an equal amount of the oligomer and showed mannose‐dominant extraction among naturally abundant hexoses. The oligomer bound to native saccharides even in 20 % DMSO‐containing 1,2‐dichloroethane and exhibited association constants of greater than 10 M ?1 for D ‐mannose and D ‐glucose. 相似文献
117.
建立了一种液相色谱-串联质谱(LC-MS/MS)同时测定齐墩果酸和熊果酸含量的分析方法,利用衍生化试剂N,N-二甲基乙二胺(DMED)和d4-N,N-二甲基乙二胺(d4-DMED)分别衍生样品和标准工作溶液中的目标分析物,并将标准工作液的衍生产物作为稳定同位素内标。该方法线性关系良好,相关系数均0.99;齐墩果酸和熊果酸的检出限(S/N=3)分别为0.92 ng/L和1.06 ng/L,加标回收率分别为98.7%~102.7%和97.2%~105.0%。该方法简单、快速、准确,可满足枇杷膏中齐墩果酸和熊果酸高灵敏度检测的需求。 相似文献
118.
Nakayama Masanobu Nishimura Norimitsu Kondo Yuki Takeda Hayami Kasuga Toshihiro 《Journal of Solid State Electrochemistry》2017,21(4):1137-1143
Journal of Solid State Electrochemistry - We demonstrate the Laplace transform (LT) impedance technique for measuring electrochemical lithiation and delithiation in the two-phase system of spinel... 相似文献
119.
Oligosaccharides in therapeutic recombinant antibodies play important roles in regulation of various biological functions. To monitor the glycosylation profiles of antibody pharmaceuticals in the manufacturing process, a highly sensitive and specific method is required. We extended partial-filling techniques using lectins and exoglycosidases in capillary electrophoresis for the characterization of 8-aminopylene-1,3,6-trisulfonic acid labeled N-linked oligosaccharides derived from the therapeutic antibody rituximab. In the lectin-filling method, Galb1–4GlcNAc-specific Erythrina cristagali agglutinin, a1, 6-linked Fuc-specific Aleuria aurantia lectin and Neu5Aca2–3Gal-specific Maackia amurensis lectin were used. The oligosaccharides migrated through the lectin plug during separation; the changes in separation profiles were observed according to the interaction with the lectins. The glycosidase-filling method allowed rapid digestion as suggested by the electropherograms. Partial-filling CE methods can avoid tedious hands-on procedures such as overnight incubation and optimization reaction condition with lectins and exoglycosidases. Combination of these partial-filling capillary electrophoresis methods makes the characterization of oligosaccharide profiles of therapeutic antibodies easier and faster. 相似文献
120.
Potential-dependent adsorption and transfer of poly(diallyldialkylammonium) ions at the nitrobenzene|water interface 总被引:1,自引:0,他引:1
Zhang L Kitazumi Y Kakiuchi T 《Langmuir : the ACS journal of surfaces and colloids》2011,27(21):13037-13042
Electrochemically driven adsorption and partition of a series of poly(diallyldialkylammonium) ions (PDADAA(+): alkyl = methyl, ethyl, propyl, and butyl) at the nitrobenzene (NB)|water (W) interface have been studied using voltammetry and electrocapillary measurements. When the phase-boundary potential, Δφ, that is, the inner potential of the W phase referred to that of the NB phase, is negative, poly(diallyldimethylammonium) (PDADMA(+)) shows little surface activity. The scanning of Δφ in the positive direction induces, first, the adsorption of PDADMA(+) at the interface and, then, the desorption of adsorbed PDADMA(+) ions into the NB phase, followed by the diffusion-limited transfer of PDADMA(+) from W to NB. The elongation of the dialkyl chains gives the stronger surface activity of PDADAA(+) even when Δφ < 0. The PDADAA(+) polyions studied are only slightly more hydrophilic than the corresponding monomers. However, the polycationic character of PDADAA(+) renders the adsorption, desorption, and ion transfer strongly dependent on Δφ and gives rise to unusual, M-shaped electrocapillary curves. The interplay of adsorption-desorption and ion transfer of PDADAA(+) ions induces the electrochemical instability of the interface and the emulsion formation on the NB side of the interface. 相似文献