Gas chromatographic/mass spectrometric measurement of deuterium-labelled valine,leucine, isoleucine and phenylalanine in the human body

N-Trifluoroacetyl-n-butyl ester derivatives of deuterium-labelled valine, leucine, isoleucine and phenylulanine were analysed by the isotope dilution technique and gas chromatography/mass spectrometry (GC/MS). Selected ion retrieval and peak-area integration were applied. The conditions adopted gave good separations with a short experimental time and high intensity. Ratios of the total isotopic abundance and metabolic kinetic curves were obtained. The regression coefficient of the standard dilution curve was 0.99 and the relative standard deviation was 0.3%. The stabilities of the amino acid derivatives were also tested.     

Optical and structural properties of nanosized ZnGa2O4:Cr phosphor

Nanosized ZnGa₂O₄:Cr³⁺ powder is synthesized through hydrothermal method. The average particle size is 20 nm and they are spherical in shape. The excitation band from the charge transfer between Cr³⁺-O²⁻ shows a blueshift behavior due to quantum confinement effect. X-ray diffraction pattern, Fourier transform-infrared spectrum, and electron paramagnetic resonance signal indicate that nanosized ZnGa₂O₄:Cr³⁺ phosphor shows many defect-related energy states and heavy lattice distortion in comparison with bulk ZnGa₂O₄:Cr³⁺ phosphor. Many defect states result in more nonradiative loss and shorter decay time.     

Fabrication and magnetic properties of amorphous Co0.71Pt0.29 nanowire arrays

Highly ordered Co_0.71Pt_0.29 alloy nanowire arrays have been fabricated successfully by direct current electro-deposition into the pores of a porous anodic aluminum oxide (AAO) template. SEM and TEM images reveal that the nanowires of array are uniform, well isolated, and parallel to one another. The aspect ratio of nanowires is over 200. XRD and EDS pattern indicates that amorphous Co_0.71Pt_0.29 structure was formed during electro-deposition. In amorphous sample, magnetocrystal anisotropy is very small, therefore, shape anisotropy plays a dominant role which leads to strong perpendicular anisotropy. High coercivity (Hc=1.7 kOe) and squareness (Mr/Ms) around 0.7 were obtained in the samples when the field was applied parallel to the axis of the nanowires. However, when it changed to polycrystalline structure after annealing, due to the competition of magnetocrystal anisotropy and shape anisotropy, the sample did not display perpendicular anisotropy.     

Thermal analysis of aged hdpe based composites

HDPE based composites were produced with 10-20-30 and 40% composite mass of wood fiber. The coupling agents were epolene and silane. The thermal behavior of composite samples was analyzed as a function of the coupling agent content, the exposure time and the wood fibers content by means of differential scanning calorimetry. Calorimetric curves of all samples of first and second heating shows a similar behavior. Some significant relation has been observed between the exposure time and the degree of crystallinity for the same percentage of fiber samples. A linear relation between the melting enthalpy average vs. content in cellulosic fibers is detected. Nevertheless, the fibers non-pretreated with coupling agent show a lower loss of crystallinity of the HDPE matrix at low wood fiber content (10%). A slight diminution of the melting peak temperature is detected as increasing the exposure time. This revised version was published online in July 2006 with corrections to the Cover Date.     

关于度量加的一个定理及一个矩阵不等式

关于度量加的一个定理及一个矩阵不等式苏化明（合肥工业大学数学力学系２３０００９）§１关于度量加的一个定理Ｒ。Ａｌｅｘａｎｄｅｒ在［１］中曾提出如下猜想：设两个单形的顶点分别为ｐ＿１，Ｐ＿２，…，Ｐ＿（ｎ＋１），和构作第三个单形，使得测应当有不等式这里...     

Singular Points Near an X_0-breaking Double Singular Fold Point in Z_2-symmetric Nonlinear Equations

ＳｉｎｇｕｌａｒＰｏｉｎｔｓＮｅａｒａｎＸ_０－ｂｒｅａｋｉｎｇＤｏｕｂｌｅＳｉｎｇｕｌａｒＦｏｌｄＰｏｉｎｔｉｎＺ_２－ｓｙｍｍｅｔｒｉｃＮｏｎｌｉｎｅａｒＥｑｕａｔｉｏｎｓＳｕＹｉ（苏毅）ａｎｄＷｕｗｅｉ（吴微）（ＤｅｐａｒｔｍｅｎｔｏｆＭａｔｈｅ...     

系统可靠性与最优检测周期的综合研究

本文研究可修系统的一个模型,假定系统可能因为各种原因造成失效率增大,并且这种情况需要检测之后才能发现,本文利用概率分析、补充变量和最优化方法,求出了系统的可靠性指标,并给出了计算最优检测周期的方法。     

大孔膦酸树脂吸附钇的研究

大孔膦酸树脂吸附钇的研究舒增年熊春华（丽水师范专科学校化学系浙江３２３０００）林峰（杭州大学化学系杭州３１００２８）关键词大孔膦酸树脂钇吸附机理中图分类号Ｏ６１４．３２２本文在ＨＡｃ－ＮａＡｃ体系中，研究了树脂吸附钇的性能及其机理，获得了诸多的结果，...     

局部域上的局部Hardy空间

文献［１］，［２］，［３］中讨论了Ｒ^ｎ上的局部Ｈａｒｄｙ空间，并利用乘子定理证明了ｈ_ｐ（Ｒ^ｎ）＝Ｆ_p.2⁰（Ｒ^ｎ）．本文利用Ｃｈｅｂｙｓｈｅｖ等式及正则函数的性质证明了在局部域上有类似的结果ｈ_ｐ（Ｒ^ｎ）＝Ｆ_p.2⁰（Ｒ^ｎ），从而建立起函数空间之间的关系，并由此给出一个乘子定理．