全文获取类型
收费全文 | 40130篇 |
免费 | 6668篇 |
国内免费 | 5756篇 |
专业分类
化学 | 30787篇 |
晶体学 | 599篇 |
力学 | 2006篇 |
综合类 | 387篇 |
数学 | 4277篇 |
物理学 | 14498篇 |
出版年
2024年 | 79篇 |
2023年 | 713篇 |
2022年 | 1006篇 |
2021年 | 1345篇 |
2020年 | 1616篇 |
2019年 | 1672篇 |
2018年 | 1422篇 |
2017年 | 1397篇 |
2016年 | 1946篇 |
2015年 | 1906篇 |
2014年 | 2389篇 |
2013年 | 3126篇 |
2012年 | 3659篇 |
2011年 | 3802篇 |
2010年 | 2809篇 |
2009年 | 2705篇 |
2008年 | 2922篇 |
2007年 | 2674篇 |
2006年 | 2486篇 |
2005年 | 2063篇 |
2004年 | 1573篇 |
2003年 | 1284篇 |
2002年 | 1272篇 |
2001年 | 1022篇 |
2000年 | 854篇 |
1999年 | 772篇 |
1998年 | 593篇 |
1997年 | 524篇 |
1996年 | 461篇 |
1995年 | 417篇 |
1994年 | 371篇 |
1993年 | 274篇 |
1992年 | 250篇 |
1991年 | 236篇 |
1990年 | 185篇 |
1989年 | 145篇 |
1988年 | 112篇 |
1987年 | 83篇 |
1986年 | 93篇 |
1985年 | 81篇 |
1984年 | 38篇 |
1983年 | 34篇 |
1982年 | 32篇 |
1981年 | 22篇 |
1980年 | 15篇 |
1979年 | 10篇 |
1974年 | 7篇 |
1973年 | 7篇 |
1971年 | 8篇 |
1936年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 234 毫秒
121.
Imaging mass spectrometry requires the acquisition and interpretation of hundreds to thousands of individual spectra in order to map the mineral phases within heterogeneous geomatrices. A fuzzy logic inference engine (FLIE) was developed to automate data interpretation. To evaluate the strengths and limitations of FLIE, the chemical images obtained using FLIE were compared with those developed using two chemometric methods: principle component analysis (PCA) and cluster analysis (K-Means). Two heterogeneous geomatrices, a low-grade chalcopyrite ore and basalt, were imaged using a laser-desorption Fourier transform mass spectrometer. Similar mineral distribution patterns in the chalcopyrite ore sample were obtained by the three data analysis methods with most of the differences occurring at the interfaces between mineral phases. PCA missed one minor mineral phase in the chalcopyrite ore sample and did not clearly differentiate among the mineral classes of the basalt. K-Means cluster analysis differentiated among the various mineral phases in both samples, but improperly grouped some spectra in the chalcopyrite sample that only contained unanticipated high mass peaks. Unlike the chemometric methods, FLIE was able to classify spectra as unknowns for those spectra that fell below the confidence level threshold. A nearest neighbor approach, included in FLIE, was used to classify the unknowns to form a visually complete image; however, the unknowns identified by FLIE can be informative because they highlight potential problems or overlooked results. In conclusion, this study validated the fuzzy logic-based approach used in our laboratory and reveald some limitations in the three techniques that were evaluated. 相似文献
122.
采用固相反应合成了四羟基苯基卟啉与与Fe^2+,Co^2+金属离子的配合物,在室温下,将其与分子O2作用,提纯后得到两种固态氧合配合物.通过元素分析、红外光谱(IR)、核磁共振氢谱(^1HNMR)、电导、热分析(TG/DTA)、紫外光谱(UV)等测试手段确定了氧合配合物的组成为[Co·THPP·O2](NO3)2·2H2O、[Fe·THPP·O2]Cl2·2H2O],可知1mol配合物吸收了1molO2,采用失重法测定了氧合配合物中的配位氧,确定1mol金属配合物吸收1molO2形成超氧配合物. 相似文献
123.
Sang Kyu Lee Min Ju Cho Jung‐Il Jin Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):531-542
New photocrosslinkable maleimide copolymers have been synthesized by the attachment of a tricyanopyrrolidene‐based chromophore. The 2‐(3‐cyano‐4‐(2‐{4‐[hexyl‐(6‐hydroxy‐hexyl)‐amino]‐phenyl}‐vinyl)‐5‐oxo‐1‐{4‐[4‐(3‐oxo‐3‐phenyl‐propenyl)‐ phenoxy]‐butyl}‐1,5‐dihydro‐pyrrol‐2‐ylidene)‐malononitrile chromophore exhibits nonlinear optical activity and contains a chalcone moiety that is sensitive to UV light (λ = 330–360 nm) for crosslink formation. The maleimide monomers have also been functionalized with chalcone moieties. The resultant copolymers exhibit great processability, and one of them shows a maximum electrooptic coefficient of 90 pm/V at 1300 nm. We could control the thermal stability of the electrooptic coefficient with the newly synthesized photoreactive copolymers successfully. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 531–542, 2007 相似文献
124.
Xinhuan Feng Lei Sun Yange Liu Lingyun Xiong Shuzhong Yuan Guiyun Kai Xiaoyi Dong 《Optical and Quantum Electronics》2004,36(10):919-926
A simple actively mode-locked fiber ring laser is proposed and successfully demonstrated to generate dual-wavelength picosecond pulses with close wavelength spacing using one Bragg grating in standard single-mode fiber. The proposed laser can be made to operate in stable dual-wavelength at room temperature, due to the birefringence characteristic of the FBG induced by transverse strain. Transverse strain loading on the FBG allows the wavelength spacing to be controlled. Generation of stable dual-wavelength pulses with a pulsewidth of 212–234 ps and a tunable wavelength separation from 0.2 to 0.44 nm at a pulse rate of 1.05 GHz was demonstrated. 相似文献
125.
基于平稳小波变换及奇异值分解的湖底回波分类 总被引:6,自引:0,他引:6
提出一种水下目标回波的特征提取方法。该方法根据平稳小波变换的冗余性和奇异值的稳健性,将湖底回波信号的平稳小波变换系数矩阵的奇异值作为特征向量。它本质上是利用平稳小波变换将信号分解到多个子空间,再采用K-L变换实现对子信号的特征压缩。实测数据分析表明,本文方法与子带能量特征法相比: (1)在相同的样本集和类内距条件下,得到的类间距大于后者, (2)不论所选测试样本和训练样本是否属于同次湖试所得,分类正确识别率均高于后者, (3)随样本集的变动,其正确识别率抖动程度远小于后者。因此,该方法能得到更加稳健、有效的特征以及更好的分类效果。 相似文献
126.
127.
Lotka-Volterra型N-种群竞争系统的持久性和稳定性 总被引:6,自引:0,他引:6
本文研究一类具有无穷时滞的概周期Lotka-Volterra型N-种群竞争系统的持久性和全局渐近稳定性.一些新的充分条件被得到. 相似文献
128.
129.
130.
Jie Xue Liang Chen Li Zhou Zhifeng Jia Yanping Wang Xinyuan Zhu Deyue Yan 《Journal of Polymer Science.Polymer Physics》2006,44(15):2050-2057
α‐Cyclodextrin (α‐CD) has been complexed with various poly(ethylene glycol) (PEG) derivatives in aqueous solution. It has been found that the end groups of PEG derivatives affect the complexation kinetics greatly, but have only a little influence on the thermodynamic behavior. By increasing the hydrophobicity of end groups, the complexation speeds up rapidly. On the other hand, the bulky end groups slow down the threading of polymeric guests into the cavity of CD. By changing the hydrophobicity and the size of end groups, the complexation rate can be adjusted in the range of several orders of magnitudes, which should be quite useful in the design of new supramolecular systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2050–2057, 2006 相似文献