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81.
THE PHOTODYNAMIC EFFECT OF ROSE BENGAL ON PROTEINS OF THE MITOCHONDRIAL INNER MEMBRANE 总被引:2,自引:0,他引:2
Cecilia Giulivi Monica Sarcansky Esteban Rosenfeld Alberto Boveris 《Photochemistry and photobiology》1990,52(4):745-751
Photodynamic action promoted by Rose Bengal was evaluated in solutions of unsaturated fatty acids or histidine, and on beef heart submitochondrial particles. Rose Bengal-promoted photooxidation of histidine was mainly due to the opening up of the imidazole ring by singlet oxygen. Photosensitization of polyunsaturated fatty acids (PUFA) resulted in oxygen consumption and thiobarbituric acid-reactive substances (TBARS) formation, the extent of which was linearly related to the increasing degree of unsaturation. Photosensitization of submitochondrial particles caused oxygen consumption and TBARS production. These processes involved two different reaction components: during the first, most of the mitochondrial proteins were inactivated, the most sensitive being succinate dehydrogenase and cytochrome c. The values for the rate ratios of [TBARS] formation/[O2] consumption for the first and second phase were 0.36 and 1.32%, respectively, pointing to a larger contribution of lipid peroxidation during the second phase. The calculation of the rate constants for reaction of singlet oxygen with mitochondrial proteins suggests that singlet oxygen is more reactive towards proteins than to PUFA. The biological role of this selectivity is discussed in terms of the mitochondria as one of the first targets for photosensitized reactions. 相似文献
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Csorna SE Garren L Mestayer MD Panvini RS Yi X Alam MS Avery P Bebek C Berkelman K Cassel DG Copie T DeSalvo R DeWire JW Ehrlich R Ferguson T Galik R Gilchriese MG Gittelman B Halling M Hartill DL Holzner S Ito M Kadaswamy J Kreinick DL Kubota Y Mistry NB Nordberg E Ogg M Peterson D Perticone D Read K Silverman A Stein PC Stone S Kezun X Sadoff AJ Giles RT Hassard J Hempstead M Kinoshita K McKay WW Pipkin FM Wilson R Haas P Jensen T Kagan H Kass R Behrends S Gentile T Guida JM Guida JA Morrow F 《Physical review letters》1985,54(17):1894-1897
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L. Rosenfeld 《Zeitschrift für Physik A Hadrons and Nuclei》1929,57(11-12):835-854
86.
Journal of Mathematical Chemistry - The construction of vertex-decorated graphs can be used to produce derived graphs with specific eigenvalues from undecorated graphs, which themselves do not have... 相似文献
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We report structural and dynamical properties of water confined within reverse micelles (RMs) ranging in size from R = 10 A to R = 23 A as determined from molecular dynamics simulations. The low-frequency infrared spectra have been calculated using linear response theory and depend linearly on the fraction of bulklike water within the RMs. Furthermore, these spectra show nearly isosbestic behavior in the region near 660 cm(-1). Both of these characteristics are present in previously measured experimental spectra. The single dipole spectra for interfacial trapped, bound, and bulklike water within the RMs have also been calculated and show region-dependent frequency shifts. Specifically, the bound and trapped water spectra have a peak at lower frequencies than that for the inner core water. We therefore assign the low-frequency band in the IR spectra to bound and trapped interfacial water. Finally, region-dependent hydrogen bonding profiles and spatial distribution functions are also presented. 相似文献
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