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101.
文献[ 2 ] 在理论上不必要地复杂化了, 由此导出的算法也相当繁琐. 本文在独立性假设下, 推导了一 种估计参数的有效方法,能大大减少计算工作量. 实例还表明, 用新法估计的参数更接近于实际情况 相似文献
102.
Liping Li Quan Wein Chuanbin Jiang Xiaolin Ren Zhigou Yao Wenhui Su 《Hyperfine Interactions》1995,96(1):237-243
The samples of Eu1–x
Sr
x
FeO3–y
(x=0.0–1.0) were prepared by the solid state reaction method. Their X-ray diffraction patterns and57Fe Mössbauer spectra at room temperature were measured. It is found that Sr ions incorporate in the lattice of EuFeO3, the change of crystal structure is related to the dopant.57Fe Mössbauer spectra consist of one magnetic, one doublet and one single paramagnetic components. The Fe ions in the cubic phase are in intermediate valence state between Fe(III) and Fe(IV) and may participate in electron hopping. 相似文献
103.
104.
Haijun Tao Jun Zhang Xiaolin Wang Jiali Gao 《Journal of Polymer Science.Polymer Physics》2007,45(2):153-161
The effects of the polymer concentration and quenching temperature on the phase separation, the membrane morphology and polymer crystallization behavior in a poly(4‐methyl‐1‐pentene) (TPX)‐dioctylsebacate (DOS)‐dimethylphthalate (DMP) system via thermally induced phase separation were studied with a pseudobinary phase diagram, with the weight ratio of DOS:DMP = 1:1. SEM was used to observe the membrane morphology and structure, whereas the TPX crystallization behavior was studied with DSC and WAXD. Liquid‐liquid phase separation occurred, although quenching under the crystallization temperature. As the quenching temperature decreased, the pore size decreased, with better connected pore structure formed. The membranes quenched at 333 and 363 K showed good cellular structures, with an average pore size of about 2.3μm, whereas the pores of the membranes quenched at 393 and 423 K were not well formed, with some lamellar crystals on the inner side. The diluent assisted the mobility of the polymer chain, which improved the polymer crystallization. Dual‐melting‐peak behavior occurred for all the samples studied here. As the quenching temperature increased, the first peak of the melting trace moved to a higher temperature, whereas the second one stayed almost the same. The flexibility of the TPX main chain was restricted by the side groups, which allowed liquid‐liquid phase separation to occur first when quenched below the equilibrium crystallization temperature. This allowed primary and secondary crystallization, which was responsible for the dual‐melting‐peak behavior. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 153–161, 2007 相似文献
105.
王小林 《数学物理学报(A辑)》1997,17(3):348-355
利用复插值样条函数,给出了定义于光滑封闭曲线上一般的正则型奇异积分方程的样条间接逼近解法,证明了一致收敛性.对于其中的一类奇异积分方程,还给出了近似解和误差估计. 相似文献
106.
107.
The refractive index nf, extinction coefficient kf and thickness df of a dip coated film are measured by using p-polarized laser beams. A sample is oblique illuminated with a p-polarized laser beam, and then two reflected beams, from the front and back surfaces, are received with a detector. After measuring their intensity ratio versus the angle of incidence, it is convenient to obtain the parameters of the film by means of data fitting. The films of polymethyltriethoxy silane (PMTES), which were made on a BK-7 glass substrate by dip coating, were measured. The method is non-contact, non-destructive and has the advantages of simplicity of both equipment and understanding. It is also shown that the values measured by this method are coincident with those measured by ellipsometry. 相似文献
108.
109.
Soulard P Asselin P Cuisset A Aviles Moreno JR Huet TR Petitprez D Demaison J Freedman TB Cao X Nafie LA Crassous J 《Physical chemistry chemical physics : PCCP》2006,8(1):79-92
CHFClI is among the more favorable molecules for parity violation (PV) measurements in molecules. Despite the fact that calculated PV effects are two orders of magnitude smaller than in some organometallic compounds, CHFClI displays interesting features which could make possible a new experimental PV test on this molecule. Indeed, ultrahigh resolution spectroscopy using an ultrastable CO(2) laser is favored by several intrinsic properties of this molecule. For example, the high vapor pressure of CHFClI allows investigation by supersonic beam spectroscopy. Indeed, the spectroscopic constants have been accurately determined by microwave and millimetre wave spectroscopy. This is important for the subsequent selection of an appropriate absorption band of CHFClI that could be brought to co?ncide with the absorption of CO(2). Partially resolved (+)- and (-)-CHFClI enantiomers with respectively 63.3 and 20.5% ee's have been recently prepared and analyzed by molecular recognition using chiral hosts called cryptophanes. Finally, the S-(+)/R-(-) absolute configuration was ascertained by vibrational circular dichro?sm (VCD) in the gas phase. 相似文献
110.
首先对我国1960-2017年的碳排放趋势分5个阶段分析,发现虽然在不同时期存在波动,但长期来看,我国碳排放强度呈逐步下降趋势.然后对差分平稳后的序列数据建立Adaboost-SVR预测模型,采用RMSE、MAPE、MAE、MSE四个评价指标比较Adaboost-SVR模型与Adaboost-DT、SVR、BP神经网络对碳排放强度的预测精度.结果表明,组合模型明显优于其他3种模型,对于碳排放强度预测具有很高的可靠性.另外,通过使用Adaboost-SVR模型进行后续年份预测,发现我国未来碳排放强度总体将继续缓慢下降.最后,基于二氧化碳排放量的LMID分解结果,提出调整能源产业结构, 促进可再生能源利用等节能减排建议. 相似文献