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21.
A series of dealuminated mordenites treated under various conditions of acid leaching was impregnated in an aqueous solution of ammonium heptamolybdate to achieve a loading of 12 wt% Mo. These samples were characterized by XRD, UV-DRS, N(2) adsorption, TGA, and FTIR techniques. Special attention was given to the far-IR measurements and IR study of surface hydroxyl groups before and after dealumination. A polymolybdate species was recognized by the appearance of bands at 344, 319, and 236 (229) cm(-1) due to the vibrational modes of delta(Mo-O) and delta(Mo-O-Mo), respectively. The disappearance of the 236 cm(-1) band as well as that at 344 cm(-1) in favor of the 319 cm(-1) band, with the dealumination, was related to the high dispersion of Mo species in the produced mesopore surface assessed by the N(2) adsorption at 77 K. No bands due to bulk MoO(3) were detected from the IR and XRD results. A strong interaction between Mo species and dealuminated mordenite surfaces (OH groups) was recognized by a decrease in intensity and a marked shift of the band at 3745 to 3727 cm(-1) as well as the appearance of a new band at 3668 cm(-1). The latter band was produced by the interaction of the framework Al-OH with Mo species. The BET surface areas of Mo-dealuminated mordenite samples were higher than the corresponding Mo-free ones. The diffuse reflectance measurements suggested that Mo cations are predominantly present as an octahedrally coordinated Mo(6+), along with some tetrahedral Mo(6+). New spectral features as a consequence of dealumination events in the far-IR range were evaluated and discussed. 相似文献
22.
An equivalent representation of the Spearman footrule is considered and a characterization in terms of a Markov chain is established. A martingale approach is thereby incorporated in the study of the asymptotic normality of the statistics. 相似文献
23.
We study the adiabatic time evolution of quantum resonances over time scales which are small compared to the lifetime of the
resonances. We consider three typical examples of resonances: The first one is that of shape resonances corresponding, for
example, to the state of a quantum-mechanical particle in a potential well whose shape changes over time scales small compared
to the escape time of the particle from the well. Our approach to studying the adiabatic evolution of shape resonances is
based on a precise form of the time-energy uncertainty relation and the usual adiabatic theorem in quantum mechanics. The
second example concerns resonances that appear as isolated complex eigenvalues of spectrally deformed Hamiltonians, such as
those encountered in the N-body Stark effect. Our approach to study such resonances is based on the Balslev-Combes theory
of dilatation-analytic Hamiltonians and an adiabatic theorem for nonnormal generators of time evolution. Our third example
concerns resonances arising from eigenvalues embedded in the continuous spectrum when a perturbation is turned on, such as
those encountered when a small system is coupled to an infinitely extended, dispersive medium. Our approach to this class
of examples is based on an extension of adiabatic theorems without a spectral gap condition. We finally comment on resonance
crossings, which can be studied using the last approach. 相似文献
24.
M. Salama 《Annalen der Physik》1987,499(8):630-632
25.
Military course of action planning involves time and space synchronization as well as resource and asset allocation. A mission could be seen as a defined set of logical ordered tasks with time and space constraints. The resources to task rules require that available assets should be allocated to each task. A combination of assets might be required to execute a given task. The couple (task, resources) constitutes an action. This problem is formulated as a multi-objectives scheduling and resource allocation problem. Any solution is assessed based on a number of conflicting and heterogeneous objectives. In fact, military planning officers should keep perfecting the plan based on the Commander’s criteria for success. The scheduling problem and resource allocation problem are considered as NP-Hard Problems [A. Guitouni, B. Urli, J.-M. Martel, Course of action planning: A project based modelling, Working Paper, Faculté des sciences de l’ administration, Université Laval, Québec, 2005]. This paper is concerned with the multi-objectives resource allocation problem. Our objective is to find adequate resource allocation for given courses of action schedule. To optimize this problem, this paper investigates non-exact solution methods, like meta-heuristic methods for finding potential efficient solutions. A progressive resource allocation methodology is proposed based on Tabu Search and multi-objectives concepts. This technique explores the search space so as to find a set of potential efficient solutions without aggregating the objectives into a single objective function. It is guided by the principle of maximizing the usage of any resource before considering a replacement resource. Thus, a given resource is allocated to the maximum number of tasks for a given courses of action schedule. A good allocation is a potential efficient solution. These solutions are retained by applying a combination of a dominance rule and a multi-criteria filtering method. The performance of the proposed Pareto-based approach is compared to two aggregation approaches: weighted-sum and the lexicographic techniques. The result shows that a Pareto-based approach is providing better solutions and allowing more flexibility to the decision-maker. 相似文献
26.
In order to solve linear programs with a large number of constraints, constraint generation techniques are often used. In
these algorithms, a relaxation of the formulation containing only a subset of the constraints is first solved. Then a separation
procedure is called which adds to the relaxation any inequality of the formulation that is violated by the current solution.
The process is iterated until no violated inequality can be found. In this paper, we present a separation procedure that uses
several points to generate violated constraints. The complexity of this separation procedure and of some related problems
is studied. Also, preliminary computational results about the advantages of using multiple-points separation procedures over
traditional separation procedures are given for random linear programs and survivable network design. They illustrate that,
for some specific families of linear programs, multiple-points separation can be computationally effective. 相似文献
27.
Salah-Eddine Chorfi Ghita El Guermai Lahcen Maniar Walid Zouhair 《Mathematical Methods in the Applied Sciences》2023,46(1):911-929
This paper studies an inverse hyperbolic problem for the wave equation with dynamic boundary conditions. It consists of determining some forcing terms from the final overdetermination of the displacement. First, the Fréchet differentiability of the Tikhonov functional is studied, and a gradient formula is obtained via the solution of an associated adjoint problem. Then, the Lipschitz continuity of the gradient is proved. Furthermore, the existence and the uniqueness for the minimization problem are discussed. Finally, some numerical experiments for the reconstruction of an internal wave force are implemented via a conjugate gradient algorithm. 相似文献
28.
29.
Ramzia I. El-Bagary Gabor Patonay Asmaa A. Elzahr Ehab F. Elkady Walid A. Ebeid 《Chromatographia》2014,77(3-4):257-264
A rapid and precise LC method was developed for the simultaneous determination of aliskiren hemifumarate (ALS), amlodipine besylate (AML) and hydrochlorothiazide (HCZ) using acetonitrile:25 mM octane sulfonic acid sodium salt monohydrate in water (60:40 v/v) as the mobile phase. The flow rate was maintained at 1.2 mL min?1 on a stationary phase composed of Supelco, Discovery® HS (C18) column (25 cm × 4.6 mm, 5 μm). Isocratic elution was applied throughout the analysis. Detection was carried out at λ max (232 nm) at ambient temperature. The method was validated according to ICH guidelines. Linearity, accuracy and precision were satisfactory over the concentration ranges of 32–320, 2–44 and 4–64 μg mL?1 for ALS, AML and HCZ, respectively. LOD and LOQ were estimated and found to be 0.855 and 2.951 μg mL?1, respectively, for ALS, 0.061 and 0.202 μg mL?1, respectively, for AML as well as 0.052 and 0.174 μg mL?1, respectively, for HCZ. The method was successfully applied for the determination of the three drugs in their co-formulated tablets. The results were compared statistically with reference methods and no significant difference was found. The developed method is specific and accurate for the quality control and routine analysis of the cited drugs in pharmaceutical preparations. 相似文献
30.