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71.
72.
Masaoka S Tanaka D Kitahata H Araki S Matsuda R Yoshikawa K Kato K Takata M Kitagawa S 《Journal of the American Chemical Society》2006,128(49):15799-15808
This paper reports a novel crystal growth system of a coordination framework {[Cu3(CN)3{hat-(CN)3(OEt)3}]}n (1) (hat-(CN)3(OEt)3 = 2,6,10-tricyano-3,7,11-triethoxy-1,4,5,8,9,12-hexaazatriphenylene). The coordination polymer is crystallized through the reaction of 2,3,6,7,10,11-hexacyano-1,4,5,8,9,12-hexaazatriphenylene (hat-(CN)6), ethanol, and copper(I) complex, involving the breaking and forming of covalent bonds. The crystal morphologies obtained in the present system contain dumbbells, cogwheels, and superlattices. Moreover, in the growth perpendicular to the c-axis, periodic ramification at regular interval is observed, affording superlattice morphologies. Observation of the growth of dumbbell crystals shows that the growth rates parallel and perpendicular to the crystallographic c-axis are quite different: the former shows a drastic change with the reaction duration, while the latter is almost constant. These results are reproduced as a simple reaction-diffusion system, indicating that chemical reactions on crystal surfaces play an important role in determining the macroscopic crystal morphologies. 相似文献
73.
Tsukamoto I Constantinoiu E Furuta M Nishimura R Maeda Y 《Ultrasonics sonochemistry》2004,11(3-4):167-172
The inactivation effects of ultrasonic irradiation at 27.5 kHz and chlorination using sodium hypochlorite solution (NaOCl) on the growth of Saccharomyces cerevisiae (yeast cells) were investigated. In order to evaluate the effect of ultrasound on the growth of the yeast cells, calorimetric analysis was carried out in addition to colony counting. The heat evolution produced by the growth of yeast cells detected by calorimetry showed completely different patterns between sonication and chlorination. In case of sonication, the yeast cells were inactivated almost like a bactericidal effect, i.e. a quantitative change in cell number, at the beginning of sonication. It was similar to patterns obtained on simple dilution of yeast cells. In contrast, longer sonication increased the bacteriostatic effect, i.e. qualitative damage of the cell growth activity, together with the bactericidal effect. These results suggest that the cavitation caused by ultrasonic irradiation initially disrupted the cells located near the cavitation bubble which caused immediate cell death and the growth activity of the surviving cells was gradually damaged by further sonication. On the other hand, only a bacteriostatic effect was observed when the yeast cells were inactivated by chlorination. 相似文献
74.
Gold nanoparticles located at the interface of anatase/rutile TiO2 particles as active plasmonic photocatalysts for aerobic oxidation 总被引:1,自引:0,他引:1
Tsukamoto D Shiraishi Y Sugano Y Ichikawa S Tanaka S Hirai T 《Journal of the American Chemical Society》2012,134(14):6309-6315
Visible-light irradiation (λ > 450 nm) of gold nanoparticles loaded on a mixture of anatase/rutile TiO(2) particles (Degussa, P25) promotes efficient aerobic oxidation at room temperature. The photocatalytic activity critically depends on the catalyst architecture: Au particles with <5 nm diameter located at the interface of anatase/rutile TiO(2) particles behave as the active sites for reaction. This photocatalysis is promoted via plasmon activation of the Au particles by visible light followed by consecutive electron transfer in the Au/rutile/anatase contact site. The activated Au particles transfer their conduction electrons to rutile and then to adjacent anatase TiO(2). This catalyzes the oxidation of substrates by the positively charged Au particles along with reduction of O(2) by the conduction band electrons on the surface of anatase TiO(2). This plasmonic photocatalysis is successfully promoted by sunlight exposure and enables efficient and selective aerobic oxidation of alcohols at ambient temperature. 相似文献
75.
76.
Sumiko Tsukamoto Mayank Jain Andrew Murray Christine Thiel Esther Schmidt Lara Wacha Reiner Dohrmann Manfred Frechen 《Radiation measurements》2012,47(9):903-908
The IRSL and post-IR IRSL (pIRIR) signal characteristics of polymineral fine grains are investigated and compared with those of K- and Na-rich feldspar extracts. TL signal loss after IR and pIRIR stimulations occurs mainly at around 320 °C for polymineral and Na-feldspar samples and around 410 °C for K-feldspar samples, when a preheat temperature of 250 °C for 60 s is used. After preheating to a higher temperature (320 °C for 60 s) all samples show a TL reduction around 410 °C in the blue detection window. Pulse annealing experiments for IRSL and pIRIR signals for preheats between 320 °C and 500 °C indicate that the signal stabilities are similar among the different feldspar types, when a higher preheat temperature (>320 °C) is used. Thermal activation energies for IRSL and pIRIR signals are largest in K-feldspar and smallest in polymineral fine grains, in both blue and UV detection windows for both fast time-resolved (TR) and continuous wave (CW) signals. These results suggest that IRSL and pIRIR signals in polymineral fine grains originate mainly from Na-feldspar grains; these signals are less thermally stable than those from K-feldspar, but a more stable signal (presumably from K-feldspar grains) can be obtained using a higher preheat temperature. 相似文献
77.
H Harada J Kazami S Watanuki R Tsuzuki K Sudoh A Fujimori T Tokunaga A Tanaka S Tsukamoto I Yanagisawa 《Chemical & pharmaceutical bulletin》2001,49(12):1593-1603
In the previous paper, we described a series of the 2-arylethenesulfonamide derivatives, a novel class of ETA-selective endothelin (ET) receptor antagonists, including the compounds 1a, b. Compound 1a showed excellent oral antagonistic activities and pharmacokinetic profiles, and the monopotassium salt of 1 (YM-598 monopotassium) is in clinical trials. In this paper, we wish to report the investigation of the further details of structure-activity relationships (SARs) of the 2-phenylethenesulfonamide region in 1a. It was found that methyl substitutions at the 2-, 4- and 6-positions of the phenyl group in 1a led to the discovery of the ET(A)/ET(B) mixed antagonist (6s) with an IC50 of 2.2 nM for the ET(A) receptor. We also found that introduction of an ethyl group to the 1-position of the ethenyl group in 1a gave the ET(A) selective antagonist (6u) with an oral endothelin antagonistic activity in rats. 相似文献
78.
Choji Kashima Yoshihiro Tsukamoto Yohei Miwa Kohei Higashide 《Journal of heterocyclic chemistry》2001,38(3):601-606
The enantioselective reduction of ketones was accomplished by borane in the presence of pyrazole derivatives, particularly 2‐methoxymethyl‐3‐phenyl‐1‐menthopyrazole (8). The catalysis of zinc chloride makes it possible to lower the reaction temperature below 0 °C, and to promote enantioselectivity. 相似文献
79.
The structure of a novel disaccharide, wilforibiose, isolated from the root of H(=emsl), has been established by spectral data. 相似文献
80.
Kenji Ishihara Yoshimichi Tsukamoto 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2004,80(8):372
The simplified method of analysis to assess liquefaction potential of a given sand deposit is briefly introduced in the first part of this paper. Then, recent advances in the laboratory testing for evaluating liquefaction resistance are described with a particular emphasis on the sand partly saturated with water. As a means to identify the degree of saturation which is applicable for both field deposits and laboratory samples, the use of the longitudinal wave (P-wave) is proposed based on a suite of data obtained from the triaxial tests in the laboratory. It is recommended that the non-destructive P-wave measurements be carried out first to determine the degree of saturation, and then the cyclic triaxial tests involving large destructive strains should be performed to determine the cyclic strength on the same sample of the sand. In order to demonstrate usefulness of the proposed approach, two sets of undisturbed samples were secured from two sites; one is located in Sakai-minato city which has suffered severe liquefaction at the time of the 2000 Tottoriken-Seibu earthquake and the other site is located in Koshigaya city, Saitama, where likelihood of liquefaction to occur in a future earthquake is of major concern. Penetration tests and in-situ velocity logging were also conducted at these two sites. By adjusting the P-wave velocity of the undisturbed samples in the laboratory so as to have the same velocity in the field, the in-situ state of saturation was reproduced in the laboratory samples. Then, the cyclic loading tests were conducted to determine the cyclic strength of intact samples. The results of the laboratory tests as above were incorporated into the simple method of liquefaction analysis described in the first section of this paper. The analysis seems to yield results which are in reasonably good agreement with what was observed at the time of the earthquake. 相似文献