Electrochemical procedure for express evaluation of the corrosion effect of aqueous glycol solutions on metals

Electrochemical procedure for express evaluation of the corrosion effect of aqueous glycol solutions on the metallic construction materials for cooling systems was studied. This procedure was used to develop new coolant formulations.     

Preparation of ultrapure calcium formate

Crystallization of Ca(HCOO)₂ from aqueous solutions was studied and conditions under which an ultrapure product can be obtained were determined.     

Hydrogen-induced metallization on Ge(1 1 1) c(2 × 8)

We have studied hydrogen adsorption on the Ge(1 1 1) c(2 × 8) surface using scanning tunneling microscopy (STM) and angle-resolved photoelectron spectroscopy (ARPES). We find that atomic hydrogen preferentially adsorbs on rest atom sites. The neighbouring adatoms appear higher in STM images, which clearly indicates a charge transfer from the rest atom states to the adatom states. The surface states near the Fermi-level have been followed by ARPES as function of H exposure. Initially, there is strong emission from the rest atom states but no emission at the Fermi-level which confirms the semiconducting character of the c(2 × 8) surface. With increasing H exposure a structure develops in the close vicinity of the Fermi-level. The energy position clearly indicates a metallic character of the H-adsorbed surface. Since the only change in the STM images is the increased brightness of the adatoms neighbouring a H-terminated rest atom, we identify the emission at the Fermi-level with these adatom states.     

Applications of fast atom bombardment mass spectrometry (FAB MS) to organometallic and coordination chemistry

This article describes the technique of fast atom bombardment mass spectrometry (FAB MS) and its applications to the analysis of organometallic and coordination complexes. Sections on ion generation and matrices are followed by a Periodic Group-based review of FAB MS results obtained from Transition Metal and Main Group compounds, organometallic cluster carbonyls and their derivatives, and salts of poly-oxo-anions. The literature has been surveyed from 1981 to approximately mid-1986.     

Local algebras in the representation of MV-algebras

In this paper we present several results about local MV-algebras, extending existing results given for MV-chains. The role of local MV-algebras in sheaf representation and weak boolean product is stressed and the relationship of local MV-algebras with varieties of MV-algebras is analyzed. Presented by S. Pulmannova. Received November 11, 2005; accepted in final form December 20, 2005.     

Elastic instability of the nano-structured state as an intrinsic probe to study the early formation stages of sol–gel derived (Pb<Subscript>1-x</Subscript>Ca<Subscript>x</Subscript>)TiO<Subscript>3</Subscript> thin films

A novel method to investigate the early formation stages of polycrystalline (Pb_1-xCa_x)TiO₃ (PCT) perovskite films by means of traditional Brillouin and micro-Brillouin spectroscopy (BS, mBS) is described in the present work. The films were prepared by chemical solution deposition (CSD) onto oxidized (100)Si substrates and treated at temperatures between 350–650 °C by rapid thermal processing (RTP). The elastic instability observed by Brillouin spectroscopy at the nano-structured state of the PCT films was used here to determine their crystallization temperatures. Coexistence of different nanocrystalline phases (e.g., pyrochlore, perovskite) in the films could also be detected by this technique. The reliability of these results is demonstrated by complementary information obtained by X-ray diffraction (XRD) and scanning force microscopy (SFM). The effects of the annealing temperature and of the Ca²⁺ content on the crystallization process of these films are also discussed. PACS 78.35.+c; 77.84.-s; 61.82.Rx     

Binding energy of impurity states in an inverse parabolic quantum well under magnetic field

 We have investigated the effects of the magnetic field which is directed perpendicular to the well on the binding energy of the hydrogenic impurities in an inverse parabolic quantum well (IPQW) with different widths as well as different Al concentrations at the well center. The Al concentration at the barriers was always x_max=0.3. The calculations were performed within the effective mass approximation, using a variational method. We observe that IPQW structure turns into parabolic quantum well with the inversion effect of the magnetic field and donor impurity binding energy in IPQW strongly depends on the magnetic field, Al concentration at the well center and well dimensions.     

Dark matter annihilation in the Galaxy

The awaited dark matter (DM) neutralino annihilation signal from the galactic halo crucially depends on the presence of small-scale clumps. A mass function of the DM small-scale clumps is calculated in the standard cosmological scenario. The final distribution of clumps in the Galaxy is influenced by their tidal destruction. The basic sources of clump destruction are (i) clumps of larger scales, (ii) the gravitational field of the galactic disk, (iii) the stars in the galactic bulge, and (iv) the stars in the galactic halo. The destruction of clumps due to their mutual tidal interactions is important at earl stages of hierarchical clustering and the galactic halo formation. The clumps surviving through the hierarchical clustering are continuously destroyed by interactions with the galactic disk and stars. It is shown that, among the Moon or Earth mass DM clumps surviving through the hierarchical clustering, only 20% will further survive near the Sun’s position mainly because of the tidal destruction by the galactic disk. This reduction of DM clump density significantly diminishes the expected DM annihilation signal from the galactic halo. The text was submitted by the authors in English.     

Control of the temperature hysteresis and diffuse dielectric anomaly in the temperature range of the ferroelectric-antiferroelectric phase transition in PbZr1 − x TixO3 (0.03 ≤ x ≤ 0.05) ceramics

The magnitudes of the temperature hysteresis and diffuse dielectric anomaly corresponding to the transition from the antiferroelectric phase to the ferroelectric phase in PbZr_{1 ? x} Ti_xO₃ (0.03 ≤ x ≤ 0.05) ceramics can be reversibly changed by varying the temperatures of heating and cooling in the course of thermocycling. The results obtained indicate that the antiferroelectric-ferroelectric transition in the PbZr_{1 ? x} Ti_xO₃ ceramics materials is a smeared first-order phase transition.