乙醇对超临界CO2中乙酰乙酸乙酯异构化平衡的影响

超临界流体（SCF）是物质所处的温度和压力同时高于其临界值时的流体．在超临界体系中存在特殊的分子间相互作用，从而使其具有诸如高压缩性、高扩散系数、强溶剂化力等许多独特的性质.在超临界流体研究领域引起人们普遍关注的问题之一是共溶剂效应（cosolventeffect），即在超     

Preparation of weak cation exchange packings based on monodisperse poly(glycidyl methacrylate-<Emphasis Type="Italic">co</Emphasis>-ethylene dimethacrylate) beads and their chromatographic properties

The monodisperse, macroporous poly(glycidyl methacrylate- co-ethylene dimethacrylate) beads were synthesized by a single-step swelling and polymerization method. Based on this media, a weak cation exchange (WCX) stationary phase for HPLC was synthesized by a new chemically modified method. The prepared resin has advantages for biopolymer separation, high column efficiency, low column backpressure, high protein mass recovery, and good resolution for proteins. The measured bioactivity recovery for lysozyme was 98+/-5%. The dynamic protein loading capacity of the WCX packings was 17.3 mg g(-1). The experimental results show that the synthesized WCX resin has very weak hydrophobicity.     

基于风险-均值分析的供应商选择与订单分配集成优化模型与求解

针对不确定环境下具有不同供应合约的供应商选择与订单分配问题,本文构建了基于风险-均值分析的模糊两阶段多周期集成优化模型。与传统的该问题研究并未充分考虑供应商选择与订单分配两阶段决策的交互影响不同,在该模型中,第一阶段供应商选择的评价目标依赖于后期实际运营中的订单分配决策;并考虑未来需求和实际运营成本的不确定性,引入在险价值和期望值两种决策准则对供应商选择方案的绩效进行评价。提出了该模型的分析求解方法,在险价值得以精确评估,期望值被控制在确定的误差范围内,并可以达到足够的精度要求。     

政府奖惩机制下零售商主导的闭环供应链微分博弈策略

本文在考虑政府奖惩机制下,研究零售商主导的闭环供应链中成员的动态均衡策略,其中制造商负责回收再制造,回收率随时间动态变化。分别构建了三种模式下的Stackelberg微分博弈模型:政府不对制造商和零售商实施奖惩机制、政府只对制造商实施奖惩机制以及政府同时对制造商和零售商实施奖惩机制。运用贝尔曼连续型动态规划理论,求解了三种模式下制造商和零售商的决策均衡结果并进行了对比分析,从消费者剩余价值和成员利润的视角证明了政府实施奖惩机制的有效性。最后通过算例对成员均衡策略进行了稳态分析和非稳态分析。研究结果表明:政府的奖惩机制能够正确引导闭环供应链成员做出最优决策,有利于减缓分散决策所带来的双重边际效应,提高消费者剩余价值。零售商分担回收责任会削减政府对制造商回收的激励作用,降低闭环供应链整体利润。相比之下,政府只对制造商实施奖惩机制是最优模式选择,可以同时提高经济和环保双重效益。     

Inclusion complexes of alcohols with α-cyclodextrin

Calorimetric studies of the inclusion complexes of straight and branched alcohols and of diols with alpha-cyclodextrin (-CD) have been carried out in water solvent. The data suggest that straight and branched chain alcohols enter the cavity of -CD alkyl end first. The hydroxyl group hydrogen bonds to the outer oxygen ring of the cyclodextrin. For branched chain alcohols the longer alkyl part of the molecule penetrates the -CD cavity up to the hydroxyl group. Diols form two hydrogen bonds to the outer oxygen ring of the cyclodextrin with some penetration into its interior.     

A New Method to Investigate the Clustering Phenomena in Supercritical Fluids

EstimationoflocaldensityofsolventaboutthesoluteSolvatochromicbehaviorsofspectroscopicprobesarewidelyusedtoestimatethesol-ventstrengthofsupercriticalfluids(SCF,).i-3lnthiswork,thesolvatochrondcshiftofthen-n*transitionbandforacetone(O.o37mo1.L-')insupercrihcal(SC)CO2wasde-terminedbyUVspectroscopytostUdythesolvationeffect.TheMcRae-BaylissexpressionbasedonthedielectriccontinUUInmodelgivestherelahonshipbetWeenso1vatochromicshiftandpo1arizabilityofnonPolarsolvents4-5asfollows:wherevisthewave…     

若干锰(Ⅲ)希夫碱配合物的合成和表征

合成了六种锰(Ⅲ)希夫碱配合物:Mn(bzacem)X(X~-=Cl~-,Br~-,I~-,NCS~-,NO_2~-)和Mn(bzacen)ClO_4·2H_2O,其中bzacen~(2-)为N,N′-二(苯甲酰丙酮缩)-乙二胺阴离子.用NMR法测定配合物在DMSO溶液中的有效磁矩值为4.46—4.63,表明为高自旋配合物,将电子光谱中的吸收带分别按配位场带、荷移带和配体带进行了归属,在配合物的红外光谱中,原配体H_2bzacen中的ν_(N-H)带消失,ν_(C-O)带移向低频,并对Mn-O、Mn-N和Mn-X的伸缩带进行了归属。     

Mn_3O(Salea)_2(C_2H_3O_2)_3·HC_2H_3O_2的合成、表征及放氧活性测定

合成了三核锰(Ⅲ)Schiff碱配合物:Mn_3O(Salea)_2(C_2H_3O_2)_3·HC_2H_3O_2(其中Salea~(2-)为水杨醛缩乙醇胺Schiff碱阴离子),经元素分析、磁矩、化合价、电导率、热分析、红外、紫外光谱等进行表征,并利用氧电极进行了放氧活性测试,发现在对苯醌存在下配合物能促使水分解释放氧气,其反应受温度、对苯醌和配合物浓度等因素影响,并提出了可能的放氧反应方程.     

对硝基氯苄与活性亚甲基化合物的反应

对硝基苄基衍生物可以与许多阴离子起单电子转移的亲核取代反应。Kornblum等以对硝基氯苄为底物,2-乙氧羰基香豆满-3-酮的钠盐为阴离子,作了深入的研究,得出对硝基氯苄与2-乙氧羰基香豆满-3-酮钠盐的C-烷化反应机理为自由基链式亲核取代反应。同时,Russell等提出对硝基氯苄与2-     

REDUCING NONSELECTIVE PROTEIN ADSORPTION AND CELL ADHESION ON POLYACRYLONITRILE FILMS BY COPOLYMERIZATION OF ACRYLONITRILE WITH α-ALLYL GLUCOSIDE

In this work, the surface properties of novel sugar-containing polymers, α-allyl glucoside (AG)/acrylonitrile (AN)copolymers, were studied by contact angle, protein adsorption and cell adhesion measurements. It was found that the contactangle of the copolymer films decreased from 68° to 30° with the increase of AG content in the copolymer. The adsorptionamount of bovine serum albumin (BSA) and the adhesive macrophage onto the film surface also decreased significantly withincreasing α-allyl glucoside content from 0 to 42 wt% in the copolymer. These preliminary results reveal that both thehydrophilicity and the biocompatibility of polyacrylonitrile-based membranes could be improved by copolymerizing acrylonitrile with vinyl carbohydrates.