Handedness inversion of chiral mesoporous silica: A diffuse-reflectance circular dichroism study

Temperature-depended handedness inversion in chiral mesoporous silica was investigated by diffuse-reflectance circular dichroism spectra.     

新型7-乙基-10-羟基喜树碱衍生物的合成及其体外抗肿瘤活性

以乙二醇为起始原料,依次经亲核取代和点击反应合成了一种7-乙基-10-羟基喜树碱(SN38)的新型葡萄糖残基衍生物(FSY02),其结构经¹H NMR, ¹³C NMR和HR-MS(ESI)表征。采用四甲基偶氮唑盐比色法（MTT法）研究了FSY02对人非小细胞肺癌细胞(A549)、人肝癌细胞(HepG2)、人结直肠癌细胞(SW-480)、人宫颈癌细胞(Hela)和人乳腺癌细胞(MDA-MB-231)的生长抑制作用。并采用Hoechst 33258染色和Western blot技术对给药后的结肠癌细胞凋亡情况和相关凋亡信号通路Caspase 3、 Bax和Bcl-2蛋白的表达情况进行了检测。结果表明：FSY02具有广谱抗癌活性,IC₅₀=0.118~4.295 μmol·L^-1,优于对照组伊立替康(IC⁵⁰=14.330~65.353 μmol·L^-1)。 Hoechst 33258染色及Western blot检测结果显示：FSY02通过上调Caspase 3和Bax的表达,下调凋亡抑制蛋白Bcl-2的表达诱导细胞凋亡。     

Synergistic effects of mono-component intumescent flame retardant grafted with carbon black on flame retardancy and smoke suppression properties of epoxy resins

Journal of Thermal Analysis and Calorimetry - A mono-component intumescent flame retardant named pentaerythritol phosphate melamine salt (PPMS) was grafted on the surface of carbon black (CB) to...     

Hybrid Organic–Inorganic Thermoelectric Materials and Devices

Hybrid organic–inorganic materials have been considered as a new candidate in the field of thermoelectric materials since the last decade owing to their great potential to enhance the thermoelectric performance by utilizing the low thermal conductivity of organic materials and the high Seebeck coefficient, and high electrical conductivity of inorganic materials. Herein, we provide an overview of interfacial engineering in the synthesis of various organic–inorganic thermoelectric hybrid materials, along with the dimensional design for tuning their thermoelectric properties. Interfacial effects are examined in terms of nanostructures, physical properties, and chemical doping between the inorganic and organic components. Several key factors which dictate the thermoelectric efficiency and performance of various electronic devices are also discussed, such as the thermal conductivity, electric transportation, electronic band structures, and band convergence of the hybrid materials.     

Vehicle–bridge interaction analysis under high-speed trains

The dynamic interaction between high-speed train and simply supported girders is studied by theoretical analysis and field experiment in this paper. The dynamic interaction model of the train–bridge system is established, in which the rigid-body dynamics theory, finite element method and wheel–rail displacement corresponding assumption are adopted for the vehicle model, bridge model and wheel–rail interaction model, respectively. The measured track irregularities are taken as the system excitation. The responses of a 24 m-span PC box girder bridge are calculated. The proposed analysis model and the solution method are verified through the comparison between the calculated results and the measured results.     

香烟燃烧产生的亚微米颗粒物动态粒径谱特征

应用SMPS (Scanning Mobility Particle Sizer)对ETS (Environmental Tobacco Smoke)亚微米颗粒物的粒径谱演变进行了测量分析.结果发现,ETS颗粒物在10~500nm范围内呈对数正态单峰分布,数量粒径谱和质量粒径谱的演化有类似的递减趋势,但其浓度衰减率有明显的不同.分析得知,由于在演化过程中颗粒物直径是动态变化的,并不能用简单的方法获得凝并和沉积损失率.     

引射式增压装置的设计与试验研究

本文研究以蒸汽为工作流体的引射式增压装置,蒸汽引射水后利用自身的动力使水得到增压,使引射器出口水的压力超过入口蒸汽的压力.同时,由于蒸汽的凝结实现换热,水温得以提升,该装置义可视为一个直接接触式换热器,增压的特点使该装置具有特殊的应用前景,如可用于核电的非能动安伞系统,然而有关设计的研究却较少.本文对基于两相流激波的引射式增压装置进行研究,给出其设计方法,并进行了试验研究,得到了增压效果.试验结果与设计结果吻合,说明了设计的可靠性.     

Closed-form Analysis of Lossy Cosine-Squared Tapered Nonuniform Transmission Lines

The rigorous analytical solutions and the ABCD matrix of the lossy Cosine-Squared tapered nonuniform transmission lines (CSTNTL) are presented in this paper. According to different boundary conditions, the unique solution is obtained mathematically. Through the numerical calculations based on analytical solutions, the distributed voltages and currents in different terminated cases are shown to explain the transmission characteristics of CSTNTL. Especially in the lossy case the distributed power values are simulated to show the attenuation phenomenon.     

Associated Production of Scalars and New Gauge Bosons from a Little Higgs Model at the LHC

The littlest Higgs model with T-parity （LHT model） predicts the existence of the T-odd scalars （Φ^±, Φ^0, and Φ^P）. We consider the production of these new particles associated with T-odd gauge bosons at the Large Hadron Collider （LHC）. It is found that the partonic process qq^1 →Φ^＋ BH can generate a number of the characteristic signal events with a charged lepton and large missing energy at the LHC.