REM树脂的制备及亲核加成应用研究

用Mitsunobu反应及丙烯酰氯酰化反应制备了用于固相有机合成的载体REM树脂，将REM树脂与苄胺加成，考查了所合成REM树脂的反应性能，并通过元素分析测定氮含量，推出REM树脂的烯丙基固载量。利用所合成的REM树脂进行了与胺、酚的加成反应动力学研究。结果表明，REM树脂与脂肪族伯胺和促胺的加成反应能够进行，与苯胺不发生反应；REM树脂与酚不能发生亲核加成反应。     

About the focal mechanism of Friuli earthquake occurred on May 6, 1976

Summary We are going to present the focal-mechanism solution of Fruili earthquake occurred on May 6, 1976, as it results from the analysis, on original seismograms, of the polarities of initial longitudinal waves obtained in 92 seismic stations. The polarities so obtained have been reported on the projection which represents the surface of the Earth and the solution has been drawn, directly, from the study of the resulting distribution, by establishing through Gr?fe's theory the two couples of forces considered as the sources of the seism at the focus. At last, a comparison has been carried out with the solution already obtained by other authors.

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Riassunto Si presenta la soluzione del meccanismo focale del terremoto del Fruili del 6/5/1976 ottenuta dallo studio, sui sismogrammi originali, della polarità delle onde longitudinali iniziali, quale si è presentata in 92 stazioni sismiche vicine e lontane. Le polarità ottenute sono state riportate sulla superficie della Terra e la soluzione è stata ricavata direttamente dallo studio della distribuzione così ottenuta, definendo mediante la teoria di Gr?fe le due coppie di forze che hanno agito all'ipocentro. Un confronto è stato infine eseguito con le soluzioni in precedenza ottenute da altri autori.

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Резюме Предлагается решение фокального механизма землетрясения, имевшего место в Фриули 6 мая 1976 г. Решение есть результат анализа исходных сейсмограмм, которые получены на 92 сейсмнческих, удаленнынных и близких. Полученные пояьрности представлены в проекции на поверхность Земли. Решение получено непосредственно из исследования результируюшего распределения, которое следует из теории Грефа для для двух пар сил, представляюших источники землетрясения в фокусе. В заключение проводится сравнение с решением, полученным ранее другими авторами.

     

晶体学与准晶体学点群的母子群关系

依据群论，得出了准晶体学点群的直积或半直积推导算式；依据结晶学理论，绘出了五角、八角、十角和十二角晶系各点群的极赤投影图.据此推导出了每一个准晶体学点群的全部最大子群，从而推导并绘制出了三维晶体学和准晶体学点群之间的母子群关系(60个点群的“家谱”).该“家谱”以最大子群链的图解形式直观地给出了每个点群的最小母群和最大子群. 关键词： 准晶体 晶体 点群 最大子群 最小母群 群链     

基于LiCo0.8M0.2O2 (M=Ni,Zr)薄膜的全固态薄膜锂电池

用射频磁控溅射结合传统退火的方法制备LiCo0.8M0.2O2 (M=Ni,Zr)阴极薄膜．X射线衍射、拉曼光谱、扫描电子显微镜等手段表征了不同掺杂的LiCo0.8M0.2O2薄膜．结果显示,700℃退火的LiCo0.8M0．2O2薄膜具有类似α-NaFeO2的层状结构．通过对不同掺杂锂钴氧阴极的全固态薄膜锂电池Li／LiPON／LiCo0.8M0.2O2的电化学性能研究表明,电化学活性元素Ni的掺杂使全固态电池具有更大的放电容量(56μAh／cm2μm),而非电化学活性元素Zr的掺杂使全固态电池具有更好的循环稳定性．     

实际量子密钥分配扩展BB84协议窃听下的安全性分析

考虑强衰减激光脉冲技术实现的准单光子源和量子信道损耗以及窃听者Eve窃听能力有限等实际情况， 提出了一种窃听装置；同时对扩展BB84协议的各种窃听做了全面分析，计算得出发送者Alice/窃听者Eve所获得的交互信息量和发送者Alice/接收者Bob所能容忍的误码率上限，以此作为检测量子信道安全性的标准，同时得出Breidbart基/分束攻击相结合的方法是比截取/重发更为有效的窃听方案.     

基于扩散势能和自由体积的自扩散系数模型

在考虑自由体积和局部临界扩散势能的基础上,提出一种新的计算自扩散系数模型,并给出新模型中各个因子物理含义．同时还提出一种计算局部临界扩散势能的新方法,并应用于新模型．另外将衍生van der Waals状态方程应用于求解自由体积,式中所需径向分布函数由Morsali-Goharshadi方程得到．在相同条件下,新模型比原自由体积模型更准确．     

单链表在离子发动机光学系统粒子模拟中的应用

 目前离子发动机光学系统数值模拟大多采用PIC方法，由于该方法需要跟踪单个粒子的运动，因此需要存储每个粒子的位置信息与运动信息。传统的粒子模拟程序中，保存粒子信息大多采用数组的方式，但是采用这种方式存在弊端，例如对粒子总数变化的自适应不好。基于此开发了一种使用链式存储结构的粒子模拟程序，该程序使用带头节点的单向链表存储粒子信息。使用基于链式存储结构的PIC方法对离子发动机光学系统进行了粒子模拟，验证了链式粒子信息存储方法在粒子模拟中的可用性。模拟表明：（1）在粒子模拟中采用链式存储结构存储粒子信息，无需预先指定最大粒子总数，程序可自适应粒子总数的变化，因此无需进行试算，节省了计算时间；（2）在粒子模拟中采用链式存储结构，由于不存在内存资源的浪费，因而可显著提高程序的存储效率与计算效率。     

Photoinduced Transformation between Charge Carrier and Spin Carrier in Polymers

By dynamical simulations, we show a transforming process between neutral soliton （spin carrier） and charged soliton （charge carrier） in polymers via photo-excitation, taking a polaron as the transitional bridge. It is photoinduced transformation between spin carrier and charge carrier. In this way, we demonstrate an access for polymers to be applied to spintronics.     

Anchoring Properties of Nematic Liquid Crystals Studied Using the Attenuated Total Reflection Method

By using the attenuated total reflection method associated with the excitation of surface plasmons, the tilt angle of the liquid crystal director and its gradient at the surface are measured in a planar nematic cell as a function of the applied voltage. The surface anchoring anisotropy δπ of the liquid crystal and the surface elastic constant k_s, are found to be δπ = 0.288 erg/cm and k_s, = 9·12 × 10^-11 erg, respectively, when the boundary condition suggested by Barbero et al is used. The theoretical and experimental values obtained with this boundary condition and that of Mada are discussed. The results show that the boundary condition proposed by Barbero et al is in better agreement with the experiment.