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111.
112.
A simple, selective, rapid, and economical reversed phase high performance liquid chromatography(RP-HPLC) method for the determination of doxofylline in the commercial dosage form has been developed and validated. The separation
and quantification were achieved on an HiQ Sil C 18 W column using a mobile phase of acetonitrile: buffer (50: 50), pH 3,
at a flow rate of 1 mL/min with detection of analyte at 272 nm. The separation was achieved within 3.1 ± 0.3 min for doxofylline
sample. The method showed good linearity in the range of 10–80 μg/mL. The intra and inter day RSD ranged from 0.37–0.53%.
The recovery (mean ± S.D.) of low, middle and high concentrations were 100.04 ± 0.80, 100.01 ± 0.20, 100.07 ± 0.30 respectively.
Limit of detection and limit of quantification were 0.03 and 0.1 μg/mL, respectively. 相似文献
113.
Ravi Mosurkal Lynne A. Samuelson Kenneth D. Smith Phillip R. Westmoreland Virinder S. Parmar Fadong Yan 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(11):942-946
Composites of titanium dioxide (TiO2) nanoparticles and biocatalytically synthesized dimethylsiloxane copolyamides were prepared, and their thermal and flame-retardant properties were investigated. The flammability properties such as heat release capacity and total heat release were measured from microscale cumbustion calorimetry (MCC). The thermal degradation temperatures, char yields, and the heat-release capacities of these nanocomposites were significantly improved over the pure polymers. The heat-release capacities of the siloxane copolymer nanocomposites with 20wt% of TiO2 were found to be 167 and 129 J/g K, which is a 35% less than the pure polymers (260 and 194 J/g K, respectively). The SEM/EDAX surface-analysis studies on nanocomposite films and their char revealed that nanocrystalline-TiO2 plays an important role in forming carbonaceous silicate char on the surface as a protective layer. 相似文献
114.
A series of metal complexes of Zn(II) and Hg(II) having the general composition [ML2]X2 with thiosemicarbazide have been prepared and characterized by elemental chemical analysis, molar conductance, and spectral
(IR and mass) studies. The IR spectral data suggest the involvement of sulfur and terminal amino nitrogen in coordination
to central metal ion. On the basis of spectral studies, a tetrahedral geometry has been assigned for the Zn(II) and Hg(II)
complexes. Thiosemicarbazide and its metal complexes have been tested in vitro against a number of microorganisms in order
to assess their antimicrobial properties.
The article is published in the original. 相似文献
115.
A series of metal complexes of cobalt(II), nickel(II), and copper(II) having the general composition [M(L)2X2] with thioacetamide have been prepared and characterized by elemental chemical analysis, molar conductance, magnetic susceptibility
measurements, mass, IR, EPR, and electronic spectral studies. The IR spectral data suggests the involvement of sulfur and
amino nitrogen in coordination to central metal ion. On the basis of spectral studies, an octahedral geometry has been assigned
for the cobalt(II) and nickel(II) complexes whereas tetragonal geometry for copper(II) complexes. Thioacetamide and its metal
complexes have been tested in vitro against a number of microorganisms in order to assess their antimicrobial properties. 相似文献
116.
Rayaprol S. Parmar Rohini Kuberkar D. G. Chakraborty Keka R. Krishna P. S. R. Ramanadham M. 《Pramana》2004,63(2):213-219
Structural studies on Dy-substituted La-2125 type superconductors have been carried out by neutron diffraction experiments at room temperature using a monochromatic neutron beam of wavelength (λ) = 1.249 Å. A series of samples with La2-xDyxCa2xBa2Cu4+2xOz stoichiometric composition, forx = 0.1–0.5, have been studied for their structural properties. A tetragonal Y-123 unit cell was taken as the starting model for the Rietveld analysis. All the samples fit into the starting model, with no structural transition taking place with increasing dopant concentration. The results of Rietveld analysis and structural properties will be discussed in detail.
相似文献117.
118.
The synthesis of coumarin derivatives via Pechmann reaction using anhydrous FeCl3 as Lewis acid catalyst in ionic liquid medium has been carried out. The best results were obtained (yields as high as 89%) with ionic liquids having bis(triflic)imide as a counteranion. The ionic liquid could easily be recovered and reused. 相似文献
119.
Shrutisagar Dattatraya Haveli Sudipta Roy Vibha Gautam Ketan C. Parmar Srinivasan Chandrasekaran 《Tetrahedron》2013,69(52):11138-11143
NIS/NaN3 mediated ring opening of various donor–acceptor cyclopropanes has been investigated. The study shows the necessity of the donor oxygen lone pair in such ring opening reactions. This methodology has been utilized in the synthesis of C-1 linked pseudodisaccharides through the use of click chemistry. 相似文献
120.
A facile method has been developed for the ester ification of halides/alcohols/olefins with carboxylic acids using iron(III) perchlorate. 相似文献