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991.
硫脲在酸性溶液中的表面增强拉曼光谱 总被引:1,自引:0,他引:1
本文在电镀沉积的银衬底上,研究了硫脲分子在酸性溶液中的表面增强拉曼散射。结果表明,硫脲分子是通过硫原子倾斜着吸附在银表面;当溶液中的HCl浓度增加时,在银表面吸附的硫脲分子面更加偏离银表面的法线方向;实验结果还暗示,该体系存在着较强的化学增强机制。 相似文献
992.
Whenφ(4030) is considered as a molecule formed from D* and D* and not as an excited states of J/φ,then all excited states of J/φ may be described by a wave equation of simple harmonic oscillator, with eigen-values equal to the squared masses of these states. The same conclusion is also obtained for γ particles. 相似文献
993.
The independent particle approximation is used to treat the bound state problems in the quark model. The solution for meson states obtained in this approximation is the same as that obtained from the Bethe-Salpeter equation. The solution for the baryon states is also obtained. The mass spectra of mesons and baryons determined from these equations are in agreement with the experiment. 相似文献
994.
995.
The calculations of the whole energy spectrum of Zns:Ni2+ at normal pressure and pressure-induced shifts of its levels have been carried out on the basis of the theory of pressure-induced shifts and the diagonalization of the complete d8 energy matrix in a regular tetrahedral field. The calculated results are in very good agreement with experimental data at normal and high pressures. The comparison between the results of ZnS:Ni2+ and Mg0:Ni2+ indicates that the comlency of ZnS:Ni2+ is obviously stronger than the one of MgO:Ni2+;the expansion of electron wavefunctions of ZnS:Ni2+ under pressure is obviously larger than that of MgO:2+; and the pressure-induced shifts of levels of znS:NiZf show strong nonlinearity. 相似文献
996.
997.
998.
By using strong-field scheme, the complete d5 energy matrix with D2d symmetry has been constructed. Then, by diagonalization of this matrix at normal and various pressures,the whole energy spectrum [including the ground-state zero-field-splitting (GSZFS)], its PS and the g factor of the ground state for zns:Mn2+ have uniformly been calculated. According to the eigenfunctions and PS, the new assignments of five absorption bands have been given.The variation of tetragonal field with pressure makes a main contribution to the pressureinduced shift (PS) of GSZFS of zns:Mn2+, which supports the existence of tetragonal Jahn-Teller distortion in zns:Mn2+. It is found that when P≥62 kbar, t24(3T1)e4T1 merges with t2e4 2T2, which has to be taken into account in the calculation of PS of the fifth band in the range of 1 bar ~ 95 kbar. It is demonstrated that the Mn2+ ions in ZnS:Mn2+ have tetrahedral coordination, and the difference between ζ and ζ' caused by the covalency effect is very important for GSZFS. The physical essentials of typical levels, GSZFS and their PS have been revealed. By taking into account the influence of covalency on t23(4A2)e2(3A2)4A1 and t23(2E)e2(3A2)4E, the positon of the third absorption band at normal pressure has been estimated. 相似文献
999.
电感耦合等离子体原子发射光谱法(ICP-AES)测定铜磁铁矿中铜、锰、铝、钙、镁、钛和磷的含量 总被引:1,自引:0,他引:1
通过样品处理、干扰实验、方法检出限、准确度和精密度实验,确定了最佳实验条件,建立了电感耦合等离子体-原子发射光谱法(ICP-AES)测定铜磁铁矿中铜、锰、铝、钙、镁、钛和磷含量的方法。试料经盐酸、硝酸、氢氟酸、高氯酸分解,用盐酸溶解盐类,过滤,采用电感耦合等离子体原子发射光谱法同时测定滤液中铜、锰、铝、钙、镁、钛和磷的含量。方法检出限为锰、钛和磷小于0.00085%,其它元素小于0.0054%,分析结果与分光光度法、X射线荧光光谱法(XRF)和原子吸收光谱法(AAS)分析结果一致,8个实验室对5个水平样品进行协同实验给出了方法的精密度。 相似文献
1000.