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131.
A modified technique of the self-absorption method has been developed and applied to natural mercury afterglows. A narrow light-emitting layer is produced inside an absorption tube by external pumping at the moment of measuring the afterglow. 相似文献
132.
133.
Minoru Ishikura Machiko Kamada Izumi Oda Tsukasa Ohta Masanao Terashima 《Journal of heterocyclic chemistry》1987,24(2):377-386
The reaction of various lithium tributylheteroarylborates with allylic bromides in the presence of copper(I) cyanide furnished the regioselective allylation at the heteroaryl ring. 相似文献
134.
135.
Minoru Umeda Hiroyuki Ojima Mohamed Mohamedi Isamu Uchida 《Journal of Polymer Science.Polymer Physics》2002,40(11):1103-1109
Methanol vapor‐induced membranous changes in a cast‐coated Nafion thin film were studied through current–voltage (I–V) characteristics with an interdigitated microarray (IDA) electrode and atomic force microscopy (AFM). The obtained I–V curves showed that the as‐prepared Nafion film was stable under humidified nitrogen gas; however, the I–V profile dramatically changed with exposure to methanol vapor. Next, the morphology of the film was compared before and after methanol exposure with AFM images. On the basis of our observations, we found that the as‐prepared film had an irregularly complicated microstructure, whereas the structure became homogeneous in appearance after 30 min of exposure to methanol gas. The alternating‐current conductivity data, showing almost the same magnitude before and after exposure, strongly suggested that the I–V profile shift was based on a change in an electrode reaction mechanism induced by a change in the junction at the Nafion/IDA electrode interface. Furthermore, the methanol vapor‐pre‐exposed Nafion was stable for further exposure to methanol vapor, water vapor, or both. With the stabilized film used in combination with the IDA electrode, a reversible change in the magnitude of the current was observed when the methanol/water vapor ratio was varied. This indicated that the electrode reaction had good reproducibility after the treatment. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1103–1109, 2002 相似文献
136.
Nobuoki Eshima Claudio Giovanni Borroni Minoru Tabata Takeshi Kurosawa 《Entropy (Basel, Switzerland)》2021,23(2)
This paper proposes a method for deriving interpretable common factors based on canonical correlation analysis applied to the vectors of common factors and manifest variables in the factor analysis model. First, an entropy-based method for measuring factor contributions is reviewed. Second, the entropy-based contribution measure of the common-factor vector is decomposed into those of canonical common factors, and it is also shown that the importance order of factors is that of their canonical correlation coefficients. Third, the method is applied to derive interpretable common factors. Numerical examples are provided to demonstrate the usefulness of the present approach. 相似文献
137.
Spectroscopic Properties of Amine‐substituted Analogues of Firefly Luciferin and Oxyluciferin 下载免费PDF全文
Michio Kakiuchi Soichiro Ito Minoru Yamaji Vadim R. Viviani Shojiro Maki Takashi Hirano 《Photochemistry and photobiology》2017,93(2):486-494
Spectroscopic and photophysical properties of firefly luciferin and oxyluciferin analogues with an amine substituent (NH2, NHMe and NMe2) at the C6' position were studied based on absorption and fluorescence measurements. Their π‐electronic properties were investigated by DFT and TD‐DFT calculations. These compounds showed fluorescence solvatochromism with good quantum yields. An increase in the electron‐donating strength of the substituent led to the bathochromic shift of the fluorescence maximum. The fluorescence maxima of the luciferin analogues and the corresponding oxyluciferin analogues in a solvent were well correlated with each other. Based on the obtained data, the polarity of a luciferase active site was explained. As a result, the maximum wavelength of bioluminescence for a luciferin analogue was readily predicted by measuring the photoluminescence of the luciferin analogue in place of that of the corresponding oxyluciferin analogue. 相似文献
138.
Reaction of 2-propargylphenylcarbamates with diphenyliodonium salts via Meyer-Schuster rearrangement
Hideki Minami Noriko Okamoto Takuya Sueda Takatsugu Sakaguchi Minoru Ishikura Reiko Yanada 《Tetrahedron letters》2017,58(45):4277-4280
The syntheses of 2,3-dihydro-4-quinolones from 2-propargylphenylcarbamates by one-pot tandem process that involves Meyer-Schuster rearrangement or arylative Meyer-Schuster rearrangement/Michael addition of carbamate nitrogen to the resulting vinyl ketones have been developed. Phenylcarbamates tethering tertiary propargyl alcohols underwent arylative Meyer-Schuster rearrangement/Friedel-Crafts alkylation to produce 2,3-dihydroindenones. 相似文献
139.
Though preparation procedures of heterogeneous Ziegler‐Natta catalysts for propylene polymerization are sophisticated, it is uncertain whether the nature of the active sites is similar or different for different preparation procedures. In this study, the effects of preparation procedures on the nature of the active sites were investigated by stopped‐flow polymerization in combination with microstructure analysis of polymers. Both basic and advanced types of catalysts showed the same two kinds of isospecific active site, which indicated little influence of the preparation method on the active site structure. On the contrary, the ratios of the two kinds of isospecific sites were not the same, resulting in variation of average polymer properties.
140.
We consider positive solutions of elliptic partial differential equations on non-compact domains of Riemannian manifolds. We explicitly determine Martin compactifications and Martin kernels for a wide class of elliptic equations in skew product form by exploiting parabolic Martin kernels for associated parabolic equations. 相似文献