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991.
基于全固态电子器件和零中频机制,设计了基于调频连续波的太赫兹无损检测成像系统。所提系统的有效频率范围为9.375~13.75 GHz,经24倍频后自由空间中的频率范围为0.225~0.330 THz。采用单个喇叭天线与定向耦合器结合,实现收发一体,并利用光学透镜组对太赫兹波束进行准直聚焦。对准光系统的波束质量进行了优化,提高了系统的信噪比,确保了在现有参数条件下的最佳空间分辨率。同时,采用相位聚焦的方法对系统进行了非线性矫正,使得深度分辨率接近理论分辨率。系统采用直线扫描和旋转扫描组合的方式,实现了柱坐标三维数据的获取。利用所提系统对高压绝缘端子进行了检测评估,并重构了全视角透视图像,实现了目标三维结构在实空间和像空间的孪生对应。此外,所提系统能够准确地显示绝缘端子内部的异常区域,有助于直观地评估被检测目标的内部状态,进而可以进一步满足工业领域无损检测的需求。 相似文献
992.
Yufeng Liang Shiqin Miao Jie Mao Dr. Shekaraiah Devari Maricarmen Gonzalez Prof. Dennis Bong 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(2):e202103616
We hypothesize that programmable hybridization to noncanonical nucleic acid motifs may be achieved by macromolecular display of binders to individual noncanonical pairs (NCPs). As each recognition element may individually have weak binding to an NCP, we developed a semi-rational approach to detect low affinity interactions between selected nitrogenous bases and noncanonical sites in duplex DNA and RNA. A set of fluorogenic probes was synthesized by coupling abiotic (triazines, pyrimidines) and native RNA bases to thiazole orange (TO) dye. This probe library was screened against duplex nucleic acid substrates bearing single abasic, single NCP, and tandem NCP sites. Probe engagement with NCP sites was reported by 100–1000× fluorescence enhancement over background. Binding is strongly context-dependent, reflective of both molecular recognition and stability: less stable motifs are more likely to bind a synthetic probe. Further, DNA and RNA substrates exhibit entirely different abasic and single NCP binding profiles. While probe binding in the abasic and single NCP screens was monotonous, much richer binding profiles were observed with the screen of tandem NCP sites in RNA, in part due to increased steric accessibility. In addition to known binding interactions between the triazine melamine (M) and T/U sites, the NCP screens identified new targeting elements for pyrimidine-rich motifs in single NCPs and 2×2 internal bulges. We anticipate that semi-rational approaches of this type will lead to programmable noncanonical hybridization strategies at the macromolecular level. 相似文献
993.
Xueping Liu Ji‐Qiang Chen Minghui Zhang Ying Wu Miao Yang Ke Zhang 《Journal of polymer science. Part A, Polymer chemistry》2019,57(17):1811-1820
A versatile method was introduced to prepare cyclic polymers from both conjugated and unconjugated vinyl monomers. It was developed on the combination of the RAFT polymerization and the self‐accelerating double strain‐promoted azide‐alkyne click (DSPAAC) reaction. In this approach, a switchable chain transfer agent 1 was designed to have hydroxyl terminals and a functional pyridinyl group. The protonation and deprotonation of pyridinyl group endowed the chain transfer agent 1 with a switchable control capability to RAFT polymerization of both conjugated and unconjugated vinyl monomers. Based on this, RAFT polymerization and the following hydroxyl end group modification were used to prepare various azide‐terminated linear polymers including polystyrene, poly(N‐vinylcarbazole), and polystyrene‐block‐poly(N‐vinylcarbazole). Using sym‐dibenzo‐1,5‐cyclooctadiene‐3,7‐diyne (DBA) as small linkers, the corresponding cyclic polymers were then prepared via the DSPAAC reaction between DBA and azide terminals of the linear precursors. Due to the self‐accelerating property of DSPAAC reaction, this bimolecular ring‐closing reaction could efficiently produce the pure cyclic polymers using excess molar amounts of DBA to linear polymer precursors. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 1811–1820 相似文献
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996.
Wei Wu Xingfeng Sheng Yusheng Qin Lijun Qiao Yuyang Miao Xianhong Wang Fosong Wang 《Journal of polymer science. Part A, Polymer chemistry》2014,52(16):2346-2355
Due to the concern on residue toxic metal in biodegradable poly(propylene carbonate) (PPC), soil tolerant and heavy metal free aluminum complexes, that is, bifunctional aluminum porphyrin catalysts bearing quaternary ammonium salts on the ligand framework were prepared. Variation of the quaternary ammonium anion and the axial ligand had dramatic effects on the catalytic activity of resultant complex, among which complex 3b yielded perfectly alternative PPC with high molecular weight and relatively narrow polydispersity, and its TOF reached 3,407 h?1 at [PO]/[cat.] ratio of 20,000 at 110 °C, although the PPC selectivity was 71%. By introducing specific substituent on the ligand framework, the electronic environment at the active center can be changed, among which complex 5b bearing tertiary butyl‐functionalized aryl substituents exhibited a TOF of 449 h?1 at [PO]/[cat.] ratio of 5,000 at 70 °C, with PPC selectivity of 92% and number average molecular weight of 36 kg mol?1. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 2346–2355 相似文献
997.
Weiben Chen Simeng Zhang Dr. Gaole Dai Dr. Ying Chen Miao Li Xiaoyu Zhao Prof. Yulan Chen Prof. Long Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(2):469-473
A series of symmetric squarylium dyes (SQDPA-X) with different halogen (X=F, Cl, Br, I) substituents have been developed. The photophysical properties could be facilely tuned by the halogen modulation effects. The strategy of incorporating different halogen substitutions into AIE active luminogens enables a facile approach for exploring new intriguing organic fluorescent dyes. 相似文献
998.
Chen Mulan He Miao Liu Mingxue Dong Faqin Wei Hongfu Nie Xiaoqin 《Journal of Radioanalytical and Nuclear Chemistry》2019,322(2):731-742
Journal of Radioanalytical and Nuclear Chemistry - Photocatalytic removal of U(VI) has attracted much attention due to its advantages such as no secondary pollution and less energy... 相似文献
999.
Bing Li Tiankuo Wang Dr. Xin Wang Dr. Xin Wu Chenyu Wang Prof. Feng Miao Prof. Meng Qin Prof. Wei Wang Prof. Yi Cao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(34):7991-7997
Aqueous ultrasonic exfoliation by using proteins as dispersants allows for the simultaneous production and biofunctionalization of single- or few-layered 2D materials for biomedical applications. However, the production yield and quality are always a concern. Here, the production of stable, low-defect, and biofunctionalized 2D flakes of graphene by using bifunctional chimeric polyproteins as dispersants is shown. The chimeric polyproteins contain an amphiphilic protein, hydrophobin (HFBI), to serve as the anchoring point that strongly binds to graphene layers and tandem repeats of a globular protein, GB1, to respond and transmit the ultrasonic force for efficient mechanical exfoliation. For this reason, the production yield is much higher than those obtained by using HFBI alone. Moreover, the yield, lateral size and number of layers can be fine-tuned by the number of GB1 repeats. Other 2D materials, such as MoS2 and WS2, can also be exfoliated in the same manner, demonstrating the versatility of this approach. 相似文献
1000.
Meccanica - Dynamic equivalent modeling is convenient to the vibration controller design of large space truss structures. Consequently, it is important to study the effectiveness of designed... 相似文献