首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   31573篇
  免费   620篇
  国内免费   617篇
化学   12541篇
晶体学   300篇
力学   1497篇
综合类   15篇
数学   9242篇
物理学   9215篇
  2023年   69篇
  2022年   67篇
  2021年   139篇
  2020年   156篇
  2019年   133篇
  2018年   1290篇
  2017年   1542篇
  2016年   847篇
  2015年   703篇
  2014年   638篇
  2013年   892篇
  2012年   3429篇
  2011年   2596篇
  2010年   1968篇
  2009年   1747篇
  2008年   710篇
  2007年   772篇
  2006年   749篇
  2005年   4528篇
  2004年   4006篇
  2003年   2360篇
  2002年   538篇
  2001年   325篇
  2000年   142篇
  1999年   234篇
  1998年   152篇
  1997年   102篇
  1996年   92篇
  1995年   63篇
  1994年   66篇
  1993年   49篇
  1992年   193篇
  1991年   170篇
  1990年   155篇
  1989年   128篇
  1988年   111篇
  1987年   75篇
  1986年   49篇
  1985年   43篇
  1984年   41篇
  1983年   32篇
  1976年   80篇
  1975年   38篇
  1974年   41篇
  1973年   49篇
  1972年   39篇
  1970年   34篇
  1969年   37篇
  1968年   35篇
  1966年   37篇
排序方式: 共有10000条查询结果,搜索用时 900 毫秒
81.
正则带的半格结构   总被引:3,自引:1,他引:2  
孔祥智  袁志玲 《数学进展》2002,31(5):476-482
Petrich解决了一般带的构造定理(见[1]或[2]),在此基础上,我们将证明正则带(满足等式axya=axaya的带)的一些特征,并给出一个带为正则带或右似正规带(满足等式xya=xaya的带)的充分必要条件,这些结果是Yamada和Kimura的关于正规带(满足等式axya=ayxa的带)的结果的推广,正规带被他们描述为矩形带的强半格(见[1]或[3])。  相似文献   
82.
分别通过理论和实验研究了周期性极化的钽酸锂(PPLT)倍频宽线宽准连续掺镱双包层光纤放大激光.PPLT样品长为40 mm,极化周期为7.67 μm.基频光的中心波长为1064 nm,线宽约为6 nm.从基频光的光谱特性出发,利用超晶格倍频理论,解释了实验中获得的倍频温度与二次谐波功率之间的关系.在基频光的功率为2.2 W时,获得的宽线宽光纤激光倍频效率为1.8%.  相似文献   
83.
A set of a-SiOx:H (0.52 <x< 1.58) films are fabricated by plasma-enhanced-chemical-vapor-deposition (PECVD) method at the substrate temperature of 250°C. The microstructure and local bonding configurations of the films are investigated in detail using micro-Raman scattering, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). It is found that the films are structural inhomogeneous, with five phases of Si, Si2O:H, SiO:H, Si2O3:H and SiO2 that coexist. The phase of Si is composed of nonhydrogenated amorphous silicon (a-Si) clusters that are spatially isolated. The average size of the clusters decreases with the increasing oxygen concentration x in the films. The results indicate that the structure of the present films can be described by a multi-shell model, which suggests that a-Si cluster is surrounded in turn by the subshells of Si2O:H, SiO:H, Si2O3:H, and SiO2.  相似文献   
84.
A general method to convert single-stranded, chemically synthesized oligonucleotides into cloned duplexes is described. Oligonucleotides supplied with 3'-terminal extensions that are complementary to 3'-protruding ends obtained by certain restriction enzymes can be cloned either directly or with the help of an adapter molecule into double-stranded vectors. Two methods have also been developed for consecutive cloning applications. According to these methods, the synthetic oligonucleotides (and their enzymatically prepared complementary strands) are joined, one after the other, inside a cloning vector, each joining requiring one cloning step. Synthetic genes are thus built up from oligonucleotides corresponding to only one strand of the DNA. The sequential assembly of the cloned duplex takes place in the 5' to 3' direction. Each oligonucleotide is supplied with a four-nucleotide-long 3'-terminal extension, but this sequence is eliminated when the joining takes place, leaving no limiting sequence between the oligonucleotides. The two consecutive cloning methods, the adapter and the polycloning site methods, are illustrated by the assembly of short artificial genes.  相似文献   
85.
The photolysis reactions of three compounds commonly used as a sunscreen agents, Parsol 1789 (1-[4-(1,1-dimethylethyl)phenyl]-3-(4-methoxyphenyl)-1,3- propanedione), Oxybenzone ((2-hydroxy-4-methoxyphenyl)phenyl-methanone) and Padimate O (2-ethylhexyl-4-(dimethylamino)benzoate), were investigated to provide a chemical background to aid in the understanding of the photosensitization of the sunscreen agents. Photolysis was carried out in cyclohexane for 70–140 h using a mercury vapor lamp (450W) without excluding oxygen.

Irradation of Parsol 1789 in cyclohexane yielded tert-butylbenzene, p-tert-butylbenzoic acid and p-methoxybenzoic acid; products obtained from the combination of the sunscreen with the solvent included the cyclohexyl esters of p-methoxybenzoic acid, p-tert-butylbenzoic acid and methanoic acid; products obtained from the solvent included cyclohexanol, cyclohexanone and dicyclohexyl ether.

Irradiation of Oxybenzone in the cyclohexane for 100 h produced no detectable products by either gas or liquid chromatographic analysis. Oxybenzone was recovered unchanged and no products were observed from the photoinitiated reaction of oxygen with the solvent.

Irradiation of Padimate O in cyclohexane yielded the ethylhexyl esters of p-aminobenzoic acid, p-monomethylaminobenzoic acid and p-dimethylamino (o/m)-methylbenzoic acid, as well as products from the photoinitiated reaction of oxygen with the solvent.  相似文献   

86.
We use a newly introduced concept of neocompactness to study problems from metric fixed point theory. In particular, we give a sufficient condition for a superreflexive Banach space X to have the fixed point property and obtain shorter proofs of some well-known results in that theory.  相似文献   
87.
88.
The properties of the excitonic luminescence for nanocrystalline ZnO thin films are investigated by using the dependence of excitonic photoluminescence (PL) spectra on temperature. The ZnO thin films are prepared by thermal oxidation of ZnS films prepared by low-pressure metalorganic chemical vapor deposition (LP-MOCVD) technique. The X-ray diffraction (XRD) indicates that ZnO thin films have a polycrystalline hexagonal wurtzite structure with a preferred (0 0 2) orientation. A strong ultraviolet (UV) emission peak at 3.26 eV is observed, while the deep-level emission band is barely observable at room temperature. The strength of the exciton-longitudinal-optical (LO) phonon coupling is deduced from the temperature dependence of the full-width at half-maximum (FWHM) of the fundamental excitonic peak, decrease in exciton-longitudinal-optical (LO) phonon coupling strength is due to the quantum confinement effect.  相似文献   
89.
In vitro and in vivo proton T1 data are reported that demonstrate that the paramagnetic copper-D-penicillamine complex can be applied as a potential contrast agent to magnetic resonance imaging.  相似文献   
90.
Biosynthetic human growth hormone specifically 13C-labelled in the carbonyl positions of all 26 leucine residues has been obtained by recombinant DNA techniques using 13C-labelled leucine and an E. coli strain that requires leucine. It is shown that, on the whole, the labelling is specific with no significant mislabelling as would have been the case had the 13C-labelled leucine been metabolized.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号