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71.
R. Garrison Kinney Bruce A. Arndtsen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(15):5139-5143
We report a new strategy for the conversion of carboxylic acids into potent acid triflate electrophiles. The reaction involves oxidative carbonylation of carboxylic acids with I2 in the presence of AgOTf, and is postulated to proceed via acyl hypoiodites that react with CO to form acid triflates. Coupling this chemistry with subsequent trapping with arenes offers a mild, room temperature approach to generate ketones directly from broadly available carboxylic acids without the use of corrosive and reactive Lewis or Bronsted acid additives, and instead from compounds that are readily available, stable, and functional group compatible. 相似文献
72.
73.
Kinney WA Zhang X Williams JI Johnston S Michalak RS Deshpande M Dostal L Rosazza JP 《Organic letters》2000,2(19):2921-2922
A short formal synthesis of squalamine is described, utilizing the biotransformation product 2, which is available in one step from commercially available 3-keto-23,24-bisnorchol-4-en-22-ol (1). Regioselective C-22 oxidation and C-24 sulfation of the corresponding alcohols in the presence of a free C-7 alcohol make for an efficient preparation of squalamine intermediate 11. 相似文献
74.
Simmons K Kinney J Owens A Kleier D Bloch K Argentar D Walsh A Vaidyanathan G 《Journal of chemical information and modeling》2008,48(8):1663-1668
High-throughput screening (HTS) has become a central tool of many pharmaceutical and crop-protection discovery operations. If HTS screening is carried out at the level of the intact organism, as is commonly done in crop protection, this strategy has the potential of uncovering a completely new mechanism of actions. The challenge in running a cost-effective HTS operation is to identify ways in which to improve the overall success rate in discovering new biologically active compounds. To this end, we describe our efforts directed at making full use of the data stream arising from HTS. This paper describes a comparative study in which several machine learning and chemometric methodologies were used to develop classifiers on the same data sets derived from in vivo HTS campaigns and their predictive performances compared in terms of false negative and false positive error profiles. 相似文献
75.
Leng X Garcia-Barriocanal J Yang B Lee Y Kinney J Goldman AM 《Physical review letters》2012,108(6):067004
We successfully tuned an underdoped ultrathin YBa2Cu3O(7-x) film into the overdoped regime by means of electrostatic doping using an ionic liquid as a dielectric material. This process proved to be reversible. Transport measurements showed a series of anomalous features compared to chemically doped bulk samples and a different two-step doping mechanism for electrostatic doping was revealed. The normal resistance increased with carrier concentration on the overdoped side and the high temperature (180 K) Hall number peaked at a doping level of p~0.15. These anomalous behaviors suggest that there is an electronic phase transition in the Fermi surface around the optimal doping level. 相似文献