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991.
992.
The theory of atomic diffraction from a classical standing wave light field in the presence of spontaneous emission in the Raman-Nath regime was developed by Tanguy et al. [6]. We describe the basis of computationally efficient methods for performing calculations in this regime and show their agreement with recent experimental results of Gould et al. [4]. 相似文献
993.
Ming Tan 《Journal of multivariate analysis》1991,38(2)
The problem of finding classes of estimators which improve upon the usual (e.g., ML, LS) estimator of the parameter matrix in the GMANOVA model under (matrix) quadratic loss is considered. Classes of improved estimators are obtained via combining integration-by-parts methods for normal and Wishart distributions. Also considered is the application of control variates to achieve better efficiency in multipopulation multivariate simulation studies. 相似文献
994.
B. P. Liu X. C. Lv Z. C. Tan Z. H. Zhang Q. Shi L. N. Yang J. Xing L. X. Sun T. Zhang 《Journal of Thermal Analysis and Calorimetry》2007,89(1):283-287
The molar heat capacity, C
p,m, of a complex of holmium chloride coordinated with L-aspartic acid, Ho(Asp)Cl2·6H2O, was measured from 80 to 397 K with an automated adiabatic calorimeter. The thermodynamic functions H
T-H
298.15 and S
T-S
298.15 were derived from 80 to 395 K with temperature interval of 5 K. The thermal stability of the complex was investigated by
differential scanning calorimeter (DSC) and thermogravimetric (TG) technique, and the mechanism of thermal decomposing of
the complex was determined based on the structure and the thermal analysis experiment. 相似文献
995.
Photochemical cycloaddition of cyclopentene with enone esters containing different chiral auxiliaries yielded anti and syn adducts and in good yield and with moderate to high (79%) enantiomeric excesses. 相似文献
996.
酶解鲐鱼蛋白制取低分子肽的进一步研究 总被引:5,自引:0,他引:5
确定了用胰蛋白酶-木瓜蛋白酶混合酶法水解鲐鱼蛋白制取低分子肽的最适工艺条件为:胰蛋白酶和木瓜蛋白酶的酶量比为1:4(W/W),肉水比为1:1,温度55℃,pH7.0。在加酶量为鱼糜中蛋白质含量的1.25%,反应时间6h的条件下,制得的低分子肽无苦味,氮利用率可达78.5%,平均链长为2.80,游离氨基酸含量为26.57%,必需氨基酸含量占总氨基酸的41.8%,且比例合理,富含镁,是一种很有开发前途的功能食品原料。 相似文献
997.
对三维空间某个多面体区域的四面体剖分,通过在每个四面体胞腔的棱和顶点设置适当的插值结点.本文给出了(1,1)型C0及C1光滑的非奇异有理样条存在的充分必要条件. 相似文献
998.
999.
J. S. Tan 《Journal of Polymer Science.Polymer Physics》1974,12(1):175-185
Rotational isomeric-state theory has been applied to investigate chain configurations of a polyester prepared from 4′,5-(1,1,3-trimethyl-3-phenylindan) dicarboxylic acid and 2,2-bis(4′-hydroxyphenyl) propane (POLA polyester). Independent conformations for each repeat monomer unit of the chain have been assumed in the calculations of the unperturbed dimensions. Rotations about the oxygen-phenylene-carbon (O? ?? C) bonds are considered to be free with twofold symmetric potentials. The trans and cis conformations of the carbonyl-phenylene-carbon (O?C? ?? C) and the indan-carbonyl residues are assumed to have equal probability. Two rotational states, trans and cis, are assigned to the ester C? O bonds. Calculation of the reduced unperturbed dimensions (〈r02〉/M)∞ with conformations thus assigned for the bonds in the repeat unit, and comparison with experiment (0.72 ± 0.02 Å2/g) indicate that the conformation in the ester C? O bonds is predominantly trans. An equation for the conformational potential as a function of rotational angle about the ester C? O bond has been formulated using data on potential barriers for low molecular weight compounds. This equation, yielding a potential difference between the cis the trans isomers of 2.5–3.0 kcal/mole, is in good agreement with the prediction made from the calculation of the unperturbed dimensions where a cis/trans ratio of 0.01 for the ester C? O bonds was obtained. 相似文献
1000.
The conformational character of a random copolymer of ethyl acrylate and acrylic acid (mole ratio 3:1) has been examined by intrinsic viscosity and light scattering in organic and in aqueous media. The unperturbed dimensions of this copolymer in its un-ionized state in an organic theta solvent are 1.3 to 1.4 times those obtained for the fully ionized polymer in an aqueous theta solvent. The data also suggest that a change in conformation from a swollen random coil to a compact random coil occurs in aqueous media as a function of ionic strength. These results are interpreted in terms of the hydrophobic interaction of the ester groups on the chain. An application of the wormlike chain model shows that viscosity data can be used to predict the light scattering results well with in experimental error. 相似文献