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排序方式: 共有421条查询结果,搜索用时 625 毫秒
41.
de França KW Oliveira Jde L Florêncio T da Silva AP Navarro M Léonel E Nédélec JY 《The Journal of organic chemistry》2005,70(26):10778-10781
[reactions: see text] Nickel-catalyzed electroreductive homocoupling of 2-bromomethylpyridines and 2-bromopyridine has been investigated in an undivided cell in the presence of a zinc sacrificial anode. A series of reactions were performed with various types and concentrations of supporting electrolyte. It was observed that a key step in this process is the formation of an arylzinc through a nickel-zinc transmetalation. This intermediate can be transformed back to the reactive arylnickel species to afford the homocoupling as the final product. The back process from the arylzinc intermediate is, however, suppressed in the presence of high concentration (0.2 M) of tetraalkylammonium salts. On the contrary, with NaI, the formation of the dimer is not prevented, whatever the NaI concentration. 相似文献
42.
Recent crystal structures of nicotine bound to the acetylcholine binding protein (AChBP) ended a long debate confirming that the pyridine nitrogen of nicotine is indeed hydrogen-bonded to receptor residues through a bridging water molecule. Here, we describe the first direct experimental evaluation of the hydrogen-bond affinity of the nicotinium pyridine nitrogen. The equilibrium constant of its association with a phenol is 1 order of magnitude greater than the association of the acetylcholine carbonyl oxygen. 相似文献
43.
Jean-Yves Charbonnel 《Journal of Functional Analysis》1981,41(2):175-203
Let G be a connected solvable Lie group, π a normal factor representation of G and ψ a nonzero trace on the factor generated by G. We denote by (G) the space of C∞ functions on G which are compactly supported. We show that there exists an element u of the enveloping algebra U of the complexification of the Lie algebra of G for which the linear form on (G) is a nonzero semiinvariant distribution on G. The proof uses results about characters for connected solvable Lie groups and results about the space of primitive ideals of the enveloping algebra U. 相似文献
44.
45.
Lyskawa J Sallé M Balandier JY Le Derf F Levillain E Allain M Viel P Palacin S 《Chemical communications (Cambridge, England)》2006,(21):2233-2235
The formation of the two dimeric species [(TTF)2]+* and (TTF+*)2 can be monitored by complexation of Na+ on a calix[4]arene-TTF assembly. 相似文献
46.
An exact algorithm for a vehicle routing problem with time windows and multiple use of vehicles 总被引:2,自引:0,他引:2
Nabila Azi Michel Gendreau Jean-Yves Potvin 《European Journal of Operational Research》2010,202(3):756-763
The vehicle routing problem with multiple use of vehicles is a variant of the classical vehicle routing problem. It arises when each vehicle performs several routes during the workday due to strict time limits on route duration (e.g., when perishable goods are transported). The routes are defined over customers with a revenue, a demand and a time window. Given a fixed-size fleet of vehicles, it might not be possible to serve all customers. Thus, the customers must be chosen based on their associated revenue minus the traveling cost to reach them. We introduce a branch-and-price approach to address this problem where lower bounds are computed by solving the linear programming relaxation of a set packing formulation, using column generation. The pricing subproblems are elementary shortest path problems with resource constraints. Computational results are reported on euclidean problems derived from well-known benchmark instances for the vehicle routing problem with time windows. 相似文献
47.
Chemin Jean-Yves 《偏微分方程通讯》2013,38(11-12):1771-1779
In this article, we shall study the inviscid limit of two dimensional fluids with bounded voticity. We prove that the solution of incompressible Navier-Stokes system converges strongly in L2 to the solution of the Euler incompressible system in the case of two-dimensional fluids in the whole space. 相似文献
48.
Ioannis G. Tigelis Jean-Yves Raguin Zisis C. Ioannidis George P. Latsas Angelos J. Amditis 《International Journal of Infrared and Millimeter Waves》2008,29(4):432-442
The dispersion characteristics of a circular cylindrical waveguide with periodic surface corrugations consisting of rectangular
grooves with smoothing are examined using the Space Harmonic Method (SHM). The whole structure is divided into two regions,
one describing the propagation volume and one inside the grooves. In the first region, the Floquet theorem is applicable and
the field distribution is expressed as a summation of spatial Bloch components, whereas in the second one an appropriate Fourier
expansion of standing waves is used. Applying the boundary conditions an infinite system of equations is obtained, which is
solved numerically by truncation. Several cases are considered, including the limiting cases of a sinusoidal and a rectangular
corrugation profile, to check the accuracy of the method proposed as well as its dependence on the corrugation profile. Numerical
results are presented only for transverse magnetic modes, although the formalism can be easily extended to include all kinds
of waves that can in principle propagate in such a structure. 相似文献
49.
Romain Plais Guy Gouarin Dr. Anne Gaucher Violette Haldys Arnaud Brosseau Dr. Gilles Clavier Dr. Jean-Yves Salpin Prof. Dr. Damien Prim 《Chemphyschem》2020,21(12):1249-1257
The intrinsic properties of tetrazine as a π-anion receptor and as an on/off recognition probe merged with H-bond ability of an urea motif into a single architecture constitutes a new generation of well-defined anion receptors. Complexation properties directly benefit from the dual and synergistic contribution of tetrazine and urea. In this study, we report on the synthesis and assessment of binding properties to anions of diverse geometries. Association constants have been predicted by theoretical calculations and evaluated by multiple and complementary experimental techniques including electrospray-mass tandem spectroscopy, NMR, UV-visible, steady state fluorescence spectroscopies and time resolved fluorescence. These results provide the basis for a better understanding of both the complexation and the anion-dependent quenching mechanism. 相似文献
50.