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71.
72.
Dye ST Annis J Becker-Szendy R Bratton CB Casper D Claus R Crouch M Errede S Gajewski W Goldhaber M Haines TJ Jones TW Kielczewska D Kropp WR Learned JG LoSecco JM McGrew C Matthews J Mudan MS Price LR Reines F Schultz J Seidel S Sinclair D Sobel HW Stone JL Sulak LR Svoboda R Thornton G van der Velde JC 《Physical review letters》1989,62(18):2069-2072
73.
Terence Davis Matthew C Dix Michal J Rokicki Amy JC Brook Caroline S Widdowson David Kipling Mark C Bagley 《Chemistry Central journal》2011,5(1):1-5
To develop more potent small molecules with enhanced free radical scavenger properties, a series of N-substituted isatin derivatives was synthesized, and the cytoprotective effect on the apoptosis of PC12 cells induced by H2O2 was screened. All these compounds were found to be active, and N-ethyl isatin was found with the most potent activity of 69.7% protective effect on PC12 cells. Structure-activity relationship analyses showed the bioactivity of N-alkyl isatins decline as the increasing of the chain of the alkyl group, furthermore odd-even effect was found in the activity, which is interesting for further investigation. 相似文献
74.
Two new isostructural two-dimensional (2D) coordination polymers exhibiting spin crossover (SCO) behavior of formulation [Fe(4,4'-bipy)(2)(NCX)(2)]·4CHCl(3) (4,4'-bipy = 4,4'-bipyridine; X = S [1·4CHCl(3)], Se [2·4CHCl(3)]) have been synthesized and characterized, and both undergo cooperative spin transitions (ST). For 1·4CHCl(3) the ST takes place in two steps with critical temperatures of T(c1)(down) = 143.1 K, T(c2)(down) = 91.2 K, T(c1)(up) = 150.7 K, and T(c2)(up) = 112.2 K. 2·4CHCl(3) displays half ST characterized by T(c)(down) = 161.7 K and T(c)(up) = 168.3 K. The average enthalpy and entropy variations and cooperativity parameters associated with the ST have been estimated to be ΔH(1)(av) = 5.18 kJ mol(-1), ΔS(1)(av) = 35 J K(-1) mol(-1), and Γ(1) = 2.8 kJ mol(-1) and ΔH(2)(av) = 3.55 kJ mol(-1), ΔS(2)(av) = 35 J K(-1) mol(-1), and Γ(2) = 2.6 kJ mol(-1) for 1·4CHCl(3), and ΔH(av) = 6.25 kJ mol(-1), ΔS(av) = 38.1 J K(-1) mol(-1), and Γ = 3.2 kJ mol(-1) for 2·4CHCl(3). At T > [T(c1) (1·4CHCl(3)); T(c) (2·4CHCl(3))], both compounds are in the space group P2/c while at T < [T(c1) (1·4CHCl(3)); T(c) (2·4CHCl(3))] they change to the C2/c space group and display an ordered checkerboard-like arrangement of iron(II) sites where the high- and low-spin states coexist at 50%. 相似文献
75.
The relative rates of H-transfer between partners in ion-neutral complexes were compared with those in intramolecular rearrangements using results of first differential photoionization mass spectrometry measurements. Complex-mediated H-transfers are inferred to have rates of the same order as those for intramolecular hydrogen rearrangements, suggesting a similar range of motion of the reactive sites in both types of reactions. It is also concluded that at their fastest H-transfers take place between the partners in ion-neutral complexes within at most the time of several rotations of the partners in the complexes. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
77.
M. A. Schumaker D. Cline G. Hackman C. Pearson C. E. Svensson C. Y. Wu A. Andreyev R. A. E. Austin G. C. Ball D. Bandyopadhyay J. A. Becker A. J. Boston H. C. Boston L. Buchmann R. Churchman F. Cifarelli R. J. Cooper D. S. Cross D. Dashdorj G. A. Demand M. R. Dimmock T. E. Drake P. Finlay A. T. Gallant P. E. Garrett K. L. Green A. N. Grint G. F. Grinyer L. J. Harkness A. B. Hayes R. Kanungo A. F. Lisetskiy K. G. Leach G. Lee R. Maharaj J-P. Martin F. Moisan A. C. Morton S. Mythili L. Nelson O. Newman P. J. Nolan J. N. Orce E. Padilla-Rodal A. A. Phillips M. Porter-Peden J. J. Ressler R. Roy C. Ruiz F. Sarazin D. P. Scraggs J. C. Waddington J. M. Wan A. Whitbeck S. J. Williams J. Wong 《The European Physical Journal A - Hadrons and Nuclei》2009,42(3):477-484
The low-energy structures of the radioactive nuclei 20, 21Na have been examined using Coulomb excitation at the TRIUMF-ISAC radioactive ion beam facility. Beams of ~ 5×106 ions/s were accelerated to 1.7MeV/A and Coulomb excited in a 0.5mg/cm^2 natTi target. Two TIGRESS HPGe clover detectors perpendicular to the beam axis were used for $ \gamma$ -ray detection, while scattered nuclei were observed by the Si detector BAMBINO. For 21Na , Coulomb excitation from the 3/2+ ground state to the first excited 5/2+ state was observed, while for 20Na , Coulomb excitation was observed from the 2+ ground state to the first excited 3+ and 4+ states. For both beams, B ( $ \lambda$ L) values were determined using the 2+ $ \rightarrow$ 0+ de-excitation in 48Ti as a reference. The resulting B(E2) ↓ value for 21Na is 137±9 e^2fm^4, while the resulting B( $ \lambda$ L) ↓ values for 20Na are 55±6 e^2fm^4 for the 3+ $ \rightarrow$ 2+ , 35.7±5.7 e^2 fm^4 for the 4+ $ \rightarrow$ 2+ , and 0.154±0.030 μ_N^2 for the 4+ $ \rightarrow$ 3+ transitions. This analysis significantly improves the measurement of the 21Na B(E2) value, and provides the first experimental determination of B( $ \lambda$ L) values for the proton dripline nucleus 20Na .-1 相似文献
78.
Hannu?TiitinenEmail author Anna?Mari?M?kel? Ville?M?kinen Patrick?JC?May Paavo?Alku 《BMC neuroscience》2005,6(1):62
Background
The cortical activity underlying the perception of vowel identity has typically been addressed by manipulating the first and second formant frequency (F1 & F2) of the speech stimuli. These two values, originating from articulation, are already sufficient for the phonetic characterization of vowel category. In the present study, we investigated how the spectral cues caused by articulation are reflected in cortical speech processing when combined with phonation, the other major part of speech production manifested as the fundamental frequency (F0) and its harmonic integer multiples. To study the combined effects of articulation and phonation we presented vowels with either high (/a/) or low (/u/) formant frequencies which were driven by three different types of excitation: a natural periodic pulseform reflecting the vibration of the vocal folds, an aperiodic noise excitation, or a tonal waveform. The auditory N1m response was recorded with whole-head magnetoencephalography (MEG) from ten human subjects in order to resolve whether brain events reflecting articulation and phonation are specific to the left or right hemisphere of the human brain. 相似文献79.
80.
H. P. Dixon
H. D. B. Jenkins
T. C. Waddington
《Chemical physics letters》1971,10(5):600-604The calculations reported here assign a charge qN = −0.52 electron units to the terminal nitrogen atoms in the azide ion and a value of 141.9 kJ mole−1 to the enthalpy of formation of the gaseous azide ion, ΔHf0(N3−(g)). The total lattice potential energies are found to be: Epot(NaN3) = 725.1 kJ mole−1; Epot(KN3) = 650.7 kJ mole−1 and Epot(RbN3) = 632.1 kJ mole−1. 相似文献