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131.
132.
Surface free energy of a solid surface gives a direct measure of intermolecular interactions at interfaces and has a strong influence on adsorption and adhesion behaviour. However few data are available for the surface free energies of electroless Ni–P based composition coatings. In this paper, the electroless Ni–P, Ni–P-surfactant, Ni–Cu–P, Ni–P–PTFE and Ni–Cu–P–PTFE composite coatings were prepared under various coating conditions. The chemical compositions, surface morphology and thickness of the coatings were measured using an energy dispersive X-ray microanalysis (EDX), a scanning electron microscope (SEM) and a digital micrometer respectively. The contact angles of water, diiodomethane and ethylene glycol on the coatings were measured automatically using dataphysics OCA-20 contact angle analyser. The surface free energy of the coatings and their components (e.g. dispersion, polar or acid/base portions) were calculated using various methods. The experimental results showed that the incorporation of surfactant or PTFE particles into Ni–P matrixes has a significant influence on the surface free energy of the coatings, while the incorporation of copper into Ni–P matrixes has no significant influence on the surface free energy of the coatings. 相似文献
133.
Shui Cao ZHENG Huo Nan LIN Di He HU 《数学学报(英文版)》2005,21(5):1137-1148
In this paper, we investigate the Hausdorff measure for level sets of N-parameter Rd-valued stable processes, and develop a means of seeking the exact Hausdorff measure function for level sets of N-parameter Rd-valued stable processes. We show that the exact Hausdorff measure function of level sets of N-parameter Rd-valued symmetric stable processes of index α is Ф(r) = r^N-d/α (log log l/r)d/α when Nα 〉 d. In addition, we obtain a sharp lower bound for the Hausdorff measure of level sets of general (N, d, α) strictly stable processes. 相似文献
134.
Jianhu Yang Shixun Dai Nengli Dai Lei Wen Lili Hu Zhonghong Jiang 《Journal of luminescence》2004,106(1):9-14
Nonradiative decay of 4I13/2→4I15/2 transition of Er3+ has been investigated in a series of oxide glasses. For Er3+-doped glass samples, the Judd-Ofelt analysis on absorption spectra was performed and the fluorescence lifetime was determined by extrapolating to zero Er3+ concentration limit. Infrared spectra were measured in order to investigate the influence of OH− groups in different glasses. The effects of glass matrix on the decay rate were discussed from the viewpoint of phonon energy, variations of effective fields, and OH− groups. Compared to other glasses, phosphate glass presents low quantum efficiency and large nonradiative decay rate due to its high phonon energy and hygroscopic behavior. 相似文献
135.
A. M. Povolotsky V. B. Priezzhev Chin-Kun Hu 《Journal of statistical physics》2003,111(5-6):1149-1182
An asymmetric stochastic process describing the avalanche dynamics on a ring is proposed. A general kinetic equation which incorporates the exclusion and avalanche processes is considered. The Bethe ansatz method is used to calculate the generating function for the total distance covered by all particles. It gives the average velocity of particles which exhibits a phase transition from an intermittent to continuous flow. We calculated also higher cumulants and the large deviation function for the particle flow. The latter has the universal form obtained earlier for the asymmetric exclusion process and conjectured to be common for all models of the Kardar–Parisi–Zhang universality class. 相似文献
136.
137.
Torsional vibration of multi-step non-uniform rods with various concentrated elements 总被引:1,自引:0,他引:1
Q.S. Li 《Journal of sound and vibration》2003,260(4):637-651
An analytical approach and exact solutions for the torsional vibration of a multi-step non-uniform rod carrying an arbitrary number of concentrated elements such as rigid disks and with classical or non-classical boundary conditions is presented. The exact solutions for the free torsional vibration of non-uniform rods whose variations of cross-section are described by exponential functions and power functions are obtained. Then, the exact solutions for more general cases, non-uniform rods with arbitrary cross-section, are derived for the first time. In order to simplify the analysis for the title problem, the fundamental solutions and recurrence formulas are developed. The advantage of the proposed method is that the resulting frequency equation for torsional vibration of multi-step non-uniform rods with arbitrary number of concentrated elements can be conveniently determined from a homogeneous algebraic equation. As a consequence, the computational time required by the proposed method can be reduced significantly as compared with previously developed analytical procedures. A numerical example shows that the results obtained from the proposed method are in good agreement with those determined from the finite element method (FEM), but the proposed method takes less computational time than FEM, illustrating the present methods are efficient, convenient and accurate. 相似文献
138.
The problem of generating a matrix A with specified eigen‐pair, where A is a symmetric and anti‐persymmetric matrix, is presented. An existence theorem is given and proved. A general expression of such a matrix is provided. We denote the set of such matrices by ??????En. The optimal approximation problem associated with ??????En is discussed, that is: to find the nearest matrix to a given matrix A* by A∈??????En. The existence and uniqueness of the optimal approximation problem is proved and the expression is provided for this nearest matrix. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
139.
用密度泛函B3LYP/ 6 3 1G(d)方法 ,对质子化丙酮分子团簇 (CH3COCH3) nH+ (n =1~ 7)弱相互作用体系进行了全自由度能量梯度优化 ,得到了该系列团簇的稳定结构及其对应的体系能量 .通过对构型的分析得出了质子化丙酮分子团簇 (CH3COCH3) nH+ (n =1~ 7)的生长规律 .计算了中性丙酮分子团簇体系的质子亲合能并总结出其变化趋势 .分析讨论了质子化团簇的红外振动光谱 ,发现质子化团簇的振动光谱普遍较中性环型团簇的振动光谱复杂 ,最强的振动峰来源于质子在溶剂壳中两个氧原子之间的振动 ,而且随着团簇尺寸的增加羰基的伸缩振动峰的数目也随之增多 相似文献
140.
This work is devoted to near-optimal controls of large-scale discrete-time nonlinear dynamic systems driven by Markov chains; the underlying problem is to minimize an expected cost function. Our main goal is to reduce the complexity of the underlying systems. To achieve this goal, discrete-time control models under singularly-perturbed Markov chains are introduced. Using a relaxed control representation, our effort is devoted to finding near-optimal controls. Lumping the states in each irreducible class into a single state gives rise to a limit system. Applying near-optimal controls of the limit system to the original system, near-optimal controls of the original system are derived. 相似文献