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排序方式: 共有491条查询结果,搜索用时 15 毫秒
51.
52.
Yoichi Tanaka Yuji Taniguchi Daisaku Tanaka Masatoshi Toyoda Hideshi Ishii Teruo Tanabe Yasuko Terada Shinjiro Hayakawa Jun Kawai 《Analytical sciences》2005,21(7):839-843
The Kosa (yellow sand) aerosol affects the global environment as well as human health because it migrates from the interior of China to other areas, absorbing various atmospheric elements. Investigation into individual Kosa aerosol particles, which are submicroscopic to several tens of micrometers in diameter, is required to resolving the issue. We installed a scanning electron microscope (SEM) equipped with an energy dispersive X-ray spectrometer (EDX) on a synchrotron radiation (SR) beam line and introduced the SR beam into the SEM chamber for combinatorial application of SEM-EDX and SR X-ray fluorescence (SR-XRF) spectrometry to individual particles. It should be noted that detailed topographic observation by SEM and sensitive elemental analysis by SR-XRF, both crucial for individual particle measurement but which previously had to be carried out separately, were jointly performed inside the SEM chamber in this setup. Here, we show that SR-XRF results, in conjunction with SEM images, contributed toward resolving individual particle dispositions. Atmospheric sulfur primarily adheres to calcium in the aerosol particles and the particle surface roughens as a consequence of the chemical reaction between the two elements. 相似文献
53.
A convenient synthesis of chiral 3,3′-disubstituted 1,1′-binaphthyl-2,2′-disulfonic acids (BINSA, 1) was developed. The key was directed ortho-lithiation of BINSA methyl ester 2 with n-BuLi and subsequent reaction with an electrophile. Electrophiles such as Br2, I2, Me3SiOTf, and i-PrOB(Pin) reacted smoothly with 3,3′-dilithiated BINSA methyl ester, and the corresponding 3,3′-dihalo-, 3,3′-bis(trimethylsilyl)-, and 3,3′-diboryl-BINSA derivatives were obtained in yields of 21–78%. This simple synthetic method is highly attractive since the ability to prepare 3,3′-disubstituted BINOLs in advance can be useful. 相似文献
54.
55.
Shunsuke Kotani Shohei AokiMasaharu Sugiura Makoto Nakajima 《Tetrahedron letters》2011,52(22):2834-2836
Trichlorosilyl triflate, in the presence of a chiral Lewis base catalyst, provides an effective method for the enantioselective direct-type aldol reaction of aldehydes and ketones. A chiral Lewis base induces both the production and activation of trichlorosilyl enol ether, yielding an aldol product in good yield and with high diastereo- and enantioselectivities. 相似文献
56.
Kazuki OsakamaMasaharu Sugiura Makoto Nakajima Shunsuke Kotani 《Tetrahedron letters》2012,53(32):4199-4201
An efficient method was developed for the enantioselective reductive aldol reaction of α,β-unsaturated ketones with aldehydes in the presence of a Lewis base catalyst; conjugate reduction using a tertiary amine and trichlorosilyl triflate, followed by an aldol reaction with BINAP dioxide (BINAPO) as an organocatalyst, gave the corresponding product in high yield with high stereoselectivity. 相似文献
57.
Yoshiteru Sakata Hiroshi Imahori Ken-Ichi Sugiura 《Journal of inclusion phenomena and macrocyclic chemistry》2001,41(1-4):31-36
Guidelines for the design of molecules with a long lifetime of the charge-separated state and for the formation of a self-assembled monolayer were studied by preparing various model compounds linking donor and acceptor with chemical bonds. Based on the obtained results we designed and prepared the SAMs of C60-(porphyrin)-(ferrocene)-(CH2)11SH on a gold surface and observed a photocurrent with high efficiency (25% quantum yield). In addition, a well-defined, rigid-sheet-structured oligoporphyrin with 21 porphyrin chromophores was prepared as a model for antenna chlorophylls. 相似文献
58.
Nariaki Sugiura Hidetoshi Murakami Seong Keon Lee Yasutomo Maeda 《Annals of the Institute of Statistical Mathematics》2006,58(1):93-100
This paper answers the long-standing question of whether the two-sided Wilcoxon rank test for equal sample sizes is unbiased
against a location parameter family of distributions by giving a counterexample. It is also shown that the nonrandomized two-sided
Wilcoxon test for equal sample sizes with the least positive significance level is unbiased. 相似文献
59.
On the use of nickel foil strain gages at varying temperatures 总被引:1,自引:0,他引:1
When a strain gage made of nickel foil attached on the surface of a specimen is subjected to repeated loads, the elastic stress
is measured by observing slip-bands in the foil resulting from repeated strain. Calibration studies with rotating-bending
tests at various temperatures between room temperature and 350°C are performed on round steel bars with nickel foil. The relation
between the threshold stress for the first appearance of slip-bands and the number of stress cycles is examined at varying
temperatures, which provides the calibration values of the nickel foil tested at varying temperatures. Assuming that the first
appearance of slip-bands is based on the linear cumulative damage law, the calibration values at varying temperatures are
calculated from those established by the calibration tests at several constant temperatures. It is found that the calculated
calibration values agree well with the results obtained by the calibration tests at varying temperatures and that the calculation
applying the linear cumulative damage law is a useful method to presume the calibration values at varying temperatures without
performing the experiment. 相似文献