一种混合高温超导磁体及其电磁特性研究

近年来, 高温超导磁体由于载流能力高、 磁场强等优点在磁悬浮列车、 医疗成像、 飞轮储能器等系统具有广阔的应用前景. 在这些应用中, 工作面上磁场越强, 系统的性能越优. 高温超导块材能够俘获强磁场, 但因为尺寸的限制, 其磁场发散区域小, 在大气隙条件下工作面区域磁场弱. 相比而言, 高温超导线圈的尺寸不受限制, 但其磁场会随着口径的增大而降低. 因此, 本文将高温超导线圈和块材结合, 提出了一种结构紧凑、 口径大、 磁场强的混合高温超导磁体. 同时, 利用有限元仿真软件建立混合高温超导磁体的二维轴对称自洽模型并进行了实验验证, 仿真计算了混合高温超导磁体的磁场分布以及不同温度下的临界电流和最大磁场强度. 结果表明, 混合高温超导磁体可显著增加工作面的磁场, 相比于独立的高温超导线圈和高温超导块材最大磁场分别最小提升了102% 和12% .另外, 混合高温超导磁体工作面上的有效磁通相比于高温超导块材也提高了.     

Three-Component Synthesis of Dioxaphosphorane-Fused Diphosphacycles Exhibiting Unique Dynamic Fluorescence “On/Off” Properties

Rigidly planar polycyclic phosphacycles featuring an internal dioxaphosphorane are promising photofunctional materials. However, the lack of efficient synthetic methods resulted in limited structural diversities which significantly hampered extensive study. Herein, we report a straightforward three-component synthesis of novel dioxaphosphorane-fused diphosphacycles with distinctive photophysical properties. Control experiments and theory calculations were performed to account for a plausible reaction mechanism. We also systematically investigated the structure-property relationships of these unprecedented platforms by combining experiments (X-ray analysis, optical and redox properties) and theoretical computations. Based on their unique structure and properties, a novel fluorescent switch for pH sensing was revealed by a dynamic ring-opening/ring-closing process.     

The microdefects and enhanced electrochemical performances of nano-VO2(B) induced by Mg doping

Journal of Solid State Electrochemistry - The Mg-doped VO2(B) nanorods were prepared by solvothermal and further heat treatment method. The effects of Mg doping on the structure, surface...     

对聚合物玻璃化转变的几点新认识

基于聚合物玻璃化转变的定义,探讨了聚合物宏观单晶体和聚合物单链单晶的玻璃化转变问题,指出玻璃化转变的温度依赖性不服从普适的Arrhenius方程,可以把WLF方程看作是聚合物玻璃化转变的特有温度依赖关系。介绍了二维状态下聚合物可能的玻璃化转变。     

Conformational Control of Organocatalyst in Strongly Brønsted-Acidic Metal-Organic Frameworks for Enantioselective Catalysis

Chiral imidodiphosphates (IDPs) have emerged as strong Brønsted acid catalysts for many enantioselective processes. However, the dynamic transformation between O,O-syn and O,O-anti conformers typically results in low enantioselectivity. Here we demonstrate that topologies of metal-organic frameworks (MOFs) can be exploited to control IDP conformations and local chiral microenvironments for enantioselective catalysis. Two porous Dy-MOFs with different topologies are obtained from an enantiopure 1,1′-biphenol IDP-based tetracarboxylate ligand. While the ligand adopts a 4- or 3-connected (c) binding mode, all IDPs are rigidified to get only a single O,O-syn conformation and display greatly enhanced Brønsted acidity relative to the free IDP. The MOF with the 4-c IDP that has a relatively less compact shape than the 3-c IDP can be an efficient and recyclable heterogeneous Brønsted acid catalysing the challenging asymmetric O,O-acetalization reaction with up to 96 % enantiomeric excess.     

金属卟啉配合物的分子识别研究进展

综述了金属卟啉配合物的分子识别研究进展。介绍了金属卟啉配合物在分子形状与大小识别、官能团识别和手性识别方面的研究概况。