Optical characterization of bromo-alkoxyl-substituted copper phthalocyanine derivative thin films

A series of thin films of copper phthalocyanine derivatives with bromine and alkoxyl substituents [CuPc(OC₈H₁₇)₄Br_m, m=0,1,2,4] were prepared on single-crystal silicon substrates by spin coating. The ellipsometric spectra of the films have been studied on a rotating analyzer–polarizer type of scanning ellipsometer. The optical, dielectric constants and absorption coefficients of the films in 500–800 nm wavelength region were obtained. The results show that the complex refractive index, dielectric constants and absorption coefficient of these thin films are influenced regularly by bromine substituent on conjugated macrocycle. It was found that there are approximately linear relationships between the resonance absorption wavelengths of the films and the average number of bromine atoms substituted on the phthalocyanine ring.     

A New Pathway to Synthesize Cyclomercurated Ferrocenylimines Containing Heterocyclic Ring

The cyclomercurated ferrocenylimines containing heterocyclic ring were prepared by the condensation of cyclomercuration of acylferrocene with the appropriate heterocyclic amine.This procedure provides an efficient method for the synthesis of cyclomerucurated ferrocenylimines containing heterocyclic ring which are difficultly synthesized by the conventional method.The reaction mechanism is proposed.     

多孔硅制备过程中B,P杂质原子的作用

采用DV-Xα方法对多孔硅形成过程中位于表层的B和P杂质原子的作用进行研究,结果表明位于顶层硅原子层中的B和P杂质原子均可削弱其邻近的Si-Si键强度,因而可能导致出现腐蚀的突破点,再通过分析杂质对表面区势场的改变,可以认为位于顶层硅原子层中的B杂质原子产生腐蚀的突破点的可能性更大。 关键词：     

苯并噻唑重氮氨基偶氮苯与汞（Ⅱ）的显色反应及其应用

报道了新试剂苯并噻唑重氮氨基偶氮苯的合成及其与汞（Ⅱ）的显色反应，在ＴｒｉｔｏｎＸ－１００存在下弱碱性介质中，试剂与汞形成２：１的橙红色络合物，最大吸收波长位于５２０ｎｍ处，表观摩尔吸光系数为１．５１×１０＾５Ｌ．ｍｏｌ＾－１．ｃｍ＾－１。汞量在０～１．２ｍｇ／Ｌ范围内遵守比尔定律，直接应用于废水中微量汞的测定，结果满意。     

Four-wave mixing based 10-Gb/s tunable wavelength conversion in dispersion-flattened microstructure fibers

All-optical wavelength conversion of 10-Gb/s signal based on four-wave mixing is experimentally demonstrated in a 30-m-long dispersion-flattened microstructure fiber with small positive dispersion. For an average pump power of 26 dBm, the conversion efficiency was around -19.5 dB with the fluctuation less than ±1.4 dB, covering a conversion bandwidth of 20 nm. The eye diagram of the converted signal shows good eye opening.     

Realization of optical limiting with a magnetic fluid film

In this paper, optical limiting property in a magnetic fluid film is studied. The relationship between the emergent power and the incident power is investigated experimentally and theoretically. It is found that the limiting threshold is linear with the diaphragm aperture which accord with the theoretical prediction. The external magnetic field will affect the limiting property, and increase the limiting threshold.     

Multiple periodic solutions of a delayed stage-structured predator–prey model with non-monotone functional responses

A delayed stage-structured predator–prey model with non-monotone functional responses is proposed. It is assumed that immature individuals and mature individuals of the predator are divided by a fixed age, and that immature predators do not have the ability to attack prey. Some new and interesting sufficient conditions are obtained for the global existence of multiple positive periodic solutions of the stage-structured predator–prey model. Our method is based on Mawhin’s coincidence degree and novel estimation techniques for the a priori bounds of unknown solutions to Lx = λNx. An example is given to illustrate the feasibility of our main result.     

傅里叶变换红外光谱仪遥测污染云团的吸收光谱算法

遥感傅里叶变换红外光谱技术因其具有对污染源作无干扰监测、多组分的同时连续测定、区域性或大范围地区的测量等优点,因而已广泛的应用于遥感测量技术。利用傅里叶变换红外(FTIR)光谱仪远距离探测目标,根据探测的目标源是否充满光谱仪的视场,建立了三种辐射模型。在所建立模型的基础上,选用了D&P公司生产的便携式Model-101型傅里叶变换红外光谱仪,实时探测目标云团和背景,运用差谱法和发射光谱法对探测结果进行了光谱分析,进而得到了扣除背景影响后的目标云团吸收光谱。给出了相应的仿真实验结果示例。实验结果表明,由差谱法得到的结果准确度较好。     

排列形状及阵列数目对纳米导线阵列场发射性能的影响

为了进一步研究纳米导线阵列的排列形状以及阵列数目对其场发射行为的影响，利用镜像悬浮球模型对正方形以及六边形排列的纳米导线阵列的场发射行为进行计算与模拟，近似的得到纳米导线阵列的场发射增强因子满足如下的变化趋势：β=h/ρ(1/1+W)+1/2(1/1+W)²+3,其中h为纳米导线的高度，ρ为纳米导线的半径，W是以R为自变量的函数，R为纳米导线阵列的间距.结果显示纳米导线阵列的排列形状对其场发射性能的影响较小，而阵列间距则是影响场发射性能的关键因素：当R<R₀时，场发射增强因子随着阵列间距的减小而急剧减小；当R>R₀时，场发射增强因子基本不变，其中R₀为导线阵列场发射的最佳间距.进一步研究表明改变纳米导线阵列的数目基本不会改变阵列的场发射性能随间距的变化趋势，但是随着阵列数目的增加，R₀会有一定程度的减小，场发射增强因子也会降低. 关键词： 纳米导线 场发射 增强因子 阵列数目     

外加磁场微波等离子推力器内流场数值模拟

为了提高微波等离子推力器性能，改善等离子体对电磁波能量的吸收状况，提高核心区温度，提出外加磁场的方案，并对热等离子体进行了数值模拟.假设局域热平衡条件，采用Navier-Stokes，Maxwell和Saha方程，利用压力修正的半隐格式和时域有限差分求解方法，建立了径向磁镜场下推力器内等离子体流场的数值计算模型.数值模拟结果表明：外加磁场后的磁感应强度小于0.5 T时，推力器内热等离子体核心区最高温度随磁感应强度的增加而迅速提高.外加磁场后的磁感应强度大于0.5 T时，核心区最高温度随磁感应强度的增加而缓慢提高.磁感应强度为0.5 T时，热等离子体核心区最高温度与不加磁场相比提高了24%.外加磁场对等离子体流场速度分布影响不大. 关键词： 等离子体模拟 等离子体相互作用 等离子体流动