Five complexes [Co3(Hpmad)6]·(4‐sb)2·(CH3COO)2·(H2O)2 ( 1 ), [Co3(Hpmad)6]·(3‐sb)2·(CH3COO)2·(H2O)0.5 ( 2 ), [Co(Hpmad)2(4‐sb)]n ( 3 ), [Co(Hpmad)2(3‐sb)]n ( 4 ) and {[Co(Hpmad)(SO4)(H2O)2]·H2O}n ( 5 ) [Hpmad is 2‐pyrimidineamidoxime, H2(4‐sb) is 4‐sulfobenzoic acid and H2(3‐sb) is 3‐sulfobenzoic acid], were prepared at room temperature. Complexes 1 – 5 were characterized by elemental analyses, single crystal X‐ray diffractions, powder X‐ray diffractions, infrared spectra, thermogravimetric analyses, fluorescence spectra and magnetic susceptibility measurements. Complexes 1 and 2 possess the linear trinuclear Co2+ structures. Complexes 3 and 4 exhibit similar one‐dimensional (1D) chains. Complex 5 comprises the 1D helical chain. The change of anion in cobalt salt from CH3COO? to Cl? to SO42? leads to the structural evolution from the linear trinuclear Co2+ structure to the 1D chain to the 1D helical chain. Complexes 1 – 5 exhibit the Hpmad‐based emissions. The magnetic properties of 1–5 were also investigated. 相似文献
Leakage and incompatibility of paraffin wax (PW) in hydroxyl-terminated polybutadiene (HTPB) binders is a major obstacle to its application in polymer-bonded explosives (PBX). In order to solve this issue, we designed a microencapsulated PW (MePW)/PW/HTPB composite in this paper. Melamine–formaldehyde-shelled MePW (MF MePW)/PW/HTPB composites with different contents of MePW and PW were prepared by cast molding method. The chemical composition, crystallinity and microstructure of MePW/PW/HTPB composites were analyzed with Fourier transformed infrared spectroscopy, X-ray diffraction and scanning electron microscope, respectively. The results showed that PW and MF MePW have been uniformly dispersed in HTPB without any chemical interaction. Moreover, differential scanning calorimeter analysis, thermal gravimetric analyzer, thermal cycling test, leaking test, tensile and compressive test were used to investigate the thermal and mechanical properties of these composites. The composites have high latent heat and good thermal reliability. The thermal stability, tensile and compressive strength of MePW/PW/HTPB composites were dramatically increased with the increasing mass fraction of MePW. The introduction of MePW can obviously prevent the leakage of PW in both HTPB binders and PBX. Consequently, it is anticipated that MePW can be used in the next-generation of paraffin-based high-temperature PBX systems.
Utilizing a general joint remote state preparation (JRSP) model, we investigate the JRSP of an arbitrary two-qubit quantum state in noisy environments. Two important decoherence noise models, the amplitude-damping noise and the phase-damping noise, have been considered in our paper. Our investigation of the noisy environment mainly focuses on the process of distributing the channel state. We use fidelity to describe how close the output state with the prepared state are, and how much information has been lost in the transmission. Interestingly, studies show that, if the initial state is successfully prepared, the fidelities in these two cases will only depend on the amplitude parameter of the initial state and the decoherence noisy rate, but have nothing to do with the phase information. Finally, we make some discussions for these two cases to show that in which noisy environment more information will be lost. 相似文献
Exploration of α,α-dibromo-β-dicarbonyl compounds as novel organic oxidants for the mild Cu(I)-catalyzed Glaser-type homo-coupling reaction has been achieved, which provides an alternatively efficient pathway for the construction of 1,3-conjugated structures. In addition, the mechanism of this reaction was investigated. 相似文献
Superlattice materials offer new opportunities to modify optical and electrical properties of recently emerging 2D materials. The insertion of tetraethylbenzidine (EtDAB) into interlamination of the established 2D PbI2 semiconductor through a mild solution method yielded the first lead iodide superlattice, EtDAB?4PbI2 (EtDAB=tetraethylbenzidine), with radical and non‐radical forms. The non‐radical form has a non‐ionic structure that differs from the common ionic structures for inorganic–organic hybrid lead halides. The radical form shows five orders of magnitude greater conductance and broader photoconductive response range (UV/Vis → UV/Vis‐IR), than pure PbI2 and the non‐radical form of the superlattice. 相似文献
Membrane proteins are of biological and pharmaceutical significance. However, their structural study is extremely challenging mainly due to the fact that only a small number of chemical tools are suitable for stabilizing membrane proteins in solution. Detergents are widely used in membrane protein study, but conventional detergents are generally poor at stabilizing challenging membrane proteins such as G protein-coupled receptors and protein complexes. In the current study, we prepared tandem triazine-based maltosides (TZMs) with two amphiphilic triazine units connected by different diamine linkers, hydrazine (TZM−Hs) and 1,2-ethylenediamine (TZM−Es). These TZMs were consistently superior to a gold standard detergent (DDM) in terms of stabilizing a few membrane proteins. In addition, the TZM−Es containing a long linker showed more general protein stabilization efficacy with multiple membrane proteins than the TZM−Hs containing a short linker. This result indicates that introduction of the flexible1,2-ethylenediamine linker between two rigid triazine rings enables the TZM−Es to fold into favourable conformations in order to promote membrane protein stability. The novel concept of detergent foldability introduced in the current study has potential in rational detergent design and membrane protein applications. 相似文献