Infrared and EPR Spectroscopic Studies of 2-C(2)H(2)F and 1-C(2)H(2)F Radicals Isolated in Solid Argon

2-fluorovinyl radicals were generated in solid argon by solid-state chemical reactions of mobile F atoms with acetylene and its deuterated analogues. Highly resolved EPR spectra of the stabilized radicals CHF&dbond;(*)CH, CDF&dbond;(*)CD, CHF&dbond;(*)CD, and CDF&dbond;(*)CH were obtained for the first time. The observed spectra were assigned to cis-2-fluorovinyl radical based on excellent agreement between the measured (a(F) = 6.50, a(betaH) = 3.86, a(alphaH) = 0.25 mT) hyperfine constants and those calculated using density functional (B3LYP) theory. Analogous experiments carried out using infrared spectroscopy yielded a complete assignment of the vibrational frequencies. An unusual reversible photochemical conversion is observed in which cis-2-fluorovinyl radicals can be partially converted to 1-fluorovinyl radicals by pulsed laser photolysis at 532 nm. Photolysis at 355 nm converts 1-fluorovinyl back to cis-2-fluorovinyl. High-resolution EPR and infrared spectra of 1-fluorovinyl were obtained for the first time. The measured hyperfine constants (a(F) = 13.71, a(H1) = 4.21, a(H2) = 1.16 mT) are in good agreement with calculated values. Copyright 2001 Academic Press.     

Analysis of some large-scale nonlinear stochastic dynamic systems with subspace-EPC method

The probabilistic solutions to some nonlinear stochastic dynamic (NSD) systems with various polynomial types of nonlinearities in displacements are analyzed with the subspace-exponential polynomial closure (subspace-EPC) method. The space of the state variables of the large-scale nonlinear stochastic dynamic system excited by Gaussian white noises is separated into two subspaces. Both sides of the Fokker-Planck-Kolmogorov (FPK) equation corresponding to the NSD system are then integrated over one of the sub...     

高能量爆磁压缩电流发生器理论分析与实验研究

根据多分支爆磁压缩电流发生器的电路方程,建立了多分支爆磁压缩电流发生器的等效电路模型,并利用该模型优化设计了一种长600mm、直径120mm、总质量10kg且具有高能量输出的爆磁压缩装置8 7A。实验结果表明,8 7A型装置能在360nH电感性负载上产生峰值为512kA的脉冲电流,储能45.8kJ,能量放大90倍。     

Polymorphism in Br2 clathrate hydrates

The structure and composition of bromine clathrate hydrate has been controversial for more than 170 years due to the large variation of its observed stoichiometries. Several different crystal structures were proposed before 1997 when Udachin et al. (Udachin, K. A.; Enright, G. D.; Ratcliffe, C. I.; Ripmeester, J. A. J. Am. Chem. Soc. 1997, 119, 11481) concluded that Br2 forms only the tetragonal structure (TS-I). We show polymorphism in Br2 clathrate hydrates by identifying two distinct crystal structures through optical microscopy and resonant Raman spectroscopy on single crystals. After growing TS-I crystals from a liquid bromine-water solution, upon dropping the temperature slightly below -7 degrees C, new crystals of cubic morphology form. The new crystals, which have a limited thermal stability range, are assigned to the CS-II structure. The two structures are clearly distinguished by the resonant Raman spectra of the enclathrated Br2, which show long overtone progressions and allow the extraction of accurate vibrational parameters: omega(e) = 321.2 +/- 0.1 cm(-1) and omega(e)x(e) = 0.82 +/- 0.05 cm(-1) in TS-I and omega(e) = 317.5 +/- 0.1 cm(-1) and omega(e)x(e) = 0.70 +/- 0.1 cm(-1) in CS-II. On the basis of structural analysis, the discovery of the CS-II crystals implies stability of a large class of bromine hydrate structures and, therefore, polymorphism.     

微管换热器流动与传热的实验研究

本文对自制微管换热器的流动与传热性能进行了实验研究。提出了微细圆管换热器管内单相强制对流换热努摩尔数准则式,并与已有相关文献提出的关联式做了对比,结果表明:微管管内换热系数比常规尺度计算公式预测值要高,同时本文分析了微细管内的压力降、摩擦阻力系数f随雷诺数的关系。研究表明微管管内压降、摩擦系数都比常规尺度预测值要高。     

时空数据库基态修正模型的扩展

本文分析了几种有代表性的时空数据模型的特点和存在的缺陷,认为在许多时态ＧＩＳ应用领域中（如土地管理信息系统）,采用扩展的基态修正模型较为适宜,提出了采用历史、过程库和现实库对时空过程和时空关系进行描述的思路,并结合开发的商业化的土地产权籍管理系统展示了其在实际应用中的可操作性。     

Spectroscopic signatures of halogens in clathrate hydrate cages. 1. Bromine

We report the first UV-vis spectroscopic study of bromine molecules confined in clathrate hydrate cages. Bromine in its natural hydrate occupies 51262 and 51263 lattice cavities. Bromine also can be encapsulated into the larger 51264 cages of a type II hydrate formed mainly from tetrahydrofuran or dichloromethane and water. The visible spectra of the enclathrated halogen molecule retain the spectral envelope of the gas-phase spectra while shifting to the blue. In contrast, spectra of bromine in liquid water or amorphous ice are broadened and significantly more blue-shifted. The absorption bands shift by about 360 cm-1 for bromine in large 51264 cages of type II clathrate, by about 900 cm-1 for bromine in a combination of 51262 and 51263 cages of pure bromine hydrate, and by more than 1700 cm-1 for bromine in liquid water or amorphous ice. The dramatic shift and broadening in water and ice is due to the strong interaction of the water lone-pair orbitals with the halogen sigma* orbital. In the clathrate hydrates, the oxygen lone-pair orbitals are all involved in the hydrogen-bonded water lattice and are thus unavailable to interact with the halogen guest molecule. The blue shifts observed in the clathrate hydrate cages are related to the spatial constraints on the halogen excited states by the cage walls.     

具有垂直传染非自治SIR传染病模型的持久性和灭绝性

通过对一类具有垂直传染的非自治SIR传染病模型的研究，在较弱的条件下，不仅得到了疾病一致强持久（即疾病流行）的充分必要条件．而且给出了疾病消失的判别准则．     

Study of a multi-wire proportional chamber with a cathode strip and delay-line readout

The design principle for a multi-wire proportional chamber with a cathode strip and delay-line readout is described. A prototype chamber of a size of 10 cm ～ l0 cm was made together with the readout electronics circuit. A very clean signal with very low background noise was obtained by applying a transformer between the delay-line and the pre-amplifier in order to match the resistance. Along the anode wire direction a position resolution of less than 0.5 mm was achieved with a 55Fe-5.9 keV X ray source. The simple structure, large effective area and high position resolution allow the application of a gas chamber of this kind to many purposes.