On the use of Helmholtz resonators as sound attenuators

Summary In the present paper a nonlinear acoustic theory is proposed, to accurately describe the properties of a generalized type of Helmholtz resonators. The theory may be used as a layout tool to design sound attenuators for combustion facilities. The present investigation shows that, in addition to the nonlinear effects, the effects due to thermoacoustic boundary layers and the first frequency correction to the Helmholtz approximation should be taken into account, in order to predict the frequency-dependent attenuation properties of Helmholtz attenuators with the accuracy required by typical technical applications. A series of experiments is presented which is used to validate the theoretical predictions.

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Zusammenfassung In der vorliegenden Abhandlung wird eine nichtlineare akustische Theorie vorgeschlagen, mit der das Verhalten einer verallgemeinerten Art von Helmholtzresonatoren beschrieben werden kann. Die Theorie kann als Werkzeug zur Auslegung von Schalldämpfern für Verbrennungsanlagen benutzt werden. Die vorliegende Arbeit zeigt, dass neben den nichtlinearen Effekten auch die Einflüsse der thermoakustischen Grenzschichten und der ersten Frequenzkorrektur zur Helmholtzapproximation berücksichtigt werden müssen, damit die frequenzabhängigen Eigenschaften von Helmholtzdämpfern mit technisch ausreichender Genauigkeit beschrieben werden können. Mit einer Reihe von Experimenten werden die theoretischen Ergebnisse untermauert.

     

Quantitative determination of chloride by means of flow injection analysis with spectrophotometric detection in the UV/VIS range

Chloride is determined indirectly by Spectrophotometric flow injection analysis. Two systems are compared, both based on the principle of ion exchange of easily detectable anions versus chloride from suitable mercury salts. The first method is based on the exchange of chloride with chloranilate which is detected at 332 nm or at 306 nm in neutral or in acidic medium respectively. In the second case, chloride reacts with Hg(SCN)₂. The liberated thiocyanate forms a strongly coloured complex with Fe(III) in acidic solution with an absorption maximum at 460 nm. Both methods have a detection limit of about 5 mol Cl^–/l (175 ng/ml). In the case of the thiocyanate method, the relative standard deviation is about 2% (7 measurements) in the range of 5 to 150 mol/l and decreases significantly to a value of approximately 0.2% at higher concentrations; for the chloranilate method it is 10% for lower and about 1% for higher concentrations respectively.     

Trennung von V,Cr und Mn aus Stahl und Aktivierungsanalyse der Legierungselemente mit 14 MeV-Neutronen

The elements are separated from iron by solvent-extraction. Cr, V and Mn are separated by ion-exchange chromatography with a strong acidic cation-exchanger. The elements are determined by 14 MeV-neutron activation analysis using γ-spectroscopy. The method is suitable for a concentration range of 0.05 to 5%.     

Adsorption of an amphipatic copolymer on a kidney dialysis membrane

We have studied the adsorption of a copolymer of acrylonitrile and methacrylate of nonaethyleneglycol on a kidney dialysis membrane, which contains mostly nitrile groups. The kinetics study reveals at first a rapid increase of the adsorbance, followed by slow variations suggesting rearrangements at the interface. The isotherms do not present a true plateau at high concentration. The high adsorbance observed at low pH or high salt concentration could be related to the ability of polyethyleneoxide to form a complex with cations.