全文获取类型
收费全文 | 1594篇 |
免费 | 48篇 |
国内免费 | 3篇 |
专业分类
化学 | 1084篇 |
晶体学 | 9篇 |
力学 | 60篇 |
数学 | 289篇 |
物理学 | 203篇 |
出版年
2023年 | 7篇 |
2022年 | 9篇 |
2021年 | 20篇 |
2020年 | 18篇 |
2019年 | 15篇 |
2018年 | 17篇 |
2017年 | 16篇 |
2016年 | 35篇 |
2015年 | 37篇 |
2014年 | 40篇 |
2013年 | 81篇 |
2012年 | 129篇 |
2011年 | 112篇 |
2010年 | 90篇 |
2009年 | 84篇 |
2008年 | 105篇 |
2007年 | 115篇 |
2006年 | 98篇 |
2005年 | 92篇 |
2004年 | 81篇 |
2003年 | 60篇 |
2002年 | 65篇 |
2001年 | 20篇 |
2000年 | 23篇 |
1999年 | 22篇 |
1998年 | 18篇 |
1997年 | 18篇 |
1996年 | 8篇 |
1995年 | 6篇 |
1994年 | 26篇 |
1993年 | 19篇 |
1992年 | 5篇 |
1991年 | 11篇 |
1990年 | 9篇 |
1989年 | 11篇 |
1987年 | 6篇 |
1986年 | 9篇 |
1985年 | 9篇 |
1984年 | 9篇 |
1983年 | 4篇 |
1982年 | 11篇 |
1981年 | 9篇 |
1980年 | 8篇 |
1979年 | 9篇 |
1978年 | 12篇 |
1977年 | 7篇 |
1976年 | 5篇 |
1975年 | 7篇 |
1974年 | 7篇 |
1972年 | 4篇 |
排序方式: 共有1645条查询结果,搜索用时 15 毫秒
61.
Voting rules are known to exhibit various paradoxical or problematic behaviors, typically in the form of their failure to meet the Condorcet criterion or in their vulnerability to strategic voting. Our basic premise is that a decrease in the number of coalitions of voters that exist with similar preference rankings should generally lead to a reduced propensity of voting rules to yield undesired results. Surprisingly enough, conclusions that are reported by Felsenthal et al. (1990) in an early study do not corroborate this intuition. This study reconsiders and extends the Felsenthal et al. analysis by using a modified Impartial Anonymous Culture (IAC) model. It turns out that the results obtained with this probabilistic assumption are much more consistent with the stated intuitive premise. 相似文献
62.
63.
Dr. Tarun Kumar Yan Yang Sirine Sghaier Dr. Yassir Zaid Dr. Xavier F. Le Goff Dr. Elodie Rousset Dr. Fabien Massicot Dr. Dominique Harakat Agathe Martinez Dr. Marc Taillefer Prof. Laurent Maron Prof. Jean-Bernard Behr Dr. Florian Jaroschik 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(12):4016-4021
The development of new fluorine-containing building blocks and their efficient synthetic access is currently a challenging research field. Herein, the highly regio- and stereoselective addition of a large range of aldehydes onto trifluoromethylated benzofulvenes was achieved using a simple La/I2/DIBAL-Cl system via a selective C−F bond activation process. This versatile methodology provided homodienyl alcohols bearing a terminal CF2-alkene with potential further applications, as shown by the dehydration to the first benzofulvenes carrying a difluorovinyl group. In addition, for certain electron-poor aldehydes, unprecedented ipso substitution of the CF3 group in a diene was observed, which, according to DFT studies, is related to the presence of the large, Lewis-acidic lanthanum metal. 相似文献
64.
McLain Derek R. Brossard Tom W. Tsai Yifen Condon Nicholas J. Canaday Jodi L. 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(5):2169-2174
Journal of Radioanalytical and Nuclear Chemistry - Two methods were used to evaluate the age of 75Se sealed source material. Both methods utilized gamma spectroscopy to determine the quantity of... 相似文献
65.
Dr. Ting Liang Dr. Dominique Collin Melodie Galerne Dr. Gad Fuks Dr. Andreas Vargas Jentzsch Prof. Dr. Mounir Maaloum Alain Carvalho Prof. Dr. Nicolas Giuseppone Dr. Emilie Moulin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(63):14341-14348
C3-Symmetric triarylamine trisamides (TATAs), decorated with three norbornene end groups, undergo supramolecular polymerization and further gelation by π–π stacking and hydrogen bonding of their TATA cores. By using subsequent ring-opening metathesis polymerization, these physical gels are permanently crosslinked into chemical gels. Detailed comparisons of the supramolecular stacks in solution, in the physical gel, and in the chemical gel states, are performed by optical spectroscopies, electronic spectroscopies, atomic force microscopy, electronic paramagnetic resonance spectroscopy, X-ray scattering, electronic transport measurements, and rheology. The results presented here clearly evidence that the core structure of the functional supramolecular polymers can be precisely retained during the covalent capture whereas the mechanical properties of the gels are concomitantly improved, with an increase of their storage modulus by two orders of magnitude. 相似文献
66.
Róbert Bordás Volker John Ellen Schmeyer Dominique Thévenin 《Theoretical and Computational Fluid Dynamics》2013,27(3-4):253-271
The droplet size distribution in a turbulent flow field is considered and modeled by means of a population balance system. This paper studies different numerical methods for the 4D population balance equation and their impact on an output of interest, the time-space-averaged droplet size distribution at the outlet, which is known from experiments. These methods include different interpolations of the experimental data at the inlet, various discretizations in time and space, and different schemes for computing the coalescence integrals. It will be shown that noticeable changes in the output of interest might occur. In addition, the computational efficiency of the studied methods is discussed. 相似文献
67.
68.
The reaction of chloroacetyl chloride and triethylamine with a chiral imine derived from the combination of methyl glyoxylate and protected L-threonine gave two optically active α-amino acid derivatives with a cis-substituted β-lactam skeleton in a 72:28 ratio. The major product is obtained in 59% yield by simple crystallisation. 相似文献
69.
70.
This Note deals with the modeling of a structure made of straight elastic rods whose thickness tends to 0. We show that, upon an adequate scaling, the infimum of the total elastic energy tends to the minimum of a functional which depends on fields defined on the centerlines of the rods. 相似文献