Polarization of recoil protons from the reaction γp → π0p in the proton energy range 450–800 MeV

Measurement of secondary-proton polarization from the reaction γp → π⁰p have been performed in the proton energy range 500–800 MeV at c.m. pion emission angles 100°, 120°, 140°. The experiment was carried out using an optical spark chamber telescope at the output of the magnetic spectrometer. The obtained experimental data are included in a Walker-type analysis in order to verify the parameters of the resonances P₁₁(1470), D₁₃(1570) and S₁₁(1535). Proton polarization in the reaction γp → π⁰p was measured for a photon energy of 450 MeV at a c.m. pion emission angle of 105° using photons linearly polarized at 45° to the reaction plane. A liquid hydrogen target in the field of a superconducting magnet was used for the separation of the P_x′ and P_z′ components of the secondary-proton polarization vector.Data are obtained for three components (P_x′, P_y, P_z′) of the proton polarization. The obtained results are compared with predictions of different multipole analyses of photoproduction.     

Rheological Properties of Gels of Gelatin with Sodium Alginate

Effect of anionic polysaccharide, sodium alginate, on the rheological characteristics of gelatin gels is studied. It follows from the rheological curves that low-temperature gelatin gels with sodium alginate can be classified with elastoviscoplastic systems. Multicomponent gels obtained with the two gel-forming agents demonstrate synergism of the rheological characteristics.     

Non-Newtonian behavior of concentrated emulsions stabilized with globular protein in the presence of nonionic surfactant

Changes in the rheological properties of a model concentrated oil-in-water emulsion stabilized with globular protein (bovine serum albumin) upon the addition of nonionic surfactant polyoxyethylene (20) sorbitan monooleate (Tween 80) are studied. Non-Newtonian behavior is typical of the emulsions in question; moreover, they are characterized by the existence of yield stress. At stresses above the yield stress, the viscosity drops not immediately but after the intermediate Newtonian region at the flow curve. For all systems studied, the total flow curve is exhibited with the minimum Newtonian viscosity that is adequately described by the Cross formula. An increase in the Tween 80 concentration leads to a decrease in the viscosity of emulsion. Two threshold phenomena on the concentration dependences of rheological properties are revealed: at low concentration of added nonionic surfactant, the yield stress drops abruptly, whereas the viscosity lowers considerably with an increase in surfactant concentration to 1 × 10^?3 mol/l and the emulsion becomes unstable. The effects observed can be explained by the gradual displacement of high-molecular-weight stabilizer from interfacial layers and its replacement by nonionic surfactant.     

Flavonoids of inflorescences of Calendula officinalis

By column chromatography on polyamide sorbent, the inflorescences of pot marigold calendula have yielded eight substances of flavonoid nature: two aglycons — quercetin (C₁₅H₁₀O₇, mp 309–311°C) and isorhamnetin (C₁₆H₁₂O₇, mp 314–316°C); six glycosides, of which three have been identified as isoquercetin (C₂₁H₂₀O₁₂, [α] _D ²⁰ ?36° in methanol, mp 218–220°C), isorhamnetin 3-O-β-D-glucoside (C₂₂H₂₂O₁₂, [α] _D ²⁰ ?59° in dimethylformamide, mp 193–195°C), narcissin (C₂₈H₃₂O₁₆, [α] _D ²¹ ?28° in dimethylformamide, mp 180–182°C), and three substances that have proved to be new and have been called calendoflaside (C₂₈H₃₂O₁₅, [α] _D ²¹ ?85° in methanol, mp 192–195°C; calendoflavoside (C₂₈H₃₂O₁₆, [α] _D ²⁰ ?106° in methanol, mp 189–192°C), and calendoflavobioside (c₂₇H₃₀O₁₆, [α] _D ²⁰ ?105° in methanol, mp 194–197°C).     

Coumarins of the roots ofHeracleum leskovii

Summary The roots of Lesko's cow parsnip have yielded 13 substances of coumarin nature: osthole, psoralen, bergapten, xanthotoxin, isopimpinellin, phellopterin, heracol, biacangelicin, angelicin, sphondin, isobergapten, 6-isopentenyloxy-5-methoxyangelicin, and heraclesol.Heraclesol is a new compound and is (+)-6-[2(R)3-dihydroxy-3-dimethylbutoxy]-5-methoxy-furo-2,3:7,8-coumarin (I), and this is the first time that 6-isopentenyloxy-5-methoxy-angelicin has been obtained from a plant of the genusHeracleum.Khar'kov Scientific-Research Institute of Pharmaceutical Chemistry. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 184–187, March–April, 1978.