Integrable couplings of fractional L‐hierarchy and its Hamiltonian structures

Based on a general isospectral problem of fractional order, a fractional bilinear form variational identity, the new integrable coupling of fractional L‐hierarchy and the Hamiltonian structures of the integrable coupling of fractional L‐hierarchy are obtained. Copyright © 2016 John Wiley & Sons, Ltd.     

In situ composites based on blends of PEEK and thermotropic liquid crystalline polymer

A series of blends were prepared by mixing pellets of the thermotropic liquid crystalline polymers (TLCP) with poly (ether ether ketone)(PEEK) in the dry state under injection mouldingmolding conditions. The mechanical properties of blends were measured, and it is proved that the mechanical properties of blends are better than those of their matrix. Compared with the thermoplastic matrix, the tensile modulus and strength of the blends increased obviously, with the addition of only 2 wt% LCP. At the same time, the addition of TLCP decreased the melt viscosity of the blends.     

Facile and scalable fabrication engineering of fullerenol nanoparticles by improved alkaline-oxidation approach and its antioxidant potential in maize

A feasible in operation, labor-saving and low-cost one-step technology to fabricate fullerenol nanoparticles (FNPs) up to 10 g in laboratory was developed by improved alkaline-oxidation approach using moderately concentrated sodium hydroxide solution as the hydroxylation agent and o-dichlorobenzene as the solvent. This strategy paves the avenue for industrial-scale bulk production of FNPs. The resulted product, [C₆₀(OH)₂₂·8H₂O]_n, were characterized by various measurements including matrix-assisted laser desorption ionization time-of-flight mass spectrometry, high-resolution ¹H nuclear magnetic resonance spectrometry, Fourier transform infrared spectroscopy, UV-Visible spectrophotometer, thermogravimetric analysis, differential scanning calorimetry, dynamic light scattering analysis, scanning electron microscopy, and electron spin resonance spectrometer. Radical scavenging assay in vitro confirmed the high efficiency of water-soluble [C₆₀(OH)₂₂·8H₂O]_n as a novel radical scavenger. Furthermore, [C₆₀(OH)₂₂·8H₂O]_n as an excellent candidate has the potential to serve as the plant defense stimulation agent in maize.

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Influence of two different template removal methods on the micromorphology,crystal structure,and photocatalytic activity of hollow CdS nanospheres

Hollow cadmium sulfide (CdS) nanospheres of about 260 nm average diameters and about 30 nm shell thickness can be easily synthesized via a sonochemical process, in which polystyrene (PS) nanoparticles were employed as templates. In order to remove the PS templates, both etching and calcination were applied in this paper. The influence of the two different template removal methods on the surface micromorphology, crystal structure, and photocatalytic activity of hollow CdS nanospheres was carefully performed a comparative study. Results of X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray, FT-IR, thermogravimetric analysis, Brunauer–Emmett–Teller, diffused reflectance spectra, and decolorization experiments showed that the different template removal methods exhibited a significant influence on the surface micromorphology, crystal structure, and photocatalytic activity of hollow CdS nanospheres. The CdS hollow nanospheres as-prepared by etching had pure cubic sphalerite structure, higher –OH content, less defects and exhibited good photocatalytic activity for rhodamine-B, Methylene Blue and methyl orange under UV–vis light irradiation. However, CdS hollow nanospheres obtained by calcination with a hexagonal crystal structure, less –OH content, more defects have shown worse photocatalytic activity. This indicated that surface micromorphology and crystalline phase were mainly factors influencing photocatalytic activity of hollow CdS nanospheres.     

Topological phases and phase transitions on the honeycomb lattice

We investigate possible phase transitions among the different topological insulators in a honeycomb lattice under the combined influence of spin-orbit couplings and staggered magnetic flux. We observe a series of topological phase transitions when tuning the flux amplitude, and find topologically nontrivial phases with high Chern number or spin-Chern number. Through tuning the exchange field, we also find a new quantum state which exhibits the electronic properties of both the quantum spin Hall state and quantum anomalous Hall state. The topological characterization based on the Chern number and the spin-Chern number are in good agreement with the edge-state picture of various topological phases.     

分布式抽运连续光纤激光器研究

为了避免高功率光纤激光器中光纤端面出现热效应问题,依据多点级联结构的耦合器,对分布式抽运的光纤激光器进行了研究。首先,介绍了实验室自主研制的级联耦合器。然后,分析了耦合器插入对光纤激光器的影响。最后,选用自制的耦合器搭建了分布式抽运的光纤激光器。实验结果表明:对耦合器插入损耗的研究,能够促进高功率级联耦合器的实现。在光纤激光器结构中,975 nm泵浦功率注入1.1 k W时,1 080nm激光功率输出为770 W,光-光转换效率为77%。在主控振荡功率放大结构中,激光功率输出为635 W,放大级的光-光转换效率为78%。分布式抽运方式可以使泵浦光多点注入,避免了热量的集中,能够获得千瓦级的激光功率输出。     

Total synthesis of isoprekinamycin: structural evidence for enhanced diazonium ion character and growth inhibitory activity toward cancer cells

The structurally novel diazobenzo[a]fluorene antibiotic isoprekinamycin (IPK) has been synthesized for the first time employing a Suzuki coupling of a brominated AB ring synthon with a boronate ester representing the D ring, followed by anionic cyclization and appropriate functional group manipulations. The first indication that the diazobenzo[a]fluorene system exhibits in vitro anticancer activity is provided and X-ray crystallographic evidence for enhancement of diazonium ion character as a consequence of intramolecular H-bonding is described.