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991.
Hard X‐ray‐induced damage on carbon–binder matrix for in situ synchrotron transmission X‐ray microscopy tomography of Li‐ion batteries 下载免费PDF全文
Cheolwoong Lim Huixiao Kang Vincent De Andrade Francesco De Carlo Likun Zhu 《Journal of synchrotron radiation》2017,24(3):695-698
The electrode of Li‐ion batteries is required to be chemically and mechanically stable in the electrolyte environment for in situ monitoring by transmission X‐ray microscopy (TXM). Evidence has shown that continuous irradiation has an impact on the microstructure and the electrochemical performance of the electrode. To identify the root cause of the radiation damage, a wire‐shaped electrode is soaked in an electrolyte in a quartz capillary and monitored using TXM under hard X‐ray illumination. The results show that expansion of the carbon–binder matrix by the accumulated X‐ray dose is the key factor of radiation damage. For in situ TXM tomography, intermittent X‐ray exposure during image capturing can be used to avoid the morphology change caused by radiation damage on the carbon–binder matrix. 相似文献
992.
Matteo Moretti Francesca Freni Claudia Carelli Carlo Previder Pierangela Grignani Claudia Vignali Maria Cobo-Golpe Luca Morini 《Molecules (Basel, Switzerland)》2021,26(17)
Dried urine spots (DUS) represent a potential alternative sample storage for forensic toxicological analysis. The aim of the current study was to develop and validate a liquid chromatographic tandem mass spectrometric procedure for the detection and quantitative determination of cannabinoids and metabolites in DUS. A two-step extraction was performed on DUS and urine samples. An LC-MS/MS system was operated in multiple reaction monitoring and positive polarization mode. The method was checked for sensitivity, specificity, linearity, accuracy, precision, recovery, matrix effects and carryover. The method was applied to 70 urine samples collected from healthy volunteers and drug addicts undergoing withdrawal treatment. The method was successfully developed for DUS. LODs lower than 2.0 ng/mL were obtained for all the monitored substances. All the validation parameters fulfilled the acceptance criteria either for DUS or urine. Among the real samples, 45 cases provided positive results for at least one compound. A good quali-quantitative agreement was obtained between DUS and urine. A good stability of THC, THCCOOH and THCCOOH-gluc was observed after a 24 h storage, in contrast to previously published results. DUS seems to provide a good alternative storage condition for urine that should be checked for the presence of cannabinoids and metabolites. 相似文献
993.
A first-order liquid-liquid phase transition in high-pressure hydrogen between molecular and atomic fluid phases has been predicted in computer simulations using ab initio molecular dynamics approaches. However, experiments indicate that molecular dissociation may occur through a continuous crossover rather than a first-order transition. Here we study the nature of molecular dissociation in fluid hydrogen using an alternative simulation technique in which electronic correlation is computed within quantum Monte Carlo methods, the so-called coupled electron-ion Monte Carlo method. We find no evidence for a first-order liquid-liquid phase transition. 相似文献
994.
Transverse instabilities are shown to accompany counterpropagation of optical beams through reflection gratings in Kerr media. The instability threshold of continuous waves is analytically derived, and it is shown that the presence of the grating broadens and narrows the stability region of plane waves in focusing and defocusing media, respectively. Furthermore, counterpropagating soliton stability is numerically investigated and compared with the transverse modulation instability analysis, revealing an underlying physical link. 相似文献
995.
A unifying theoretical and algorithmic framework for least squares methods of estimation in diffusion tensor imaging 总被引:4,自引:0,他引:4
Koay CG Chang LC Carew JD Pierpaoli C Basser PJ 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2006,182(1):115-125
A unifying theoretical and algorithmic framework for diffusion tensor estimation is presented. Theoretical connections among the least squares (LS) methods, (linear least squares (LLS), weighted linear least squares (WLLS), nonlinear least squares (NLS) and their constrained counterparts), are established through their respective objective functions, and higher order derivatives of these objective functions, i.e., Hessian matrices. These theoretical connections provide new insights in designing efficient algorithms for NLS and constrained NLS (CNLS) estimation. Here, we propose novel algorithms of full Newton-type for the NLS and CNLS estimations, which are evaluated with Monte Carlo simulations and compared with the commonly used Levenberg-Marquardt method. The proposed methods have a lower percent of relative error in estimating the trace and lower reduced chi2 value than those of the Levenberg-Marquardt method. These results also demonstrate that the accuracy of an estimate, particularly in a nonlinear estimation problem, is greatly affected by the Hessian matrix. In other words, the accuracy of a nonlinear estimation is algorithm-dependent. Further, this study shows that the noise variance in diffusion weighted signals is orientation dependent when signal-to-noise ratio (SNR) is low (相似文献
996.
Idham Hafizh Giovanni Bellotti Marco Carminati Gianlorenzo Utica Matteo Gugiatti Antonella Balerna Vinicio Tullio Giacomo Borghi Antonio Picciotto Francesco Ficorella Nicola Zorzi Andrea Capsoni Simone Coelli Luca Bombelli Carlo Fiorini 《X射线光谱测定》2019,48(5):382-386
ARDESIA, a four-channel X-ray spectrometer based on silicon drift detectors (SDDs), is presented. It has been developed for synchrotron applications targeting especially X-ray fluorescence (XRF) and X-ray absorption spectroscopy (XAS) with good energy resolution at high count rates (a few Mcps per second). The main target applications are XRF and XAFS techniques. The system features a 2 × 2 monolithic array of 5-mm-pitch SDDs cooled with a double Peltier scheme and coupled to a four-channel CUBE charge preamplifier. Different digital pulse processors allowing operation in Mcps per second count rates are employed. The results of preliminary characterization measurements performed at both the LNF DAΦNE-Light DXR1 beamline and the ESRF LISA BM-08 are reported, in particular, XRF measurements on low atomic number elements (down to the Carbon K-line, 270 eV) and extended X-ray absorption fine structure of trace materials in pyrite. 相似文献
997.
Robertson–Walker and generalized Robertson–Walker spacetimes may be characterized by the existence of a time-like unit torse-forming vector field, with other constrains. We show that Twisted manifolds may still be characterized by the existence of such (unique) vector field, with no other constrain. Twisted manifolds generalize RW and GRW spacetimes by admitting a scale function that depends both on time and space. We obtain the Ricci tensor, corresponding to the stress–energy tensor of an imperfect fluid. 相似文献
998.
In this paper we present the spatial discretization of the thermal element model for coupled electrothermal simulation introduced in [1] with a suitable multiscale Finite Element scheme. The structure of the local matrices for the the thermal element is presented in detail and some preliminary numerical results are reported. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
999.
Weihong Lin Ejiofor AD EzekweJr Zhen Zhao Emily R Liman Diego Restrepo 《BMC neuroscience》2008,9(1):114
Background
The main olfactory epithelium (MOE) in the nasal cavity detects a variety of air borne molecules that provide information regarding the presence of food, predators and other relevant social and environmental factors. Within the epithelium are ciliated sensory neurons, supporting cells, basal cells and microvillous cells, each of which is distinct in morphology and function. Arguably, the least understood, are the microvillous cells, a population of cells that are small in number and whose function is not known. We previously found that in a mouse strain in which the TRPM5 promoter drives expression of the green fluorescent protein (GFP), a population of ciliated olfactory sensory neurons (OSNs), as well as a population of cells displaying microvilli-like structures is labeled. Here we examined the morphology and immunocytochemical properties of these microvillous-like cells using immunocytochemical methods. 相似文献1000.
Random lasing in fully disordered systems having organic and inorganic nature has been the subject of extensive studies since the beginning of the past decade. The interest mainly emerges from the unexpected role played by disorder in the laser action. The disorder was considered detrimental for the optical feedback in cavity laser, until it was demonstrated that multiple-scattering materials including a gain medium act as random laser. Here, a completely new approach is reported, where freely suspended complex fluid films doped with fluorescent molecules under optical excitation generate narrowband lasing peaks. The constellation of localized modes is selected by properly choosing the gain profile. The idea to have laser action in absence of mirrors and boundaries realizes an unparalleled tunable and moldable laser source. 相似文献