Strong coupling in a microcavity LED

Thin films of polyelectrolyte/J aggregate dye bilayers with high absorption coefficient (6 nm thick with alpha approximately equal to 1.0 x 10(6) cm(-1)) inserted in an optical microcavity enable the cavity quantum electrodynamic strong coupling limit to be reached at room temperature with a coupling strength (Rabi splitting) of 265 +/- 15 meV. By embedding these films in a resonant cavity organic LED structure, we demonstrate the first emissive electrically pumped exciton-polariton device.     

On the relationship between signal bandwidth and frequency correlation for ocean surface forward scattered signals

The relationship between the bandwidth of a signal and the correlation of that signal with its ocean surface reflected arrival, a quantity we term frequency correlation, has been investigated experimentally and compared with two theories. Decorrelation of wideband surface scattered signals is a direct consequence of time spread. The acoustic measurement utilized a very short pure tone signal, from which time spread has been estimated, and four broadband signals with different bandwidths, for which correlation with the transmitted signal has been measured. An environment-driven model developed by Dahl was used to predict time spread, which agreed favorably with our time spread measurements. The model was also employed in two theories that predict frequency correlation. The first, a theory published by Reeves in 1974, is based upon the ratio of signal temporal resolution to total time spread. This theory compared well with our measurements for 1 kHz bandwidth signals, but is not applicable for signal bandwidths greater than about 2 kHz. The second, a theory developed by Ziomek, models ocean acoustic propagation as transmission through a linear system. This theory agreed well with our frequency correlation measurements for signal bandwidths of 1-22 kHz.     

Ultrafast all-optical modulation on a silicon chip

We experimentally demonstrate ultrafast all-optical modulation using a micrometer-sized silicon photonic integrated device. The device transmission is strongly modulated by photoexcited carriers generated by low-energy pump pulses. A p-i-n junction is integrated on the structure to permit control of the generated carrier lifetimes. When the junction is reverse biased, carriers are extracted from the device in a time as short as 50 ps, permitting greater than 5 Gbit/s modulation of optical signals on a silicon chip.     

Polyborane reactions in ionic liquids: new efficient routes to functionalized decaborane and o-carborane clusters

In contrast to reactions that have been observed in traditional organic solvents, decaborane olefin-hydroboration and alkyne-insertion reactions have been found to proceed in ionic liquid solvents without the need of a catalyst. These reactions now provide important new, high-yield synthetic pathways to functionalized decaborane and o-carborane clusters.     

Charge transfer from ammonia physisorbed on nanotubes

We report the use of nanotube field-effect transistor devices for chemical sensing in a conducting liquid environment. Detection of ammonia occurs through the shift of the gate voltage dependence of the source-drain current. We attribute this shift to charge transfer from adsorbed ammonia molecules, with the amount of charge estimated to be as small as 40 electrons for the smallest shift detected. Using the concentration dependence of the response as an adsorption isotherm, we are able to measure the amount of charge transfer to be 0.04 electron per ammonia molecule.     

Dyad beads and the combinatorial discovery of catalysts

Dyad beads, bearing both a substrate and a catalyst, were prepared to enable direct split and mix bead based screening for catalysis.     

Recycling solid supports – A head-to-tail linker

The concept of a `head-to-tail linker' designed to allow the regeneration and reuse of a variety of solid supports is introduced. The synthesis of this linker, its coupling to various solid supports, its application in a number of standard solid phase reactions and resin regeneration are presented.     

X-Ray Fluorescence and the In Vivo Evaluation of Fe, Cu and Zn in Skin

We are seeking to extend the capabilities of an in vivo XRF system which was originally designed for the exclusive detection of Fe in skin. Our interest concerns development of a more versatile in vivo XRF diagnostic facility for measurement of Fe and Zn. Elevations of these two elements have been noted to occur in a number of skin disorders and ailments. The XRF system comprises a high-output tungsten anode X-ray tube, the collimated exit beam of which is made to impinge on an appropriate choice of filter. The present study makes use of a beam hardening filter in place of our previous use of a K-edge filter. Operating at 15 kVp, 23 mA, and using a Mo beam hardening filter of 0.2 mm thickness, we have obtained a quasi-monoenergetic output of approximately 13 keV and full-width at tenth maximum (FWTM) of 1.4 keV. Preliminary measurements on simulated skin indicate that we are able to detect Fe, Zn and Cu, at levels of the order of 20-, 10- and 5 g (g skin tissue)^–1, respectively, using monitoring periods of the order of 2000 seconds, and skin entrance doses of less than 16 mSv.     

Predicting reverberation times in a simulated classroom

By varying the sound-absorption treatments in a simulated classroom, experimental results were compared with analytical and computer predictions of reverberation time. Analytical predictions were made with different absorption exponents, which are the result of different weighting procedures involving room surface areas and the sound-absorption coefficients. Sound scattering was found to influence measured reverberation times. With the amount of sound scattering provided, more accurate analytical predictions were obtained with absorption exponents that give reverberation times longer than those obtained with the Sabine absorption exponent, which consistently underpredicted reverberation times. However, none of the absorption exponents could be singled out as more adequate because of similar average accuracy. Computer predictions of reverberation time were accomplished with two commercially available ray-based programs, RAYNOISE 3.0 and ODEON 2.6, with specular and calibrated diffuse reflection procedures. Neither type of procedure, in either program, was more accurate than the best analytical predictions. With RAYNOISE, neither the specular nor the calibrated diffuse reflection procedure could be singled out as more adequate. For ODEON, the calibrated diffuse reflection procedure gave consistently more accurate predictions than its specular reflection procedure, with the best accuracy of the computer predictions.