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Development of a laser-induced breakdown spectroscopy method for soil and ecological analysis (review) 总被引:2,自引:0,他引:2
V. S. Burakov S. N. Raikov N. V. Tarasenko M. V. Belkov V. V. Kiris 《Journal of Applied Spectroscopy》2010,77(5):595-608
The application of laser spectrochemical analysis to testing for basic compounds and nutritious/toxic elements in soil has
been reviewed. A combined laser-spark approach has been applied for the rapid measurement of the carbon content in soil. Spectra
have been excited both directly in a laser-ablation plume and by passing a pulsed electric discharge through the plume. The
emission spectrum intensity in the combined plasma is considerably higher. The application of a complex of methods to carbon
determination in soil has shown that in fact the data on the humus content usually obtained in agrochemical practice by a
conventional method of carbon oxidation by potassium dichromate need to be corrected taking into account the possibility of
incomplete oxidation of organic matter in soil. The efficiency of various double-pulse LIBS applications has been demonstrated
in solving a number of environmental problems such as the determination of heavy and toxic metals in soil and the detection
of sulfur in coal. The instrumentation and analytical procedures have been proposed and optimized for rapid control of the
chlorine content in plant samples. The technique can be easily extended to ecological monitoring of toxic elements and heavy
metals in any biogenic material. 相似文献
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Belkov M. V. Borisevich D. A. Catsalap K. Y. Khodasevich M. A. 《Journal of Applied Spectroscopy》2021,88(5):970-974
Journal of Applied Spectroscopy - Multivariate models were developed on the basis of raw low-resolution LIBS spectra of reference samples of lowalloy steels for calibration of the concentrations of... 相似文献
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Comparison of two laser-induced breakdown spectroscopy techniques for total carbon measurement in soils 总被引:1,自引:0,他引:1
M.V. Belkov V.S. Burakov A. De Giacomo V.V. Kiris S.N. Raikov N.V. Tarasenko 《Spectrochimica Acta Part B: Atomic Spectroscopy》2009
The potentials of two advanced laser-induced breakdown spectroscopy (LIBS) techniques which are used to determine the total carbon content in soils have been examined. The first one is the combination of a single-pulse laser ablation with spark excitation of plasma plume triggering the gap between electrodes close to the target surface. The second one is a more conventional double-pulse LIBS. In both modes the calibration graphs have a nonlinear trend in the actual range of carbon contents and present a good R2 value (0.97). In the combined laser-spark approach, using low-cost and portable laser instrumentation is possible, as well as inducing a micro-damage on the target surface. Certain regularities in the spectral line intensities of soil nutritious elements have been detected and appear to be connected to the total carbon content and to the soil origin. 相似文献
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V. M. Belkov N. F. Krynetskaya Z. A. Shabarova G. N. Novodarova M. E. Vol'pin 《Russian Chemical Bulletin》1996,45(8):2000-2007
Water-soluble Co and Fe phthalocyanines catalyze autooxidation of ascorbic acid and hydroquinone. Co and Fe phthalocyanines with cationic substituents in macroligands and also sulfo- and carboxy-substituted phthalocyanines were found to be the most active. Using the specific radical traps, the formation of active oxygen species (O2
–., OH–) in the course of the dark reaction of autooxidation was established.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 2105–2111, August, 1996. 相似文献
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S. A. Belkov G. G. Kochemasov T. E. Lyubynskaya N. V. Maslov A. S. Nuzhny L. B. Da Silva A. Rubenchik 《Applied physics. B, Lasers and optics》2011,105(3):641-648
Minimally invasive probe and optical biopsy system based on optical spectra recording and analysis seem to be a promising
tool for early diagnostics of breast cancer. Light scattering and absorption spectra are generated continuously as far as
the needle-like probe with one emitting and several collecting optical fibers penetrates through the tissues toward to the
suspicious area. That allows analyzing not only the state of local site, but also the structure of tissues along the needle
trace. The suggested method has the advantages of automated on-line diagnosing and minimal tissue destruction and in parallel
with the conventional diagnostic procedures provides the ground for decision-making. 相似文献
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M. V. Belkov A. N. Harbachova G. A. Ksendzova G. I. Polozov I. V. Skornyakov V. L. Sorokin G. B. Tolstorozhev O. I. Shadyro 《Journal of Applied Spectroscopy》2010,77(1):38-44
IR-Fourier spectroscopy methods are adopted to the study of intramolecular interactions occurring in CCl4 solutions of antivirally active derivatives of N-(3,5-di-tert-butyl-2-hydroxyphenyl)acetamide. Analysis of IR spectra has shown that intramolecular H-bonds O–H···O=C and N–H···O=C are
formed in solutions of these compounds. The O–H···O=C and N–H···O=C bond strengths and the direction of the equilibrium shift
between the two types of conformers depend on the type of carbonyl group substituent. An intramolecular O–H···O=C H-bond is
characteristic of highly active derivatives of N-(3,5-di-tert-butyl-2-hydroxyphenyl)acetamide. 相似文献
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M. V. Belkov A. N. Harbachova G. A. Ksendzova G. I. Polozov I. V. Skornyakov V. L. Sorokin G. B. Tolstorozhev O. I. Shadyro 《Journal of Applied Spectroscopy》2010,77(3):315-320
IR Fourier spectroscopy methods have been adopted to study intramolecular interactions that occur in CCl4 solutions of antiviral derivatives of aminophenol. Analysis of the IR spectra showed that intramolecular bonds O–H···N, O–H···O=C,
N–H···O=S=O, and O–H···O=S=O can occur in these compounds depending on the substituent on the amino group. Not only the presence
of intramolecular O–H···N, O–H···O=S=O, and N– H···O=S=O hydrogen bonds in 2-amino-4,6-di-tert-butylphenol derivatives containing
a sulfonamide fragment but also conformational equilibrium among these types of intramolecular interactions are essential
for the manifestation of high efficiency in suppressing HIV-infection in cell culture. 相似文献