Pyrrolidinones derived from (S)-pyroglutamic acid: penmacric acid and analogues

Alkylation reactions using alpha-halolactams or lactam enolates derived from bicyclic lactam templates can proceed with high endo- or exo- diastereoselectivity respectively. In the latter case, stereochemical correction by means of enolate generation and hindered phenol quench is possible with moderate efficiency. This protocol has been applied to the synthesis of protected penmacric acid and its analogues.     

Parallel integer relation detection: Techniques and applications

Let be a vector of real numbers. An integer relation algorithm is a computational scheme to find the integers , if they exist, such that . In the past few years, integer relation algorithms have been utilized to discover new results in mathematics and physics. Existing programs for this purpose require very large amounts of computer time, due in part to the requirement for multiprecision arithmetic, yet are poorly suited for parallel processing.

This paper presents a new integer relation algorithm designed for parallel computer systems, but as a bonus it also gives superior results on single processor systems. Single- and multi-level implementations of this algorithm are described, together with performance results on a parallel computer system. Several applications of these programs are discussed, including some new results in mathematical number theory, quantum field theory and chaos theory.

     

Measurement of the resonant d(mu)t molecular formation rate in solid HD

Measurements of muon-catalyzed dt fusion ( d(mu)t-->4He + n + mu(-)) in solid HD have been performed. The theory describing the energy dependent resonant molecular formation rate for the reaction (mu)t + HD-->[(d(mu)t)pee](*) is compared to experimental results in a pure solid HD target. Constraints on the rates are inferred through the use of a Monte Carlo model developed specifically for the experiment. From the time-of-flight analysis of fusion events in 16 and 37 microg x cm(-2) targets, an average formation rate consistent with 0.897+/-(0.046)(stat)+/-(0.166)(syst) times the theoretical prediction was obtained.     

First measurement of the ratio B(t --> Wb)/B(t --> Wq) and associated limit on the Cabibbo-Kobayashi-Maskawa element /V(tb)/

We present the first measurement of the ratio of branching fractions R identical withB(t-->Wb)/B(t-->Wq) from p_p collisions at sqrt[s] = 1.8 TeV. The data set corresponds to 109 pb(-1) of data recorded by the Collider Detector at Fermilab during the 1992-95 Tevatron run. We measure R = 0.94(+0.31)(-0.24)(stat+syst) or R>0.61 (0.56) at 90% (95)% C.L., in agreement with the standard model predictions. This measurement yields a limit on the Cabibbo-Kobayashi-Maskawa quark mixing matrix element /V(tb)/ under the assumption of three generations and unitarity.     

Measurement of d sigma/dM and forward-backward charge asymmetry for high-mass Drell-Yan e(+)e(-) pairs from pp macro collisions at square root of s = 1.8 TeV

We report on a measurement of the mass dependence of the forward-backward charge asymmetry, A(FB), and production cross section d sigma/dM for e(+)e(-) pairs with mass M(ee)>40 GeV/c(2). The data sample consists of 108 pb(-1) of pp macro collisions at square root of s = 1.8 TeV taken by the Collider Detector at Fermilab during 1992-1995. The measured asymmetry and d sigma/dM are compared with the predictions of the standard model and a model with an extra Z' gauge boson.     

Edge wave on axis behind an aperture or disk having a ragged edge

Diffraction by a circular aperture or disk having a ragged edge is investigated. Theory and measurements are reported. The ragged edge is modeled as N arcs, of differing radii a(i), each of which contributes a scattered signal to the edge wave on axis behind the aperture or disk. The amplitude of each scattered signal is proportional to the angle of the arc, and the corresponding time delay is square root of [(ai)2 + (s0)2/c0], where s0 is the axial distance from the aperture plane and c0 is the sound speed. Kirchhoff theory is used to make the calculation. A formula is derived for the rms pressure of the edge wave in terms of the rms pressure and autocorrelation function of the incident wave. The formula can be evaluated for incident waves that are sinusoidal, random (e.g., noise), or transient. Predictions agree reasonably well with underwater measurements made with a spark-generated pulse incident on various apertures. The main result is that making the edge ragged reduces the rms pressure of the edge wave. Indeed, an edge profile is presented that, for a given frequency and axial observation point, eliminates the edge wave completely.     

Ueber das Atomgewicht des Palladiums

Ohne Zusammenfassung     

Time- and space-resolved spectroscopy of dynamic hohlraum interiors

A dynamic hohlraum is created when an annular z-pinch plasma implodes onto a cylindrical 0.014 g/cc 6-mm-diameter CH₂ foam. The impact launches a radiating shock that propagates toward the axis at 350 μm/ns. The radiation trapped by the tungsten z-pinch plasma forms a 200 eV hohlraum that provides X-rays for indirect drive inertial confinement fusion capsule implosion experiments. We are developing the ability to diagnose the hohlraum interior using emission and absorption spectroscopy of Si atoms added as a tracer to the central portion of the foam. Time- and space-resolved Si spectra are recorded with an elliptical crystal spectrometer viewing the cylindrical hohlraum end-on. A rectangular aperture at the end of the hohlraum restricts the field of view so that the 1D spectrometer resolution corresponds approximately to the hohlraum radial direction. This enables distinguishing between spectra from the unshocked radiation-heated foam and from the shocked foam. Typical spectral lines observed include the Si Lyα with its He-like satellites and the He-like resonance sequence including Heα, Heβ, and Heγ, along with some of their associated Li-like satellites. Work is in progress to infer the hohlraum conditions using collisional–radiative modeling that accounts for the radiation environment and includes both opacity effects and detailed Stark broadening calculations. These 6-mm-scale radiation-heated plasmas might eventually also prove suitable for testing Stark broadening line profile calculations or for opacity measurements.