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Druart C Delhomme O de Vaufleury A Ntcho E Millet M 《Analytical and bioanalytical chemistry》2011,399(4):1725-1732
Analysing herbicides in soil is a complex issue that needs validation and optimization of existing methods. An extraction and analysis method was developed to assess concentrations of glyphosate, glufosinate and aminomethylphophonic acid (AMPA) in field soil samples. After testing extractions by accelerated solvent extraction and ultrasonic extraction, agitation was selected with the best recoveries. Water was preferred as solvent extraction because it resulted in a cleaner chromatogram with fewer impurities than was the case with alkaline solvents. Analysis was performed by FMOC pre-column derivatization followed by high-performance liquid chromatography (HPLC) on a 300 mm C(18) column which permitted enhanced separation and sensitivity than a 250 mm C(18) column and increased resistance than the NH(2) column for soil samples. This extraction and analysis method allowing a minimum of steps before the injection in the HPLC with fluorescence detection is efficient and sensitive for a clay-loamy soil with detection limits of 103 μg kg(-1) for glyphosate, 15 μg kg(-1) for glufosinate and 16 μg kg(-1) for AMPA in soil samples. 相似文献
73.
García F Less RJ McPartlin M Michalski A Mulvey RE Naseri V Stead ML Morán de Vega A Wright DS 《Chemical communications (Cambridge, England)》2011,47(6):1821-1823
The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li(4)·3thf}(4)(μ(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li(4) sites has negligible effect on the structural parameters. 相似文献
74.
Allison Talley Annette F. Kelley Marcus R. Bond 《Acta Crystallographica. Section C, Structural Chemistry》2011,67(12):m395-m399
The title compound, {(C3H10N)4[Ni3Cl10]}n, contains zigzag layers of tri‐μ‐chlorido‐bridged linear 2/m‐symmetric Ni3Cl12 segments, linked by mono‐μ‐chlorido quasi‐linear bridges to two other segments at each end. These inorganic layers are interleaved with interdigitated bilayers of mirror‐symmetric n‐propylammonium cations, the ammonium head groups of which are directed into the inorganic layers to form multiple N—H...Cl hydrogen bonds, while the propyl tail groups pack together in a tongue‐and‐groove manner in the center of the bilayer. The propyl groups are ordered at 100 K but disordered with opposite conformations on the mirror plane at 240 K. 相似文献
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Wayland E. Noland Mary J. Walhstrom Michael J. Konkel Mark E. Brigham Annette G. Trowbridge Lisa M. C. Konkel Ronald P. Gourneau Cheryl A. Scholten Nina H. Lee John J. Condoluci Todd S. Gac Mehrdad Mostafaei Pour Peter M. Radford 《Journal of heterocyclic chemistry》1993,30(1):81-91
Tetrahydrocarbazoles have been prepared in one-flask syntheses from indoles, ketones or aldehydes, and maleimides, with acid catalysis. The reactions involve a condensation of the indole with the ketone or aldehyde, followed by an in situ trapping of the vinylindole in a Diels-Alder addition with a maleimide. Isomerization of the double bond into the indole nucleus gave the tetrahydrocarbazoles which were isolated ( 6, 9 , and 10 ). Variation of the indole, carbonyl compound, and maleimide has been explored. The predominant stereochemistry of the tetrahydro ring in the products is all-cis, although a second stereoisomer has been isolated. Two regioisomers were generated from all unsymmetrical 2-alkanones, except 2-butanone, which gave the single isomer 9a . Aromatization of tetrahydrocarbazoles 6 to carbazoles 7 was accomplished with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone. 相似文献
77.
Klaus D. A. Wendt Klaus Blaum Christopher Geppert Peter Müller Wilfried Nörtershäuser Annette Schmitt Philipp Schumann Norbert Trautmann Bruce A. Bushaw 《Hyperfine Interactions》2005,162(1-4):147-157
A variety of research activities in the field of fundamental and applied nuclear physics has evolved in the last years using
resonantly tuned radiation from powerful lasers. The technique of resonance ionization spectroscopy has delivered outstanding
results and found broad acceptance in the last years as a particularly efficient and highly selective method for rare and
exotic radioisotope studies. It is used for production, spectroscopy and detection of these species and provides complete
isobaric, high isotopic and even some isomeric selection, which altogether is needed for on-line investigation of short lived
species far off stability as well as for ultra trace determination. Good overall efficiency pushes the experimental limits
of detection in elemental trace analysis down to below 106 atoms per sample, and additionally isotopic selectivity as high as 3 × 1012 has been demonstrated. The widespread potential of resonance ionization techniques is discussed, focusing on the experimental
arrangements for applications in selective on-line isotope production, spectroscopy of rare radioisotopes and ultra trace
determination of radiotoxic isotopes like 238Pu to 244Pu, 135,137Cs, 89,90Sr or 41Ca in environmental, technical and biomedical samples. 相似文献
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