Fe-Ca磁性固体碱催化剂上菜籽油酯交换反应

采用原位沉淀法合成了双功能磁性固体碱催化剂CaO·γ-Fe₂O₃,用于催化菜籽油酯交换反应制备生物柴油。利用XRD、BET、TG-DTA、SEM和VSM对催化剂进行了表征,用ICP-AES对产物脂肪酸甲酯(FAME)中Ca、Fe残留量进行了测定。结果表明,Fe和Ca两种组分间有较好复合,催化剂显示出较好的磁学性能,饱和磁化率达到45.7emu/g,明显高于文献报道的磁性碱催化剂。在温和的反应条件(常压、64℃、催化剂加入量为油重的2.5%、醇油摩尔比15、转速750r/min)下,反应2h,重复使用前三次酯交换反应转化率都维持在95%左右。     

能量连续可调LCS光源SINAP-III

X/γ探测器在航天等国家战略需求领域具有非常广泛和重要的应用。 然而, X/γ探测器要在其有效能区进行精确的标定后才能发挥作用。 目前我国缺乏sub MeV～MeV能量连续可调、 单色性好的γ源, 而用于航天的X/γ探测器无法完成精确定标, 从而使航天探测的发展出现瓶颈问题。 提出了升级原有的激光康普顿散射(LCS)原理性实验装置的方案, 建立了一个通过改变激光入射角来连续调节散射光子能量、 准单色、 极化、 sub MeV～MeV LCS光源(SINAP-III), 从而开拓LCS光源在我国航天领域（如用于航天的X/γ探测器能量定标和抗辐射加固评估研究）的崭新应用前景, 并为将来建设一个基础和应用研究相结合的多功能的γ源实验平台打下基础。 The X/γ detectors in the field of national stratagem, such as astronautical technology, have very broad and important application. These detectors, however, will play their role properly only after accurate calibrations in effective energy region. For the shortage of continuously adjustable and quasi monochromatic γ source in China, it is impossible for the detector employed in aerospace to achieve an accurate calibration so that development of such detector has encountered a big obstacle (or a bottleneck). Therefore, we propose to upgrade the original LCS device to an adjustable photon energy by changing incident angle of laser beam, monochromatic, and polarized sub MeV~MeV LCS γ source(SIMAP III) , in order to explore the new applications of LCS γ source in aerospace as well as to establish a platform for a multifunctional of γ source.     

Experimental demonstration of single-mode fiber coupling using adaptive fiber coupler

Coupling plane wave into a single-mode fiber(SMF) with high and steady coupling efficiency is crucial for fiberbased free-space laser systems, where random angular jitters are the main influencing factors of fiber coupling. In this paper, we verified a new adaptive-optic device named adaptive fiber coupler(AFC) which could compensate angular jitters and improve the SMF coupling efficiency in some degree. Experiments of SMF coupling under the angular jitter situation using AFC have been achieved. Stochastic parallel gradient descent(SPGD) algorithm is employed as the control strategy, of which the iteration rate is 625 Hz. In closed loop, the coupling efficiency keeps above 65% when angular errors are below 80 μrad. The compensation bandwidth is 35 Hz at sine-jitter of 15 μrad amplitude with average coupling efficiency of above 60%. Also, experiments with simulated turbulence have been studied. The average coupling efficiency increases from 31.97% in open loop to 61.33% in closed loop, and mean square error(MSE) of coupling efficiency drops from 7.43% to 1.75%.     

含氟丙烯酸酯与苯乙烯共聚物的RAFT合成及表征

通过可逆加成-断链链转移(RAFT)溶液聚合,以三硫代碳酸酯为RAFT试剂,偶氮二异丁腈(AIBN)为引发剂,1,4-二氧六环为溶剂,制备甲基丙烯酸(2,2,2-三氟)乙酯(TFEMA)和苯乙烯(St)共聚物.详细研究了不同引发剂的用量、RAFT试剂与引发剂摩尔比以及聚合温度等实验条件对聚合反应过程的影响.通过GPC、FTIR测试共聚物的分子量、分子量分布和分子结构,并用静态接触角仪和AFM分别表征聚合物膜的接触角、表面能及膜的表面形貌.     

Measurement of PV asymmetry in n＋p→d＋γ and γ＋d→n＋p

The measurement of parity-violating （PV） observables in few-nucleon system can shed light on our current understanding of the weak interaction between nucleons.Theoretical models describe the nucleonnucleon weak interaction at low energies use a series of undetermined parameters.Two parity violating measurements have been considered： the capture of polarized slow neutrons on hydrogen （n ＋ p → d ＋ γ） at Los Alamos National Laboratory for first phase and Oka Ridge National Laboratory for second phase and the helicity dependence of the deuteron photodisintegration cross section using circularly polarized photons （γ ＋ d → n ＋ p） at Shanghai Institute of Applied Physics.The goal of both experiments is to constraint the weak meson-nucleon couplings to a precision of 1 ×10^-8 .The introduction of both experiments is presented.     

用光学极限的Glauber模型结合相对论平均场对8Li和8B的半径的研究

We study the reaction cross sections （σR） and root-mean-square （RMS） radii of ^8Li and ^8B, the halo-like nuclei, with stable target ^12C, ^27Al and ^9Be within the standard optical-limit Glauber model, using densities obtained from relativistic mean-field （RMF） formalisms and other types of distributions. It is found that the experimental σR can be reproduced well at high energy. The RMS radius and Ar extracted by RMF- theory and harmonic oscillator distribution are compared. larger than those of SLi. In addition, we analyze in detail the We find that the RMS radius and Ar of SB are relationship between σR and density distribution.     

康普顿γ光源SLEGS对长寿命裂变产物126Sn的嬗变潜力

结合激光康普顿散射模拟程序4D-MCLCSS和Geant4软件包, 模拟上海激光电子γ源(SLEGS)的γ光产生及其对长寿命裂变产物¹²⁶Sn的光核嬗变过程, 研究嬗变率与嬗变靶几何参数的依赖关系, 并初步诊断基于SLEGS的光核嬗变产物分布, 获得¹²⁶Sn嬗变靶的最佳靶厚和半径分别为16cm和0.4cm, 对应的嬗变率为1.89×10⁶/s。研究结果表明:基于SLEGS的光核嬗变率比强激光驱动的轫致辐射法要高2倍, 而且升级潜力巨大。     

红外光声光谱技术结合区间、组合区间偏最小二乘测定油菜籽含氮量和含油量

应用红外光声光谱技术结合区间、组合区间偏最小二乘,建立了油菜籽含氮量和含油量的校正模型。结果表明,红外光声光谱技术可以应用于油菜籽品质的快速测定。相对于全谱偏最小二乘建模,区间、组合区间偏最小二乘的采用筛选出了含氮量和含油量的相关波段,使模型简化,并提高了模型预测精度。     

两亲性RAFT试剂存在下丙烯酸六氟丁醋和苯乙烯的无皂乳液聚合

合成了具有两亲性结构的可逆加成断裂链转移(RAFT)试剂,在RAFT试剂的作用下,通过无皂乳液聚合方法合成了丙烯酸六氟丁酯与苯乙烯的共聚物.研究了RAFT试剂浓度和聚合温度对聚合动力学、聚合反应可控性及乳胶粒粒径的影响.通过红外光谱(FTIR)、核磁共振谱(1H NMR)、示差扫描量热仪(DSC)、凝胶渗透色谱仪(GPC)及表面张力仪表征了共聚物的结构、玻璃化转变温度(Tg)、分子量和分子量分布及乳胶膜表面性能.结果表明,得到的苯乙烯和丙烯酸六氟丁酯共聚物无皂乳液的乳胶粒粒径在100 nm左右且呈单分散分布.当RAFT试剂浓度高于0.016 mol/L时聚合体系有较好的可控性.共聚物乳液的乳胶膜对水和二碘甲烷的接触角都很高.     

激光主动照明均匀性影响因素及其规律

针对阶梯相位调制窄谱激光主动照明方法,基于物理模型及工程应用需求,对窄谱激光谱线线型、阶梯相位调制器光学镜数量、光学镜厚度梯度误差三种影响因素,进行了主动照明远场光斑均匀性数值模拟,揭示了照明远场光斑闪烁指数随影响因素的变化规律.结果表明:激光谱线线型对照明光斑均匀性的影响很小,均匀型、高斯型、洛伦兹型激光谱线照明光斑空间闪烁指数均值分别为0.27, 0.28, 0.28;照明光斑闪烁指数随阶梯相位调制器光学镜数量增多而降低,且逐渐趋于平缓;光学镜厚度梯度毫米量级的误差对闪烁指数的影响很小,误差为–0.6 mm时,空间闪烁指数由0.266增大到0.271,恶化率仅为1.9%.