(1+1)维非局域非线性介质的边界对表面孤子的影响

对非局域非线性介质中, (1+1)维表面亮孤子进行了研究, 主要考虑了边界对孤子的影响. 首先, 在归一化系统中, 对于给定的边界条件, 求出了表面孤子的解析解, 得到了表面孤子的临界功率和平衡位置. 其次, 在数值模拟中, 发现当样品宽度太小时, 受到边界影响而很难形成表面孤子, 只有当样品宽度足够大时, 边界对孤子的影响可以忽略, 从而形成稳定传输的孤子, 并与解析的结果相似. 此外, 还考虑了在光束偏离平衡位置入射的情况下, 边界对孤子的影响, 发现此时光束在边界附近做周期性震荡, 相当于体介质中双光束相互作用的结果, 两者运动轨迹与震荡周期完全符合. 关键词： 非局域非线性 边界 样品宽度 周期震荡     

用毛细管成像法测量液相扩散系数——等折射率薄层测量方法

本文提出了一种测量液相扩散系数的新方法. 该方法用透明毛细管构成液相扩散池, 利用毛细管成像法特有的折射率空间分辨测量能力, 通过直接观察和记录扩散介质的等折射率薄层在毛细管中的移动规律, 基于扩散过程遵循的Fick第二定律计算出液相扩散系数. 在25 ℃下研究了丙三醇和纯水间的扩散过程, 扩散系数的测量值与全息干涉法的文献报道值之间的相对误差为4.47%, 论文同时分析了折射率测量精度和毛细管管壁黏滞力对扩散系数的影响. 用毛细管成像法测量液相扩散系数具有样品需要量少、测量速度快、系统稳定性好的特点, 为快速测定微量样品的扩散系数提供了一种有效的新方法. 关键词： 扩散系数 液体折射率 毛细管成像法     

部分相干Airy光束及其传输的研究

利用高斯-谢尔模型的交叉谱密度公式和惠更斯衍射积分, 得到了部分相干Airy光束的表达式. 对不同相干度的部分相干Airy光束的无衍射和横向加速偏移的性质进行了理论分析并予以实验验证, 结果一致表明部分相干Airy光束也具有无衍射和横向加速度的特性, 而且相干度越低, 部分相干Airy光束的无衍射距离越短, 横向加速度越小. 关键词： 傅里叶光学 全息 部分相干 艾里光束     

烯丙醇和烯丙硫醇构象的Dyson轨道和电离能

用B3LYP/aug-cc-pVTZ方法研究了烯丙醇和烯丙硫醇的构象. 采用MP3、MP4(SDQ)和CCSD(T)方法计算了它们的相对能量,这两种分子Gg0构象均最稳定. 根据理论计算的电离能模拟的光电子能谱说明在气相实验中烯丙醇和烯丙硫醇至少存在四种构象. 烯丙硫醇最外壳层和次外壳层的Dyson轨道均显示出强烈的n_S和π_C=C混合特征,这是由于S的孤对电子轨道和C=C_π轨道之间的共振效应和诱导效应引起的.     

Theoretical Study on Intramolecular Proton Transfer of Perylenequinonoid Derivatives

In the past two decades, perylenequinonoid derivatives (PQD), such as hypocrellin A (HA), hypocrellin B (HB) and hypericin (HYP) have attracted considerable attention owing to their excellent properties of photosensitization and great advantages over the investigation of intramolecular proton transfer (IPT)1-5. Previous researches demonstrated that IPT both in the ground state and excited states exists in PQD and is critical for PQD to reserve their photosensitive activity3,6. Altho…     

Determination of Cordycepin in Cordyceps kyushuensis by Capillary Electrophoresis and its Antitumour Activity

~~Determination of Cordycepin in Cordyceps kyushuensis by Capillary Electrophoresis and its Antitumour Activity~~     

Rheological and DSC Studies on the Interaction between κ-Carrageenan and Cellulose Nanocrystals (CNC)

The κ-carrageenan comes from a family of linear water-soluble polysaccharides extracted from different species of marine red algae with a primary structure of an alternating disaccharide with repeating unit of 3-linked β-D-galactose 4-sulfate and 4-link…     

Synthesis and Characterization of Amphiphilic Block Copolymer Containing PVP and Poly(5-benzyloxytrimethylene carbonate)

Amphiphilic block copolymers have attracted great interest recently, especially for thebiomedical uses1, . The hydrophilic blocks improve the biocompatibility of copolymer, 2while the hydrophobic blocks enhance the mechanics of the material and providever…     

Effects of Anions and Cations on π-Complexation Between Olefin and Metal Halide

Introduction Separation,recoveryofolefinorremovalof tracequantitiesofolefinfromitsmixturesbyusing π-complexatonisamostpromisingsolution,com- paredwithenergy-intensivedistillationorotheral- ternatives.π-Complexationisasubgroupofchemi- calcomplexationwhereamixtureisbroughtinto contactwithasecondphasecontainingacomplex- ingagent[1].Forexample,theadsorbentscontain- ingAg+orCu+canselectivelyadsorbolefinfroman ethylene/ethaneorpropylene/propanemixture. Becausetheπ-complexationbondsarestronger th…     

Attempt to Resolute Chiral Clusters by Optically Active Hydrazide

Due to the framework chirality optically active clusters can provide the proof that a cluster as a whole, and not one of its fragments, acts as a catalyst, most of the work have been directed to the synthesis of tetrahedron-type chiral clusters1-3. However, there remains another major problem to obtain the pure enantiomers. Although Vahrenkamp had obtained some pioneering results in this area before 19901, only several racemic chiral clusters have been separated into pure enantiomers until now…