高分子量聚对二氧环己酮体外降解研究

对高分子量(M=2.8×105)的聚对二氧环己酮条状样品在37℃磷酸缓冲溶液(PBS)中的降解行为进行了研究,通过定期观察其吸水率与质量损失,pH,特性黏数,降解过程中样品形态与晶体结构,热力学性能与机械性能的改化,发现此高分子量的聚对二氧环己酮在体外降解过程中质量损失与吸水率变化不大,但分子量下降明显,同时样品表面缺陷逐渐增加;结晶度与玻璃化温度随之改变,但其晶体结构基本保持不变;到第6周时,其力学强度基本消失.证明高分子量PPDO具有较慢的降解速度,显示出很好的稳定性.     

姜黄素类似物的合成及其生物活性的测定

实验合成了姜黄素的Knoevenagel缩合物4-(2-呋喃次甲基)姜黄素C1,氨基硫脲Schiff 碱配体E1,及其Schiff 碱配体的Zn(Ⅱ)配合物D1.采用DPPH法测定了产品清除自由基的能力,结果表明产品C1对DPPH自由基清除率为82.0%.在pH7.2的Tris-Hcl缓冲溶液中,采用紫外光谱和荧光光谱研究了C1与鲱鱼精DNA的相互作用,结果表明,C1与DNA是通过嵌插模式发生相互作用的,其键合常数为Kq =9.31×103.     

奇异摄动Darcy-Stokes问题的一个矩形有限元

构造了一个新的非协调的矩形单元,分析了单元对奇异摄动Darcy-Stokes问题的稳定性,给出了有限元误差分析结果.用数值实验验证了理论分析结果.     

岩土材料的非线性统一强度模型

将材料的破坏归结为剪切破坏,每种材料对应于特定的剪切滑动面,抗剪强度为滑动面上正应力的函数,基于不同材料的强度特性将一系列的剪切滑动面统一起来,建立了岩土材料的非线性统一强度模型.非线性统一强度模型的滑动面为β应力空间内的等倾面,在β应力空间内的强度面为圆锥面;在普通应力空间内的强度面为一系列连续光滑、外凸的锥面,在偏平面上强度曲线涵盖了从下限Matsuoka-Nakai曲线到上限Drucker-Prager圆之间的所有区域,子午面上强度线为直线.非线性统一强度模型只有3个材料参数,参数都具有明确的物理意义,通过与国内外学者已取得的岩土类材料真三轴强度试验结果的比较,表明模型可适用于多种类型的材料,并合理描述其非线性强度特性.      

Tracking of a third-order maneuvering target under an arbitrary topology

We explore the tracking problem of a maneuvering target. Tracking agents with third-order kinematics can communicate with each other via wireless network. The communication network topology is arbitrary rather than switches among several fixed topologies. The information sharing and interaction among agents are position, velocity, and acceleration. Some sufficient conditions of tracking strategy have been proposed. Finally, a numerical example is employed to demonstrate the effectiveness of proposed tracking strategy.     

一种基于证据理论的结构可靠性分析方法

提出了一种基于证据理论的结构可靠性高效求解方法. 通过构造优化问题求解极限状态方程的非概率可靠性指标及设计验算点, 并构造一辅助区域. 通过辅助区域显著减少需要进行极值分析的焦元个数, 并基于区间分析方法减少焦元上极限状态方程的计算次数, 从而有效降低计算成本. 数值算例及工程应用验证了该方法的有效性.     

课间二次备课——专家型教师的一种教学机智

通过观察法记录某专家型教师在不同班级的授课情况,从学生参与情况、教学内容的调整2个层面分析了课间二次备课的效果,认为课间二次备课是专家型教师特有的一种教学机智。     

Uphill anomalous transport in a deterministic system with speed-dependent friction coefficient

We investigate the transport of a deterministic Brownian particle theoretically, which moves in simple onedimensional, symmetric periodic potentials under the influence of both a time periodic and a static biasing force. The physical system employed contains a friction coefficient that is speed-dependent. Within the tailored parameter regime, the absolute negative mobility, in which a particle can travel in the direction opposite to a constant applied force, is observed.This behavior is robust and can be maximized at two regimes upon variation of the characteristic factor of friction coefficient. Further analysis reveals that this uphill motion is subdiffusion in terms of localization(diffusion coefficient with the form D(t) ~t~(-1) at long times). We also have observed the non-trivially anomalous subdiffusion which is significantly deviated from the localization; whereas most of the downhill motion evolves chaotically, with the normal diffusion.     

Stress-induced leakage current characteristics of PMOS fabricated by a new multi-deposition multi-annealing technique with full gate last process

In the process of high-k films fabrication, a novel multi deposition multi annealing(MDMA) technique is introduced to replace simple post deposition annealing. The leakage current decreases with the increase of the post deposition annealing(PDA) times. The equivalent oxide thickness(EOT) decreases when the annealing time(s) change from 1 to 2. Furthermore,the characteristics of SILC(stress-induced leakage current) for an ultra-thin SiO_2/HfO_2 gate dielectric stack are studied systematically. The increase of the PDA time(s) from 1 to 2 can decrease the defect and defect generation rate in the HK layer. However, increasing the PDA times to 4 and 7 may introduce too much oxygen, therefore the type of oxygen vacancy changes.     

基于生活实践的工程流体力学启发性教学初探

工程流体力学教学中需要强调理论与实践的有机结合.本文提出基于生活实践案例以问题链形式进行启发性工程流体力学教学.以总流能量方程及水头损失计算教学为例,设计了"自来水水龙头堵住一部分出口后水流喷射的距离和流量如何变化"这一简单生活实践问题,将重要知识点贯穿其中.教学应用效果表明,启发性、开放性的生活实践问题,能够很好地引导学生综合运用理论知识,解决实际问题,同时能够培养学生的生活观察和独立思考能力.