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131.
DING Jian DING Xue-jia XU Ri-wei YU Ding-sheng * Materials College Beijing University of Chemical Technology Beijing P. R. China Received May 《高等学校化学研究》2005,21(2):227-231
The viscoelastic behavior of isotactic polypropylene with ultra-high molecular weight (UHPPH) and broad molecular weight distribution(MWD), produced in the presence of Ziegler-Natta catalyst, was investigated by means of oscillatory rheometry at 180 and 200 ℃, whose loss modulus(G") plots at 180 and 200 ℃versus the natural logarithm of angular frequency(ω) present a pronounced maximum at 34.35 and 69.21 rad/s, respectively, and do not show a maximum peak at 0. 01-100 rad/s for Ziegler-Natta catalyzing ethylenepropylene random copolymerization (PPR) with a conventional molecular weight and broad MWD. The fact indicates that the high molecular weight is responsible for a maximum peak of G"(ω) vs. lnω curves for UHPPH. This makes it possible to determine the plateau modulus (G0N) of UHPPH from a certain experimental temperature G"(ω) curve directly. For UHPPH, the G0N determined to be 4. 28×105 and 3. 62×105 Pa at 180and 200 ℃, respectively, decreases with the increase of temperature and is independent of the molecular weight, which directly confirms reputation theoretical prediction that the G0N has no relation to the molecular weight. 相似文献
132.
利用具有同步辐射源的反射式飞行时间质谱仪,研究甲基环己烷的真空紫外光电离和光解离. 观测到母体离子C7H14+和碎片离子C7H13+,C6H11+,C6H10+,C5H10+,C5H9+,C4H8+,C4H7+和C3H5+的光电离效率曲线. 测定甲基环己烷的电离能为9.80±0.03 eV,通过光电离效率曲线确定其碎片离子的出现势. 在B3LYP/6-31G(d)水平上对过渡态、中间体和产物离子的优化结构进行表征,并使用G3B3方法计算其能量. 提出主要碎片离子的形成通道. 分子内氢迁移和碳开环是甲基环己烷裂解途径中最重要的过程. 相似文献
133.
134.
Li Zha Renzhong Feng~* 《高等学校计算数学学报(英文版)》2007,16(4):348-357
In this paper,a new quasi-interpolation with radial basis functions which satis- fies quadratic polynomial reproduction is constructed on the infinite set of equally spaced data.A new basis function is constructed by making convolution integral with a constructed spline and a given radial basis function.In particular,for twicely differ- entiable function the proposed method provides better approximation and also takes care of derivatives approximation. 相似文献
135.
Jin Yan WANG Shu De XIAO Xi Gao JIAN* Department of Polymer Science & Materials Dalian University of Technology Dalian 《中国化学快报》2003,14(4)
Aromatic polyimides are distinguished for their excellent mechanical and thermal properties in many engineering fields1. However, aromatic polyimides are normally insoluble in common organic solvents, which restricts their applications in some fields. Many efforts have been taken to improve their solubility. Introducing bulky side groups and non-coplanar structure into polymers bone chains is a good way to obtain the polymers with excellent mechanical and thermal properties2. In this paper… 相似文献
136.
Ling Jun LI Xin Ying ZHANG* Gui Sheng ZHANG* School of Chemical Environmental Sciences Henan Normal University Key Laboratory of Environmental Science Engineering of Henan Education Department Xinxiang 《中国化学快报》2004,(5)
~~An Efficient and Green Procedure for the Preparation of gem-Dicar- boxylates from Aldehydes Catalyzed by Fe_2(SO_4)_3·xH_2O~~ 相似文献
137.
利用自制的直接激光射串接飞行时间质谱 计,获得了三苯基磷和三苯基砷的激光等离子体质谱及其正 离子团簇与超声速的氮气碰撞诱离解二级行时间质谱,分析和比较了它们的质谱特征及其正 离子团簇的碰撞解离特点,探索了其团簇离子的从键和结构特征。 相似文献
138.
YU Zhaoxian LIU Yehou * 《Chinese Journal of Lasers》1998,7(4):363-367
1IntroductionItiswelknownthatbosonrealizationapproachisveryefectivetostudytherepresentationtheoryofgroup,andthebosonrealizat... 相似文献
139.
Ye Hua SHEN Hai Bo WANG Quan BAI Xin Du GENG* Institute of Modern Separation Science Shaanxi Provincial Key Laboratory of Modern Separation Science Northwest University Xi抋n 《中国化学快报》2003,(3)
Theinvestigationofproteinrenaturation,orrefoldinghasbecomeaveryhotpointinbothliquidchromatography(LC)andlifesciencefields.Besidesusualdilutionanddialysismethods,manynewmethodsconcernproteinrenaturationhavebeenpresented,suchasreversemicelles1,chaperones2,polyethyleneglycol(PEG)3,surfactant4andantibodies5etc.Oneoftheauthorssuggestedhighperformancehydrophobicinter-actionchromatography(HPHIC)tobeanewtoolforproteinrenaturation6.Areviewonproteinrenaturationwithliquidchromatography(LC)wasrecentl… 相似文献
140.
Xing Zhou LI Ke Mei WU Dao Fei HUANG Liang HUANG* Institute of Materia Medica Chinese Academy of Medical Sciences & Peking Union Medical College. Xian Nong Tan St. Beijing 《中国化学快报》2002,13(6):528-530
(-) Clausenamide (1) showed strong nootropic action, while its (+) antipode had no such an action. The content of CM1(2) in the metabolites of (-)1 is much higher than that of (+)11. For comparing the nootropic activity of enantiomers, (+) and (-) CM1 were synthesized. CM1 is the hydroxylated product of the N-methyl group of clausenamide. Oxidation of the C3-OH and C6-OH protected clausenamide to introduce the hydroxyl group into the methyl was tried but unsuccessful. Then de novo s… 相似文献